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FORMOTHION

FORMOTHION Structure
CAS No.
2540-82-1
Chemical Name:
FORMOTHION
Synonyms
p1;JC7;J-38;NUCKS;Antio;s6900;Aflix;NUCKS1;S 6900;ANTHIO
CBNumber:
CB0757865
Molecular Formula:
C6H12NO4PS2
Molecular Weight:
257.27
MOL File:
2540-82-1.mol
MSDS File:
SDS
Modify Date:
2024/3/14 15:18:25

FORMOTHION Properties

Melting point 25.5℃
Boiling point 317.8±52.0 °C(Predicted)
Density 1.361 g/cm3 (20 ºC)
vapor pressure 1.13 x 10-4 Pa (20 °C)
refractive index 1.5541 (589.3 nm 20℃)
Flash point 25 °C
storage temp. 2-8°C
pka -1.79±0.70(Predicted)
Water Solubility 2600 mg l-1(24 °C)
form solid
BRN 5942199
CAS DataBase Reference 2540-82-1(CAS DataBase Reference)
EPA Substance Registry System Formothion (2540-82-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS06,GHS08
Signal word  Danger
Hazard statements  H226-H302-H304-H311+H331-H315-H319-H335-H373-H412
Precautionary statements  P210-P273-P280-P301+P310-P303+P361+P353-P331
Hazard Codes  Xn
Risk Statements  21/22-36/38-20/21/22-10
Safety Statements  36/37-36-26
RIDADR  3018
WGK Germany  3
HazardClass  6.1(b)
PackingGroup  III
Toxicity LD50 in rats, rabbits (mg/kg): 350, 410 orally (Liesche)

FORMOTHION price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 46424 Formothion solution ~80% in xylene, PESTANAL?, analytical standard 2540-82-1 250MG ₹13486.2 2022-06-14 Buy
Product number Packaging Price Buy
46424 250MG ₹13486.2 Buy

FORMOTHION Chemical Properties,Uses,Production

Description

Formothion is a pale yellow liquid or crystalline mass, decomposes on distillation, mp 25–26 ?C, vp 0.113 mPa (20 ?C). It is poorly soluble in water (2.6 g/L at 24 ?C) and miscible with most organic solvents, except aliphatic hydrocarbons. Log Kow = 1.47. Formothion is hydrolyzed in aqueous media to dimethoate (activation) and dimethoate carboxylic acid (degradation): DT50 (23 ?C) at pH 3–9 is less than 1 d.

Chemical Properties

Formothion is an odorless, yellowish viscous oil or crystalline mass.

Uses

Formothion is used to control sucking pests and internally feeding larvae in a variety of crops.

General Description

Viscous yellow oil or a crystalline mass. Used as an insecticide and acaricide on crops and ornamentals. Not presently produced commercially in the U.S.

Air & Water Reactions

hydrolyzed by water especially under alkaline conditions. [EPA, 1998].

Reactivity Profile

Organophosphates, such as FORMOTHION, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Hazard

Cholinesterase inhibitor.

Health Hazard

FORMOTHION is one of the least toxic systemic organophosphates. FORMOTHION is a compound of low to moderate toxicity. It causes the depression of cholinesterase, leading to accumulation of acetylcholine in the nervous system, which is believed to be responsible for the symptoms.

Fire Hazard

When heated to decomposition, FORMOTHION emits very toxic fumes of nitrogen oxides, phosphorus oxides and sulfur oxides. FORMOTHION is an organophosphorus insecticide. Some of these materials may burn but none of them ignite readily. Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Avoid alkaline pesticides; hydrolyzed by water especially under alkaline conditions.

Agricultural Uses

Insecticide, Acaricide: Formothion is a systemic and contact insecticide used to control spider mites, aphids, psyllids, mealy bugs, whiteflies, jassids, leaf miners, ermine moths, and fruit flies. It is used on tree fruits, vines, olives, hops, cereals, sugar cane, rice. Formothion is available as an emulsifiable concentrate and an ultra-low-volume spray. A U.S. EPA restricted Use Pesticide (RUP). Not approved for use in EU countries

Trade name

AFLIX®; ANTHIO®; ANTIO®; CP 53926®; S 6900®; SAN 244 I®; SAN 6913 I®; SAN 71071®; SPENCER S-6900®; VEL 4284®

Safety Profile

Poison by ingestion, inhalation, sh contact, and intravenous routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, POx, and SOx. See also ESTERS.

Potential Exposure

Formothion is an insecticide and acar icide for use on crops and ornamentals. Formothion is not currently produced commercially in the U.S.

Metabolic pathway

Formothion is broken down in aqueous solution to approximately equal amounts of dimethoate and dimethoate carboxylic acid, the first of which is an activation step and the latter a degradative one. All studies which have investigated the fate of formothion in biological systems have identified these two metabolites but there is evidence that their formation is purely base-catalysed and not enzyme-catalysed. In this respect, the amide group of formothion is much more labile than that of dimethoate since dimethoate carboxylic acid has only been reported in metabolic studies and is not formed by base-catalysed hydrolysis of dimethoate.

Shipping

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the pres ence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.

Waste Disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow ing package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

FORMOTHION Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 89)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Shenzhen Nexconn Pharmatechs Ltd +86-755-89396905 +86-15013857715 China 10311 58 Inquiry
TargetMol Chemicals Inc. +1-781-999-5354 +1-00000000000 United States 19892 58 Inquiry
Career Henan Chemica Co +86-0371-86658258 +8613203830695 China 30250 58 Inquiry
Dideu Industries Group Limited +86-29-89586680 +86-15129568250 China 24200 58 Inquiry
SUZHOU SENFEIDA CHEMICAL CO.,LTD +86-0512-83500002 +8615195660023 China 23053 58 Inquiry
Chengdu Youngshe Chemical Co., Ltd. +86-17380623303 +86-17380623303 China 4887 58 Inquiry
Alta Scientific Co., Ltd. 022-6537-8550 15522853686 China 4515 55 Inquiry
Portail Substances Chimiques 10 20 0000 France 6027 58 Inquiry
United States Biological 800.520.3011 or 781.639.5092 United States 6256 80 Inquiry
S-[2-(FORMYLMETHYLAMINO)-2-OXOETHYL] O,O-DIMETHYL DITHIOPHOSPHATE S-[2-(FORMYLMETHYLAMINO)-2-OXOETHYL]-O,O-DIMETHYL-PHOSPHORODITHIONATE O,O-DIMETHYL S-(N-FORMYL-N-METHYL-CARBAMOYLMETHYL)PHOSPHORODITHIOATE Formothionsolution in xylene PESTANAL, s Formothion 0.1 ForMothion solutio Anthio 33 nthio 25 Anti-NUCKS1 antibody produced in rabbit ANTI-NUCKS1 (N-TERM) antibody produced in rabbit JC7 NUCKS NUCKS1 formothion (bsi,iso,esa,jmaf) formothion solution FORMOTHION STANDARD O,O-Dimethyl-S-(N-methyl-N-formylaminomethyl)dithiophosphate formothion (ISO) N-formyl-N-methylcarbamoylmethyl O,O-dimethyl phosphorodithioate 2-[(Dimethoxyphosphinothioyl)thio]-N-methyl-N-formylacetamide Dithiophosphoric acid O,O-dimethyl S-(N-formyl-N-methylcarbamoylmethyl) ester O,O-DIMETHYLS-(N-FORMYL-N-METHYLCARBAMOYLMETHYL)DITHIOPHOSPHATE GLY-SER-PHE-LEU-VAL-ARG-GLU-SER 2-dimethoxyphosphinothioylsulfanyl-N-formyl-N-methylacetamide 2-dimethoxyphosphinothioylsulfanyl-N-methanoyl-N-methyl-ethanamide N-[2-(dimethoxythiophosphorylthio)acetyl]-N-methyl-formamide Formothion 100mg [2540-82-1] Formothion - See P-149S-CN - See P-149S-CN Acetamide, N-formyl-2-mercapto-N-methyl-, S-ester with O,O-dimethyl phosphorodithioate acetamide,n-formyl-2-mercapto-n-methyl-,s-esterwitho,o-dimethylphosphoro acetamide,n-formyl-2-mercapto-n-methyl-,s-esterwitho,o-dimethylphosphorodi afliz(sandoz) Anthio 25 anthio25 Antio CP 53926 cp53926 des-ester ENT 27,257 ent27,257 formothion25ec J-38 mides-ester N-Formyl-N-methylcarbamoylmethyl O,O-dimethyl phosphorodithioate n-formyl-n-methylcarbamoylmethylo,o-dimethylphosphorodithioate O,O-Dimethyl Dithiophosphorylacetic acid N-methyl-N-formylamide O,O-Dimethyl phosphorodithioate N-formyl-2-mercapto-N-methylacetamide S-ester O,O-Dimethyl S-(N-methyl-N-formylcarbamoylmethyl)phosphorodithioate o,o-dimethyldithiophosphorylaceticacidn-methyl-n-formylamide o,o-dimethylester,s-esterwithn-formyl-2-mercapto-n-phosphorodithioicaci o,o-dimethylphosphorodithioaten-formyl-2-mercapto-n-methylacetamides-ester O,O-Dimethyl-S-(3-methyl-2,4-dioxo-3-azabutyl)dithiofosfaat o,o-dimethyl-s-(3-methyl-2,4-dioxo-3-aza-butyl)-dithiofosfaat O,O-Dimethyl-S-(3-methyl-2,4-dioxo-3-azabutyl)dithiophosphat o,o-dimethyl-s-(3-methyl-2,4-dioxo-3-aza-butyl)-dithiophosphat O,O-Dimethyl-S-(N-methyl-N-formylcarbamoylmethyl)dithiophosphat o,o-dimethyl-s-(n-methyl-n-formyl-carbamoylmethyl)-dithiophosphat o,o-dimethyls-(n-methyl-n-formylcarbamoylmethyl)phosphorodithioate O,O-Dimetil-S-(N-formil-N-metilcarbamoilmetil)ditiofosfato