3,3',4,4'-Biphenyltetracarboxylic dianhydride
- CAS No.
- 2420-87-3
- Chemical Name:
- 3,3',4,4'-Biphenyltetracarboxylic dianhydride
- Synonyms
- BPDA;S-BPDA;Biphthalicanhydride;S-BDPA;4,4'-Biphthalic anhydrid;4,4'-BIPHTHALIC ANHYDRIDE;4,4'-Biphthalic anhydride;4,4'-biphthalic dianhydride;4,4'-Biphthalic Anhydride >4,4'-biphthalic anhydride ,99%
- CBNumber:
- CB1763438
- Molecular Formula:
- C16H6O6
- Molecular Weight:
- 294.22
- MOL File:
- 2420-87-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/24 15:38:36
| Melting point | 299-305 °C (lit.) |
|---|---|
| Boiling point | 614.9±48.0 °C(Predicted) |
| Density | 1.625±0.06 g/cm3(Predicted) |
| vapor pressure | 0Pa at 20℃ |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | almost transparency in hot DMF |
| form | powder to crystal |
| color | Off-white |
| λmax | 300nm(lit.) |
| InChI | InChI=1S/C16H6O6/c17-13-9-3-1-7(5-11(9)15(19)21-13)8-2-4-10-12(6-8)16(20)22-14(10)18/h1-6H |
| InChIKey | WKDNYTOXBCRNPV-UHFFFAOYSA-N |
| SMILES | C1(=O)C2=C(C=C(C3C=CC4C(=O)OC(=O)C=4C=3)C=C2)C(=O)O1 |
| LogP | 3.91 |
| CAS DataBase Reference | 2420-87-3(CAS DataBase Reference) |
| NIST Chemistry Reference | 3,3',4,4'-Biphenyltetracarboxylic acid dianhydride(2420-87-3) |
| EPA Substance Registry System | [5,5'-Biisobenzofuran]-1,1',3,3'-tetrone (2420-87-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 29173990 | |||||||||
| NFPA 704 |
|
3,3',4,4'-Biphenyltetracarboxylic dianhydride price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 463310 | 3,3′,4,4′-Biphenyltetracarboxylic dianhydride 97% | 2420-87-3 | 25G | ₹4189.28 | 2022-06-14 | Buy |
| TCI Chemicals (India) | B1326 | 4,4'-Biphthalic Anhydride | 2420-87-3 | 25G | ₹5200 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B4262 | 4,4'-Biphthalic Anhydride (purified by sublimation) | 2420-87-3 | 5G | ₹8300 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B1326 | 4,4'-Biphthalic Anhydride | 2420-87-3 | 100G | ₹15500 | 2022-05-26 | Buy |
3,3',4,4'-Biphenyltetracarboxylic dianhydride Chemical Properties,Uses,Production
Chemical Properties
BPDA (3,3',4,4'-Biphenyltetracarboxylic dianhydride) is a raw material for the polyimide resin component of one of the super-engineering plastics. It is used for many important information and electronic technology products such as mobile phones and copying machines.
Uses
3,3',4,4'-biphenyltetracarboxylic dianhydride be used for the preparation of a polyimide material.
Preparation
The preparation of 3,3',4,4'-Biphenyltetracarboxylic dianhydride is as follows:In a nitrogen atmosphere, add N-(3-N,N-dimethylamino-propyl)-4-chlorophthalimide (26.65g, 0.1moL),Zinc powder (3.25g, 0.05moL), anhydrous NiCl2 (127.5mg, 1mmoL),Triphenylphosphine (250mg, 1mmoL) and 70 mL of anhydrous DMAc were stirred at 50°C for 24 hours, and 55mL of solvent DMAc was recovered under reduced pressure. Add 80g of xylene to the system and reflux (recrystallize), filter out the inorganic matter, the clarified filtrate will be cooled and precipitated, filtered, and vacuum dried for 10 hours. 21.8g of 3,3',4,4'-biphenylbisimine was obtained with a yield of 94%. In a 100mL reaction flask, add 4.62g (0.01mol) of the above 3,3',4,4'-biphenylbisimine and 9g of 20% sodium hydroxide aqueous solution, and heat to reflux for 24 hours. Filter and adjust pH=1 with concentrated hydrochloric acid to obtain 3,3’,4,4’-biphenyltetracarboxylic acid. After filtering, wash with water three times and reflux with water with 20mL trimethylbenzene.2.85g of white 3,3′,4,4′-biphenyltetracarboxylic dianhydride was obtained, the yield was 97%.
Application
3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) and 3,3′- and 4,4′-diaminodiphenylsulfones enable to prepare homo- and copolyimides. 3,3',4,4'-Biphenyltetracarboxylic dianhydride is commonly employed to synthesized the aromatic polyimide fibers which is one member of high performance fibers with high strength, high modulus, high and low temperature resistance, and radiation resistance. BPDA could be used to synthesize a series of hyper-cross-linked polymers (HPB-s) with waste polystyrene (WPS) foam. HPB-s has promising potential in purifying dye wastewater[1-2].
General Description
3,3′,4,4′-Biphenyltetracarboxylic dianhydride (s-BPDA) is a rigid symmetric polyamide with a diamine having a long distance between amine groups and reactive endgaps.
Advantages
1.Excellent thermal stability
2.Good chemical resistance
3.Stable mechanical properties
4.Polyimide does not require the addition of flame retardants to prevent combustion.
References
[1] Zhao M, et al. Porous Adsorbents Cross-Linked with Waste Polystyrene Foam and 3,3′,4,4′-Biphenyltetracarboxylic Acid Dianhydride for the Effective Removal and Enrichment of Cationic Dyes. ACS Applied Polymer Materials, 2023.
[2] Zhang Q, et al. Morphology of polyimide fibers derived from 3,3′,4,4′-biphenyltetracarboxylic dianhydride and 4,4′-oxydianiline. Journal of Applied Polymer Science, 2004; 93: 669-675.
3,3',4,4'-Biphenyltetracarboxylic dianhydride Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Supreet Chemicals Pvt., Ltd. | 91-9825404811 | Gujarat, India | 38 | 58 | Inquiry |
| Gharda Chemicals Limited | 08048372602Ext 584 | Maharashtra, India | 31 | 58 | Inquiry |
| Heynova (Shanghai) New Material Technology CO., Ltd | +86-17821320848; +8617821320848 | China | 431 | 58 | Inquiry |
| Chengdu Yuanda Chemical Co., Ltd | 28-85356300 +8618980937689 | CHINA | 94 | 58 | Inquiry |
| CHINATECH(TIANJIN) CHEMICAL CO.,LTD. | +86-18222265956 +86-18222270857 | China | 64 | 58 | Inquiry |
| Shijiazhuang Tongyang Import and Export Co., LTD | 18031361688; | China | 987 | 58 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16221 | 58 | Inquiry |
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