(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
- CAS No.
- 132873-57-5
- Chemical Name:
- (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
- Synonyms
- (S)-NITRESOLVE;(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL;(S)-alpha-methyl-4-nitrobenzenemethanamine;(S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL;(S)-α-Methyl-4-nitrobenzylamineHydrochloride;(S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE;1-(S)-4-Nitrophenyl ethylamine hydrochloride;(S)-4-Nitro-α-methylbenzylamine hydrochloride;(S)-1-(4-Nitrophenyl)ethanaMine hydrochloride;(S)-α-Methyl-4-nitrobenzylamine Hydrochloride
- CBNumber:
- CB1467176
- Molecular Formula:
- C8H11ClN2O2
- Molecular Weight:
- 202.64
- MOL File:
- 132873-57-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/6/8 17:06:36
Melting point | 248-250 °C(lit.) |
---|---|
refractive index | -7.2 ° (C=1, 0.05mol/L NaOH) |
storage temp. | Inert atmosphere,Room Temperature |
form | powder to crystal |
color | White to Light yellow |
optical activity | [α]25/D 6.5°, c = 1 in 0.05 M NaOH |
Water Solubility | faint turbidity |
CAS DataBase Reference | 132873-57-5(CAS DataBase Reference) |
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE price More Price(2)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 339822 | (S)-α-Methyl-4-nitrobenzylamine hydrochloride 97% | 132873-57-5 | 1G | ₹4416.6 | 2022-06-14 | Buy |
TCI Chemicals (India) | N0543 | (S)-α-Methyl-4-nitrobenzylamine Hydrochloride | 132873-57-5 | 1G | ₹4300 | 2022-05-26 | Buy |
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Chemical Properties,Uses,Production
Uses
(S)-α-Methyl-4-nitrobenzylamine hydrochloride can be used as:
- A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.
- A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.
Purification Methods
To ensure dryness, the hydrochloride (ca 175 g) is extracted with EtOH (3x100mL) and evaporated to dryness (any residual H2O increases the solubility in EtOH and lowers the yield). The hydrochloride residue is triturated with absolute EtOH and dried in vacuo. The product is further purified by refluxing with absolute EtOH (200 mL for 83g) for 1hour, and cool to 10o to give 76.6g of hydrochloride m 243-245o(dec). The free base is prepared by dissolving in N NaOH, extracting with CH2Cl2 (3 x 500mL), drying (Na2CO3), filtering, evaporating and distilling it. It has m 27o, b 119-120o/0.5mm (105-107o/0.5mm, 157-159o/9mm, d 1.1764, n 1.5688, [] ±17.7o (neat) [Perry et al. Synthesis 492 1977,ORD: Nerdel & Liebig Justus Liebigs Ann Chem 621 142 1959]. [Beilstein 12 IV 2451.]
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Suppliers
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
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A.J Chemicals | 91-9810153283 | New Delhi, India | 6100 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
Souvenier Chemicals | 08048372762Ext 645 | Mumbai, India | 396 | 58 | Inquiry |
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CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49374 | 58 | Inquiry |
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LEAP CHEM CO., LTD. | +86-852-30606658 | China | 24727 | 58 | Inquiry |
Golden Pharma Co., Limited | +undefined18958062155 | China | 5899 | 58 | Inquiry |
Aladdin Scientific | +1-+1(833)-552-7181 | United States | 57505 | 58 | Inquiry |
Supplier | Advantage |
---|---|
A.J Chemicals | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Souvenier Chemicals | 58 |
Shenzhen Nexconn Pharmatechs Ltd | 58 |
CONIER CHEM AND PHARMA LIMITED | 58 |
career henan chemical co | 58 |
Labnetwork lnc. | 58 |
LEAP CHEM CO., LTD. | 58 |
Golden Pharma Co., Limited | 58 |
Aladdin Scientific | 58 |