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Fluazinam

Fluazinam Structure
CAS No.
79622-59-6
Chemical Name:
Fluazinam
Synonyms
Fluazinam Standard;3-Chloro-N-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)pyridin-2-amine;pp192;Mapro;B 1216;AltiMa;Sekoya;SHIRLAN;ikf1216;IKI 1216
CBNumber:
CB1161197
Molecular Formula:
C13H4Cl2F6N4O4
Molecular Weight:
465.09
MOL File:
79622-59-6.mol
Modify Date:
2024/7/12 17:58:41

Fluazinam Properties

Melting point 100-102°
Boiling point 376.1±42.0 °C(Predicted)
Density 1.766±0.06 g/cm3(Predicted)
vapor pressure 1.5 x 10-3 Pa (25 °C)
Flash point 2 °C
storage temp. 2-8°C
solubility DMF:25.0(Max Conc. mg/mL);53.75(Max Conc. mM)
DMSO:25.0(Max Conc. mg/mL);53.75(Max Conc. mM)
Ethanol:15.0(Max Conc. mg/mL);32.25(Max Conc. mM)
PBS (pH: 7.2):0.25(Max Conc. mg/mL);0.54(Max Conc. mM)
form Solid
pka 7.11(at 25℃)
Water Solubility 1.7 mg l-1 (25 °C)
color Light yellow to Amber to Dark green
Merck 14,4117
BRN 4772672
InChIKey UZCGKGPEKUCDTF-UHFFFAOYSA-N
LogP 3.560
CAS DataBase Reference 79622-59-6(CAS DataBase Reference)
EPA Substance Registry System Fluazinam (79622-59-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H317-H318-H332-H361d-H410
Precautionary statements  P273-P280-P302+P352-P304+P340+P312-P305+P351+P338-P308+P313
Hazard Codes  T;N,N,T,Xn,F
Risk Statements  23-41-43-50/53-36-20/21/22-11-38-20-63
Safety Statements  26-36/37/39-45-60-61-36/37-16-63-57-56-38-28-27-24/25-20/21-13
RIDADR  UN 2811
WGK Germany  3
RTECS  UR8085000
HazardClass  6.1
PackingGroup  II
HS Code  29333990
NFPA 704
0
3 0

Fluazinam price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 34095 Fluazinam PESTANAL?, analytical standard 79622-59-6 100MG ₹12557 2022-06-14 Buy
TCI Chemicals (India) F0869 Fluazinam 79622-59-6 1G ₹5700 2022-05-26 Buy
Product number Packaging Price Buy
34095 100MG ₹12557 Buy
F0869 1G ₹5700 Buy

Fluazinam Chemical Properties,Uses,Production

Description

Fluazinam, with a LogP of 3.56, has very low solubility in water (1.7 mgL?1, pH6.8, 25?C) but higher solubilities in organic solvents (e.g., acetone 470 g/L, dichloromethane 330 g/L, ethanol 150 g/L, all at 20 ?C). The active ingredient forms light yellow crystals with an MP of 115 to 117 ?C and has a vp of 1.5 mPa (25 ?C). The compound is stable to acid, alkali, and heat (5).

Chemical Properties

yellow crystal mp 115 ~ 117°C

Uses

Fluazinam is a broad spectrum fungicide. Fluazinam is commonly used for control of Sclerotinia blight and other soilborne pathogens of peanut as well for the control of potato blight.

Definition

ChEBI: Fluazinam is a member of the class of aminopyridines that is 2-amino-5-(trifluoromethyl)pyridine in which one of the amino hydrogens is replaced by a 3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl group. A fungicide used to control grey mould, downy mildew and other fungal pathogens. It has a role as an apoptosis inducer, an allergen, a xenobiotic, an environmental contaminant and an antifungal agrochemical. It is a C-nitro compound, a chloropyridine, an aminopyridine, a secondary amino compound, a member of monochlorobenzenes and a member of (trifluoromethyl)benzenes.

General Description

Fluazinam is a 2,6-dinitroaniline protectant fungicide, which belongs to the pyridinamine group. It can mostly find applications in agriculture.

Hazard

Moderately toxic by ingestion and inhalation. A reproductive hazard.

Agricultural Uses

Fungicide: Used to control Sclerotinia blight on peanuts and late blight and white mold on potatoes.

Trade name

FLUAZINAM 50 WP®; FROWNCIDE®; IKF-1216®; ICIA-192®; OMEGA; PP-192®; SHIRLAN®

Contact allergens

Fluazinam is a pesticide with a broad spectrum of anti fungal activity. It caused sensitization in employees in the tulip bulb industry and in farmers. Fluazinam induced contact dermatitis in a worker in a plant where it was manufactured.

Safety Profile

Moderately toxic by ingestion and inhalation. Experimental reproductive effects. When heated to decomposition it emits toxic vapors of NOx, F-, and Cl-.

Metabolic pathway

Fluazinam may typically be applied to crops of potatoes using up to 10 applications each of 150 g ha-1. Routes of degradation involve ring hydroxylation in aerobic soils and reduction of the nitro groups in flooded soils. A large amount of unextractable residue was observed. In potatoes and rats, important reactions involve the reduction of nitro groups and the formation of conjugates. In plants, the trifluoromethyl substituents are hydrolysed to carboxylic acid groups. Most of the information presented below was taken from an evaluation of the fungicide published by the UK Pesticide Safety Directorate (PSD, 1994).

Fluazinam Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 245)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Cropnosys India Pvt Ltd +91-9820230501 +91-8029727145 Karnataka, India 25 58 Inquiry
Pharma Affiliates 172-5066494 Haryana, India 6761 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Pharmaffiliates Analytics and Synthetics P. Ltd +91-172-5066494 Haryana, India 6773 58 Inquiry
Cropnosys India (P) LTD 91--8029727145 Karnataka, India 8 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
ChemOrbit International 91-40-23712139 Hyderabad, India 264 58 Inquiry
SRIRAMCHEM Laboratories Pvt., Ltd. 91-9686622202 Karnataka, India 21 58 Inquiry

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SHIRLAN FLUAZINAM ikf1216 pp192 shirlan(zeneca) shirlanflow 3-chloro-N-(3-chloro-5-trifluoromethyl-2-pyridyl)-α,α,α-trifluor-2,6-dinitro-p-toluidine 2-Pyridinamine, 3-chloro-N-3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl-5-(trifluoromethyl)- fluazinam (bsi,iso) fluaziname FLUAZINAM SOLUTION 3-Chloro-N-(3-chloro-5-trifluoromethyl-2-pyridyl)-α,α,α-trifluoro-2,6-dinitro-p-toluidine 3-Chloro-N-(3-chloro-5-trifluoromethyl-2-pyridyl)-α,α,α-trifluoro-2,6-dinitro-p-toluidine, 3-Chloro-N-(3-chloro-2,6-dinitro-4-trifluoromethylphenyl)-5-trifluoromethyl-2-pyridylamine 3-chloro-N-(3-chloro-5-trifluoromethyl-2-pyridyl)-α,α,α-trifuor-2,6-dinitro-p-toluidine B 1216 IKI 1216 FROWNCIDE 3-chloro-n-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)-2-pyridinamine 3-CHLORO-N-(3-CHLORO-2,6-DINITRO-4-TRIFLUOROMETHYLPHENYL)-5-TRIFLUOROMETHYL-2-PYRIDYLAMINE 3-CHLORO-N-(3-CHLORO-5-TRIFLUOROMETHYL-2-PYRIDYL)-ALPHA,ALPHA,ALPHA-TRIFLUORO-2,6-DINITRO-P-TOLUIDINE 3-chloro-n-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)-2-pyridinamin 3-chloro-n-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-2-pyridinamin 6-dinitro-4-trifluoromethylphenyl)-5-trifluoromethyl-3-chloro-n-(5-chloro- asc66825 asc67178 Frowncide SC 3-Chloro-N-(5-chloro-2,6-dinitro-4-trifluoromethylphenyl)-5-trifluoromethyl-2-pyridinamine Fluazinam [iso] Hsdb 7264 Fluazinam 100mg [79622-59-6] AltiMa Mapro N-(3-Chloro-5-trifluoroMethyl-2-pyridyl)-2,6-dinitro-3-chloro-4-trifluoroMethylaniline Sekoya Fluazinam> Fluazinam @100 μg/mL in MeOH Altima(TM) 3-Chloro-N-(3-chloro-2,6-dinitro-4-trifluoromethylphenyl)-5-trifluoromethyl-2-pyridylamine, 3-Chloro-N-(3-chloro-5-trifluoromethyl-2-pyridyl)-α,α,α-trifluoro-2,6-dinitro-p-toluidine Fluazinam Solution, 1000ppm 3-Chloro-N-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)-2-pyridina FluazinamSolution,100mg/L,5x1ml FluazinamSolution,100mg/L,1ml Fluazinam@1000 μg/mL in Methanol Fluazinam Standard 3-Chloro-N-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)pyridin-2-amine fluridine Fluazinam Solution in Methanol Fluazinam Solution in Acetonitrile 79622-59-6 9622-59-6 C13H4Cl2F6N4O4 C13H4CI2F6N4O4 API intermediates Agro-Products Amines Aromatics Heterocycles Intermediates & Fine Chemicals