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N-Methyl-4-nitroaniline

N-Methyl-4-nitroaniline Structure
CAS No.
100-15-2
Chemical Name:
N-Methyl-4-nitroaniline
Synonyms
Nitronaniline;4-nitro-n-methylaniline;Methyl-4-nitroaniline;Intedanib Impurity 10;N-methy-4-nitroanline;N-Methyl-p-nitraniline;Miglinide intermediate;N-METHYL-P-NITROANILINE;N-METHYL-4-NITROANILINE;P-NITRO-N-METHYLANILINE
CBNumber:
CB1387643
Molecular Formula:
C7H8N2O2
Molecular Weight:
152.15
MOL File:
100-15-2.mol
MSDS File:
SDS
Modify Date:
2024/7/29 18:03:56

N-Methyl-4-nitroaniline Properties

Melting point 149-151 °C(lit.)
Boiling point 294.61°C (rough estimate)
Density 1.2010
vapor density 5.25 (vs air)
refractive index 1.6276 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
pka 0.56±0.12(Predicted)
color Yellow to Very Dark Yellow
Water Solubility <0.1 g/100 mL at 19 ºC
BRN 637920
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey XIFJZJPMHNUGRA-UHFFFAOYSA-N
CAS DataBase Reference 100-15-2(CAS DataBase Reference)
NIST Chemistry Reference Benzenamine, N-methyl-4-nitro-(100-15-2)
EPA Substance Registry System N-Methyl-p-nitroaniline (100-15-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08
Signal word  Danger
Hazard statements  H301+H311+H331-H373-H412
Precautionary statements  P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314
Hazard Codes  T,Xi
Risk Statements  23/24/25-33-36/37/38
Safety Statements  28-36/37/39-45-26
RIDADR  2811
WGK Germany  3
Hazard Note  Highly Toxic/Irritant
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29214200
NFPA 704
1
3 0

N-Methyl-4-nitroaniline price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 269638 N-Methyl-4-nitroaniline 97% 100-15-2 25G ₹5412.5 2022-06-14 Buy
Sigma-Aldrich(India) 269638 N-Methyl-4-nitroaniline 97% 100-15-2 100G ₹18943.75 2022-06-14 Buy
Product number Packaging Price Buy
269638 25G ₹5412.5 Buy
269638 100G ₹18943.75 Buy

N-Methyl-4-nitroaniline Chemical Properties,Uses,Production

Chemical Properties

brownish-yellow crystalline powder

Uses

N-Methyl-4-nitroaniline is a versatile reactant used in the synthesis of oxindoles using Pd-catalyzed cyclization of chloroacetanilides.

General Description

Brownish-yellow prisms with violet reflex (from ethanol) or yellow powder.

Air & Water Reactions

N-Methyl-4-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.

Reactivity Profile

N-Methyl-4-nitroaniline has a vigorous exothermic reaction with carbaryl sulfate when heated above 167° F.

Fire Hazard

Flash point data for N-Methyl-4-nitroaniline are not available; however, N-Methyl-4-nitroaniline is probably combustible.

Purification Methods

Crystallise the aniline from aqueous EtOH. [Beilstein 12 H 714.]

Global( 359)Suppliers
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