ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Aromatic ketones >4,4'-Dichlorobenzophenone

4,4'-Dichlorobenzophenone

4,4'-Dichlorobenzophenone Structure
CAS No.
90-98-2
Chemical Name:
4,4'-Dichlorobenzophenone
Synonyms
4'-DBP;usafdo-4;4,4'-DBP;4,4'-DCBP;USAF do-4;AKOS 94189;4,4'-DichL;DCBP Standard;4.4'-Dichlorob;4,4'-Dichlorobenzoph
CBNumber:
CB2120403
Molecular Formula:
C13H8Cl2O
Molecular Weight:
251.11
MOL File:
90-98-2.mol
MSDS File:
SDS
Modify Date:
2024/9/26 18:30:47

4,4'-Dichlorobenzophenone Properties

Melting point 144-146 °C (lit.)
Boiling point 353 °C (lit.)
Density 1,45 g/cm3
refractive index 1.5555 (estimate)
Flash point 352-354°C
storage temp. Sealed in dry,Room Temperature
solubility Soluble in hot acetone.
form powder to crystal
color White to Light yellow
BRN 643345
Stability Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 90-98-2(CAS DataBase Reference)
NIST Chemistry Reference p-Dichlorobenzophenone(90-98-2)
EPA Substance Registry System Methanone, bis(4-chlorophenyl)- (90-98-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-36-26
WGK Germany  3
RTECS  DJ0525000
Hazard Note  Irritant
TSCA  Yes
HS Code  29147000
NFPA 704
1
2 0

4,4'-Dichlorobenzophenone price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 113700 4,4′-Dichlorobenzophenone 99% 90-98-2 25G ₹1948.5 2022-06-14 Buy
TCI Chemicals (India) D1621 4,4'-Dichlorobenzophenone min. 99.0 % 90-98-2 25G ₹1800 2022-05-26 Buy
TCI Chemicals (India) D1621 4,4'-Dichlorobenzophenone min. 99.0 % 90-98-2 100G ₹4600 2022-05-26 Buy
TCI Chemicals (India) D1621 4,4'-Dichlorobenzophenone min. 99.0 % 90-98-2 500G ₹17900 2022-05-26 Buy
ottokemi D 1510 4,4'-Dichlorobenzophenone 98% 90-98-2 25gm ₹1341 2022-05-26 Buy
Product number Packaging Price Buy
113700 25G ₹1948.5 Buy
D1621 25G ₹1800 Buy
D1621 100G ₹4600 Buy
D1621 500G ₹17900 Buy
D 1510 25gm ₹1341 Buy

4,4'-Dichlorobenzophenone Chemical Properties,Uses,Production

Chemical Properties

faintly yellow crystalline powder

Uses

4,4'-Dichlorobenzophenone is used as pharmaceutical intermediates. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and dyestuffs. Bisaminonitrile was polymerized with 4,4'-dichlorobenzophenone using NaH as base.

Application

4,4'-Dichlorobenzophenone can be used to synthesize polyether-polyketones, as well as reduce polymer costs. Furthermore, it is a metabolic product resulting from the degredation of DDT.

Preparation

4,4'-Dichlorobenzophenone is prepared by the acylation of chlorobenzene with 4-chlorobenzoyl chloride. The conversion is typically conducted in the presence of an aluminium chloride catalyst in a petroleum ether solvent.
ClC6H5C(O)Cl + C6H5Cl → (ClC6H4)2CO + HCl

General Description

4,4′-Dichlorobenzophenone (DBP) is a metabolite obtained when one strain of ectomycorrhizal fungi, Xerocomus chrysenteron, degrades 1,1,1-trichloro-2,2-bis(4-chlorophe-nyl) ethane (DDT).

Purification Methods

Recrystallise it from EtOH [Wagner et al. J Am Chem Soc 108 7727 1986]. The semicarbazone has m 192-193o (from H2O). [Beilstein 7 H 420, 7 I 228, 7 II 359, 7 III 2076, 7 IV 1376.]

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Benzophenone, 4,4'-dichloro- benzophenone,4,4’-dichloro- p-p#-Dichlorbenzophenon USAF do-4 usafdo-4 BIS(4-CHLOROPHENYL) KETONE BIS-(4-CHLORO-PHENYL)-METHANONE 4,4'-DBP 4,4'-DCBP p-dichlorobenzophenone 4,4’-bis(p-Chlorophenyl)ketone 4,4’-dichloro-benzophenon 4,4’-dichlorodiphenylketone 4,4'-DICHLOROBENZOPHENONE, 100MG, NEAT 4,4'-DBP, PESTANAL (4,4'-DICHLORO- BENZO 4,4-Dichlorobenzophenone99% AKOS 94189 4,4μ-DBP, 4,4μ-Dichlorobenzophenone (4,4-dichloro-1-cyclohexa-1,5-dienyl)-phenylmethanone 4,4'-Dichlorobenzophenone 4.4'-Dichlorob 4.4'-Dichlorobenzophenone 100mg [90-98-2] 4,4′-Dichlorobenzophenone,4,4′-DBP 4,4'-Dichlorobenzoph 4'-DBP 4,4'-Dichlorobenzophenone 10 μg/mL in Cyclohexane bis(4-chlorophenyl)-methanon bis(p-chlorophenyl)ketone dbp(degradationproduct) di(4-chlorophenyl)ketone Di(p-Chlorophenyl)ketone Methanone, bis(4-chlorophenyl)- methanone,bis(4-chlorophenyl)- p,p’-dichlorobenzophenone p,p'-Dichlorobenzophenone p,p-Dichlorobenzophenone 4,4'-Dichlorbenzophenon DCBP Standard 4,4'-Dichlorobenzophenone @100 μg/mL in MeOH 4,4'-Dichlorobenzophenone @1000 μg/mL in MeOH 4,4'-Dichlorobenzophenone > 4,4'-DichL 4,4’-Dichlorobenzophenone Solution in Methanol, 100μg/mL 4,4'-Dicholorobenzophenone 2,6-Dichloro-8-fluoropyridin Cetirizine Impurity 89 4,4'-Dichlorobenzophenone 90-98-2 C13Cl2H8O1 C19H15AlCl2O ClC6H42CO Benzophenones (for High-Performance Polymer Research) Photopolymerization Initiators Reagent for High-Performance Polymer Research Building Blocks C13 to C14 Carbonyl Compounds Organic Building Blocks