(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Structure
CAS No.
132873-57-5
Chemical Name:
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
Synonyms
(S)-NITRESOLVE;(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL;(S)-alpha-methyl-4-nitrobenzenemethanamine;(S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL;(S)-α-Methyl-4-nitrobenzylamineHydrochloride;(S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE;1-(S)-4-Nitrophenyl ethylamine hydrochloride;(S)-4-Nitro-α-methylbenzylamine hydrochloride;(S)-1-(4-Nitrophenyl)ethanaMine hydrochloride;(S)-α-Methyl-4-nitrobenzylamine Hydrochloride
CBNumber:
CB1467176
Molecular Formula:
C8H11ClN2O2
Molecular Weight:
202.64
MOL File:
132873-57-5.mol
MSDS File:
SDS
Modify Date:
2023/6/8 17:06:36

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Properties

Melting point 248-250 °C(lit.)
refractive index -7.2 ° (C=1, 0.05mol/L NaOH)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
color White to Light yellow
optical activity [α]25/D 6.5°, c = 1 in 0.05 M NaOH
Water Solubility faint turbidity
CAS DataBase Reference 132873-57-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
3-10
HS Code  29214990
NFPA 704
0
2 0

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 339822 (S)-α-Methyl-4-nitrobenzylamine hydrochloride 97% 132873-57-5 1G ₹4416.6 2022-06-14 Buy
TCI Chemicals (India) N0543 (S)-α-Methyl-4-nitrobenzylamine Hydrochloride 132873-57-5 1G ₹4300 2022-05-26 Buy
Product number Packaging Price Buy
339822 1G ₹4416.6 Buy
N0543 1G ₹4300 Buy

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Chemical Properties,Uses,Production

Uses

(S)-α-Methyl-4-nitrobenzylamine hydrochloride can be used as:

  • A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.
  • A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.

Purification Methods

To ensure dryness, the hydrochloride (ca 175 g) is extracted with EtOH (3x100mL) and evaporated to dryness (any residual H2O increases the solubility in EtOH and lowers the yield). The hydrochloride residue is triturated with absolute EtOH and dried in vacuo. The product is further purified by refluxing with absolute EtOH (200 mL for 83g) for 1hour, and cool to 10o to give 76.6g of hydrochloride m 243-245o(dec). The free base is prepared by dissolving in N NaOH, extracting with CH2Cl2 (3 x 500mL), drying (Na2CO3), filtering, evaporating and distilling it. It has m 27o, b 119-120o/0.5mm (105-107o/0.5mm, 157-159o/9mm, d 1.1764, n 1.5688, [] ±17.7o (neat) [Perry et al. Synthesis 492 1977,ORD: Nerdel & Liebig Justus Liebigs Ann Chem 621 142 1959]. [Beilstein 12 IV 2451.]

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Suppliers

Global( 127)Suppliers
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(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL (S)-1-(4-NITROPHENYL)-METHYLAMIN HYDROCHLORIDE (S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE (S)-NITRESOLVE (S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE (S)-ALPHA-METHYL-4-NITROBENZYLAMMONIUM CHLORIDE (S)-(+)-ALPHA-METHYL-P-NITROBENZYLAMINE HYDROCHLORIDE (S)-(-)-A-METHYL 4-NITROBENZYLAMINE HYDROCHLORIDE (S)-α-Methyl-4-nitrobenzylamineHydrochloride (S)-4-Nitro-α-methylbenzylamine hydrochloride (S)-(+)-α-Methyl-p-nitrobenzylamine Hydrochloride (S)-alpha-methyl-4-nitrobenzenemethanamine (s)-alpha-Methyl-4-nitroitrobenzylaMine Hydrochloride (S)-1-(4-Nitrophenyl)ethanaMine hydrochloride (S)-Nitresolve (S)-1-(4-Nitrophenyl)ethylamine Hydrochloride (S)-alpha-Methyl-4-nitrobenzeneMethanaMine HCL (S)-alpha-Methyl-4-nitrobenzylamine hydrochloride 97% (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 99+% 1-(S)-4-Nitrophenyl ethylamine hydrochloride (S)-α-Methyl-4-nitrobenzylamineHydrochloride> Benzenemethanamine, α-methyl-4-nitro-, hydrochloride (1:1), (αS)- (S)-α-Methyl-4-nitrobenzylamine Hydrochloride 132873-57-5 O2NC6H4CHCH3NH2HCl Asymmetric Synthesis Chiral Resolution Reagents Optical Resolution for Resolution of Acids Chiral Resolving Reagents chiral for Resolution of Acids Optical Resolution Synthetic Organic Chemistry 1