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BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE

CAS No.: 184951-87-9

Chemical Name:: BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE

Synonyms: BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE;(S)-2-(Boc-amino)-3-phenyl propanethioic O-acid-1-;(S)-2-(BOC-AMINO)-PRPPNETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE;BOC-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO)BENZOTRIAZOLIDE;(S)-2-(BOC-AMINO)-3-PHENYL-PROPANETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE;(S)-2-[(t-Butoxycarbonyl)amino]-1-(6-nitrobenzotriazol-1-yl)-3-phenylpropane-1-thione;N-ALPHA-T-BUTOXYCARBONYL-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO) BENZOTRIAZOLIDE;tert-butyl N-[(2S)-1-(6-nitrobenzotriazol-1-yl)-3-phenyl-1-sulfanylidenepropan-2-yl]carbamate;[(1S)-2-(6-Nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]carbamic acid tert-butyl ester;Carbamic acid, [(1S)-2-(6-nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]-, 1,1-dimethylethyl ester (9CI)

CBNumber:: CB0753852

Molecular Formula:: C20H21N5O4S

Molecular Weight:: 427.48

MOL File:: 184951-87-9.mol

MSDS File:: SDS

Modify Date:: 2023/4/27 16:27:43

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BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Properties

Density	1.36
storage temp.	-15°C
pka	10.06±0.46(Predicted)

BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Chemical Properties,Uses,Production

Uses

BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly used in laboratory research and development process and chemical production process.

Synthesis

To a solution of thioanilide 7 (2 mmol) dissolved by gentle warming at 40 °C and then cooled to 0 °C in glacial acetic acid (diluted with 5% water, 15 mL) was added NaNO2 (0.21 g, 3 mmol) in portions over 5 min with stirring. After 30 min, ice water (～100 mL) was added, and the precipitated product was filtered and washed with water. The orange solid was dried in vacuo at rt overnight and then at 50 °C for 4 h to afford benzotriazoles 1-(N-BOC-L-thionophenylalaninyl)-6-nitrobenzotriazole (9b): yield 81%. as amorphous solids of sufficient purity for use in the next step.

BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Preparation Products And Raw materials

Raw materials

Carbamic acid, [2-[(2-amino-5-nitrophenyl)amino]-1-(phenylmethyl)-2-thioxoethyl]-, 1,1-dimethylethyl ester, (S)- (9CI) N-(tert-Butoxycarbonyl)-L-phenylalanine

Preparation Products

BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Suppliers

Global( 13)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
CONIER CHEM AND PHARMA LIMITED	+8618523575427	China	49403	58	Inquiry
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	China	29798	60	Inquiry
BOC Sciences	16314854226; +16314854226	United States	19743	58	Inquiry
Nextpeptide Inc	+86-0571-81612335 +8613336028439	China	19915	58	Inquiry
Amadis Chemical Company Limited	571-89925085	China	131980	58	Inquiry
Shanghai Hao Zhun Biological Technology Co., Ltd.	15800340161	CHINA	6846	58	Inquiry
TCI (Shanghai) Chemical Trading Co., Ltd.	021-021-61109150	China	31130	58	Inquiry
Carbosynth	+86 512 6260 5585	United Kingdom	6018	58	Inquiry
Watanabe Chemical Industries, Ltd.	81 822310540	Japan	4813	42	Inquiry
Chem-Impex International, Inc.	800 869-9290 US and Canada only	United States	6740	64	Inquiry

Supplier	Advantage
CONIER CHEM AND PHARMA LIMITED	58
Capot Chemical Co.,Ltd.	60
BOC Sciences	58
Nextpeptide Inc	58
Amadis Chemical Company Limited	58
Shanghai Hao Zhun Biological Technology Co., Ltd.	58
TCI (Shanghai) Chemical Trading Co., Ltd.	58
Carbosynth	58
Watanabe Chemical Industries, Ltd.	42
Chem-Impex International, Inc.	64

184951-87-9(BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE)Related Search:

2-(1H-BENZO[D][1,2,3]TRIAZOL-1-YL)ETHANAMINE BOC-THIONOALA-1-(6-NITRO)BENZOTRIAZOLIDE 2-AMINO-THIOPROPIONAMIDE BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE BOC-L-PHENYLALANINE THIOAMIDE

BOC-L-ALANINE THIOAMIDE 1-n-Butylbenzotriazole 2-(1H-1,2,3-TRIAZOL-1-YL)ETHANAMINE TERT-BUTYL 2-AMINO-2-THIOXOETHYLCARBAMATE 5-NITROBENZOTRIAZOLE

2-AMINO-3-PHENYL-THIOPROPIONAMIDE

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(S)-2-(BOC-AMINO)-3-PHENYL-PROPANETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE (S)-2-(BOC-AMINO)-PRPPNETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE N-ALPHA-T-BUTOXYCARBONYL-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO) BENZOTRIAZOLIDE (S)-2-(Boc-amino)-3-phenyl propanethioic O-acid-1- BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE BOC-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO)BENZOTRIAZOLIDE [(1S)-2-(6-Nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]carbamic acid tert-butyl ester Carbamic acid, [(1S)-2-(6-nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]-, 1,1-dimethylethyl ester (9CI) (S)-2-[(t-Butoxycarbonyl)amino]-1-(6-nitrobenzotriazol-1-yl)-3-phenylpropane-1-thione tert-butyl N-[(2S)-1-(6-nitrobenzotriazol-1-yl)-3-phenyl-1-sulfanylidenepropan-2-yl]carbamate 184951-87-9 C20H21N5O4S