4,4'-Dichlorobenzophenone
- CAS No.
- 90-98-2
- Chemical Name:
- 4,4'-Dichlorobenzophenone
- Synonyms
- 4'-DBP;usafdo-4;4,4'-DBP;4,4'-DCBP;USAF do-4;AKOS 94189;4,4'-DichL;DCBP Standard;4.4'-Dichlorob;4,4'-Dichlorobenzoph
- CBNumber:
- CB2120403
- Molecular Formula:
- C13H8Cl2O
- Molecular Weight:
- 251.11
- MOL File:
- 90-98-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/9/26 18:30:47
Melting point | 144-146 °C (lit.) |
---|---|
Boiling point | 353 °C (lit.) |
Density | 1,45 g/cm3 |
refractive index | 1.5555 (estimate) |
Flash point | 352-354°C |
storage temp. | Sealed in dry,Room Temperature |
solubility | Soluble in hot acetone. |
form | powder to crystal |
color | White to Light yellow |
BRN | 643345 |
Stability | Stable. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 90-98-2(CAS DataBase Reference) |
NIST Chemistry Reference | p-Dichlorobenzophenone(90-98-2) |
EPA Substance Registry System | Methanone, bis(4-chlorophenyl)- (90-98-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 22-24/25-36-26 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | DJ0525000 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | Yes | |||||||||
HS Code | 29147000 | |||||||||
NFPA 704 |
|
4,4'-Dichlorobenzophenone price More Price(7)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 113700 | 4,4′-Dichlorobenzophenone 99% | 90-98-2 | 25G | ₹1948.5 | 2022-06-14 | Buy |
TCI Chemicals (India) | D1621 | 4,4'-Dichlorobenzophenone min. 99.0 % | 90-98-2 | 25G | ₹1800 | 2022-05-26 | Buy |
TCI Chemicals (India) | D1621 | 4,4'-Dichlorobenzophenone min. 99.0 % | 90-98-2 | 100G | ₹4600 | 2022-05-26 | Buy |
TCI Chemicals (India) | D1621 | 4,4'-Dichlorobenzophenone min. 99.0 % | 90-98-2 | 500G | ₹17900 | 2022-05-26 | Buy |
ottokemi | D 1510 | 4,4'-Dichlorobenzophenone 98% | 90-98-2 | 25gm | ₹1341 | 2022-05-26 | Buy |
4,4'-Dichlorobenzophenone Chemical Properties,Uses,Production
Chemical Properties
faintly yellow crystalline powder
Uses
4,4'-Dichlorobenzophenone is used as pharmaceutical intermediates. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and dyestuffs. Bisaminonitrile was polymerized with 4,4'-dichlorobenzophenone using NaH as base.
Application
4,4'-Dichlorobenzophenone can be used to synthesize polyether-polyketones, as well as reduce polymer costs. Furthermore, it is a metabolic product resulting from the degredation of DDT.
Preparation
4,4'-Dichlorobenzophenone is prepared by the acylation of chlorobenzene with 4-chlorobenzoyl chloride. The conversion is typically conducted in the presence of an aluminium chloride catalyst in a petroleum ether solvent.
ClC6H5C(O)Cl + C6H5Cl → (ClC6H4)2CO + HCl
General Description
4,4′-Dichlorobenzophenone (DBP) is a metabolite obtained when one strain of ectomycorrhizal fungi, Xerocomus chrysenteron, degrades 1,1,1-trichloro-2,2-bis(4-chlorophe-nyl) ethane (DDT).
Purification Methods
Recrystallise it from EtOH [Wagner et al. J Am Chem Soc 108 7727 1986]. The semicarbazone has m 192-193o (from H2O). [Beilstein 7 H 420, 7 I 228, 7 II 359, 7 III 2076, 7 IV 1376.]
4,4'-Dichlorobenzophenone Preparation Products And Raw materials
Raw materials
Preparation Products
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GLR Innovations | 58 |
HYPERSYNTH LIFE SCIENCES | 58 |
ALTRAKEM PHARMA LIFE SCIENCES PRIVATE LIMITED | 58 |
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Freesia Chemicals | 58 |
JSK Chemicals | 58 |
Pratap Organics Pvt Ltd | 58 |
Dr Chindepalli | 58 |
Krystal Tech | 58 |
Unisource Chemicals Private Limited | 58 |
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