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DEHYDROASCORBIC ACID

DEHYDROASCORBIC ACID Structure
CAS No.
490-83-5
Chemical Name:
DEHYDROASCORBIC ACID
Synonyms
Dehydroascorbate;DEHYDRO-L-ASCORBIC ACID;BIS-DHA;C05422;ehydroascorbicaci;L-Dehydroascorbate;OXIDIZED VITAMIN C;DEHYDROASCORBIC ACID;Oxidized Ascorbic Acid;L-ASCORBIC ACID OXIDIZED
CBNumber:
CB1397000
Molecular Formula:
C6H6O6
Molecular Weight:
174.11
MOL File:
490-83-5.mol
MSDS File:
SDS
Modify Date:
2023/6/8 9:03:01

DEHYDROASCORBIC ACID Properties

Melting point 228 °C (dec.)(lit.)
alpha D20 +56°
Boiling point 389.3±38.0 °C(Predicted)
Density 1.743±0.06 g/cm3(Predicted)
storage temp. -20°C
solubility DMSO (Slightly, Heated), Methanol (Slightly, Sonicated)
form Solid
pka 3.90(at 25℃)
color White to Dark Orange
Merck 13,2886
Stability Light Sensitive
LogP -1.702 (est)
CAS DataBase Reference 490-83-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312+P330-P501
Hazard Codes  Xn
Risk Statements  22
WGK Germany  3
1-8-10
HS Code  2936270000
NFPA 704
0
2 0

DEHYDROASCORBIC ACID price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 261556 (L)-Dehydroascorbic acid 490-83-5 250MG ₹6646.55 2022-06-14 Buy
Sigma-Aldrich(India) 261556 (L)-Dehydroascorbic acid 490-83-5 1G ₹12156.48 2022-06-14 Buy
Sigma-Aldrich(India) 261556 (L)-Dehydroascorbic acid 490-83-5 5G ₹22743.33 2022-06-14 Buy
Product number Packaging Price Buy
261556 250MG ₹6646.55 Buy
261556 1G ₹12156.48 Buy
261556 5G ₹22743.33 Buy

DEHYDROASCORBIC ACID Chemical Properties,Uses,Production

Chemical Properties

Orange Solid

Uses

The reversibly oxidized form of ascorbic acid.

Definition

ChEBI: Dehydroascorbic acid having the L-configuration.

Purification Methods

Crystallise dehydro-L(+)-ascorbic acid from MeOH. The anhydrous acid is formed by heating it in a vacuum at 100o/1hour to give a crisp glassy product which when shaken with absolute EtOH and then kept at 0o for 2days gives microcrystals of the anhydrous acid. This is then washed with absolute EtOH and dried in a vacuum. It has m 225o(dec) and is stable in acidic solution but decomposes rapidly in alkaline solution. A 1% solution of the anhydrous acid when dissolved in phthalate/HCl buffer pH 3.5 at 60o and cooled to 20o has [] 20D +56o(0minutes), +53.5o(2hours), +19o(3days), -2o(5days) and -6o(6days); then it becomes orange in colour. A freshly prepared 1% solution in H2O has [] D +50o(0minutes), +44o(2hours), +16o(3days) and 0o(5days). [Herbert et al. J Chem Soc 1270 1933, Kenyon et al. J Chem Soc 158 1948, Beilstein 18/5 V 411.]

DEHYDROASCORBIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(5R)-5β-[(S)-1,2-Dihydroxyethyl]tetrahydrofuran-2,3,4-trione C05422 L-Dehydroascorbate L-threo-2,3-Hexodiulosonic Acid γ-Lactone Oxidized Ascorbic Acid L-ASCORBIC ACID OXIDIZED DEHYDROASCORBIC ACID DEHYDRO-L(+)-ASCORBIC ACID, DIMER BIS-DEHYDRO-L-ASCORBIC ACID OXIDIZED VITAMIN C L-(+)-Dehydroascorbic Acid (1.24728) L-threo-hexo-2,3-diulosono-1,4-lactone L-threo-2,3-Hexodiulosonic acid, .gamma.-lactone 5-(1,2-dihydroxyethyl)oxolane-2,3,4-trione DEHYDROASCORBIC ACID(RG) L-(+)-DEHYDROASCORBICACID Ascorbic Acid Impurity 18 (5R)-5-[(1S)-12-dihydroxyethyl]oxolane-234-trione L-threo-2,3-Hexodiulosonic acid, g-lactone (R)-5-((S)-1,2-dihydroxyethyl)furan-2,3,4(5H)-trione ehydroascorbicaci DEHYDROASCORBIC ACID USP/EP/BP TIANFUCHEM--High purity 490-83-5 DEHYDROASCORBIC ACID Dehydroascorbate DEHYDRO-L-ASCORBIC ACID BIS-DHA 13C6]-(L)-Dehydroascorbic acid 490-83-5 C8H10O6 Specialty Synthesis Monosaccharides Carbohydrate Synthesis KETONE Carbohydrates & Derivatives Intermediates & Fine Chemicals Pharmaceuticals Carbohydrate Synthesis Monosaccharides Specialty Synthesis