(R)-(-)-HEXAHYDROMANDELIC ACID

(R)-(-)-HEXAHYDROMANDELIC ACID Structure
CAS No.
53585-93-6
Chemical Name:
(R)-(-)-HEXAHYDROMANDELIC ACID
Synonyms
hexahydromandelic acid;Cyclohexylglycolic acid;D-HEXAHYDROMANDELIC ACID;2-CYCLOHEXYLGLYCOLIC ACID;(R)-(-)-HEXAHYDROMANDELIC ACID;CYCLOHEXYL-HYDROXY-ACETIC ACID;R(-)-CYCLOHEXYLHYDROXYACETIC ACID;(R)-(-)-HEXAHYDROMANDELICACID[095H];ALPHA-HYDROXYCYCLOHEXANE-ACETIC ACID;(αR)-α-Hydroxycyclohexaneacetic acid
CBNumber:
CB2162494
Molecular Formula:
C8H14O3
Molecular Weight:
158.2
MOL File:
53585-93-6.mol
MSDS File:
SDS
Modify Date:
2022/11/11 11:01:00

(R)-(-)-HEXAHYDROMANDELIC ACID Properties

Melting point 127-129 °C (lit.)
Boiling point 319.3±15.0 °C(Predicted)
Density 1.178±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka 3.86±0.11(Predicted)
optical activity [α]18/D 23°, c = 1 in acetic acid
BRN 3196809

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Safety Statements  22-24/25
WGK Germany  3

(R)-(-)-HEXAHYDROMANDELIC ACID price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 301140 (R)-(−)-Hexahydromandelic acid 98%, optical purity ee: 99% (GLC) 53585-93-6 1G ₹6278.5 2022-06-14 Buy
Product number Packaging Price Buy
301140 1G ₹6278.5 Buy

(R)-(-)-HEXAHYDROMANDELIC ACID Chemical Properties,Uses,Production

Uses

(R)-(?)-Hexahydromandelic acid can be used:

  • As an intermediate in the synthesis of antimycobacterial compound pyridomycin analogs.
  • As a model α-hydroxy acid compound in the chirality sensing studies of organic probes using circular dichroism technique.
  • As a starting material in the synthesis of chiral ionic liquids, which are applicable as chiral solvents in asymmetric synthesis and as chiral stationary phases in chromatographic separations.

Purification Methods

It forms hexagonal clusters on recrystallisation from CCl4 or Et2O. [Wood & Comley J Chem Soc 2638 1924, Lettré et al. Chem Ber 69 1594 1936]. The racemate has m 137.2-137.6o (134-135o) [Smith et al. J Am Chem Soc 71 3772 1949]. [Beilstein R-10 II 5; S-10 II 6.]

(R)-(-)-HEXAHYDROMANDELIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-HEXAHYDROMANDELIC ACID Suppliers

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(R)-(-)-HEXAHYDROMANDELIC ACID R(-)-CYCLOHEXYLHYDROXYACETIC ACID 2-CYCLOHEXYLGLYCOLIC ACID ALPHA-HYDROXYCYCLOHEXANE-ACETIC ACID CYCLOHEXYL-HYDROXY-ACETIC ACID D-HEXAHYDROMANDELIC ACID Cyclohexylglycolic acid hexahydromandelic acid (2R)-2-Hydroxy-2-cyclohexylacetic acid (αR)-α-Hydroxycyclohexaneacetic acid [R,(-)]-α-Hydroxycyclohexaneacetic acid 1,2,3,4,5,6-Hexahydro-D-mandelic acid (R)-2-cyclohexyl-2-hydroxyacetic acid (R)-(-)-HexahydroMandelic acid 98%, optical purity ee: 99% (GLC) (R)-(-)-HEXAHYDROMANDELICACID[095H] Cyclohexaneacetic acid, α-hydroxy-, (αR)- 53585-93-6 C6H11CHOHCO2H Asymmetric Synthesis Carboxylic Acids Chiral Building Blocks Organic Building Blocks