3-(Aminomethyl)pyridine
- CAS No.
- 3731-52-0
- Chemical Name:
- 3-(Aminomethyl)pyridine
- Synonyms
- pyridin-3-ylmethanamine;Picolamine;3AMPY;NSC 59706;Picolamin;-Aminomethyl;3-PICOLYLAMINE;AKOS BBS-00003679;3-Picolylamine>TIMTEC-BB SBB004351
- CBNumber:
- CB2284635
- Molecular Formula:
- C6H8N2
- Molecular Weight:
- 108.14
- MOL File:
- 3731-52-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/8 9:11:11
| Melting point | −21 °C(lit.) |
|---|---|
| Boiling point | 73-74 °C1 mm Hg(lit.) |
| Density | 1.062 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 213 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | soluble in Chloroform, Ethyl Acetate, Methanol |
| form | clear liquid |
| pka | 8.34±0.29(Predicted) |
| color | Colorless to Light yellow |
| PH | 11-12 (100g/l, H2O, 20℃) |
| Water Solubility | FREELY SOLUBLE |
| Sensitive | Air Sensitive |
| BRN | 108056 |
| CAS DataBase Reference | 3731-52-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Picolamine(3731-52-0) |
| EPA Substance Registry System | 3-Pyridinemethanamine (3731-52-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H290-H314 | |||||||||
| Precautionary statements | P234-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34-37-36/37/38 | |||||||||
| Safety Statements | 26-36/37/39-45-25-36 | |||||||||
| RIDADR | UN 2735 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29333999 | |||||||||
| NFPA 704 |
|
3-(Aminomethyl)pyridine price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | A65409 | 3-Picolylamine ≥99% | 3731-52-0 | 5G | ₹2121.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | A65409 | 3-Picolylamine ≥99% | 3731-52-0 | 100G | ₹5087.75 | 2022-06-14 | Buy |
| TCI Chemicals (India) | P0762 | 3-Picolylamine min. 99.0 % | 3731-52-0 | 25ML | ₹2500 | 2022-05-26 | Buy |
| TCI Chemicals (India) | P0762 | 3-Picolylamine min. 99.0 % | 3731-52-0 | 100ML | ₹4100 | 2022-05-26 | Buy |
| TCI Chemicals (India) | P0762 | 3-Picolylamine min. 99.0 % | 3731-52-0 | 500ML | ₹10100 | 2022-05-26 | Buy |
3-(Aminomethyl)pyridine Chemical Properties,Uses,Production
Chemical Properties
CLEAR COLOURLESS TO SLIGHLY YELLOW LIQUID
Application
3-(Aminomethyl)pyridine can be used to prepare metal complexes. A number of complexes of cobalt(II), nickel(II) and copper(II) thiocyanates, chlorides and bromides with 3-pyridine amine were prepared and the stereochemical configurations of these complexes were deduced using spectroscopy and magnetism, and the decomposition of the complexes was studied by thermogravimetry and differential thermal analysis[2].
Synthesis
Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?. A natural product inspired rapid access of 3-(aminomethyl)pyridine by one-pot reaction of 1-amidopyridin-1-ium salt with aminal followed by reductive cleavage of the N–N bond is developed. This C3-selective formal C–H activation of pyridine features a traceless umpolung of the 1-amidopyridin-1-ium salt toward a Mannich type C–C bond formation of the in situ generated 1-amido-2-dialkylamino-1,2-dihydropyridine intermediate[1].
References
[1] TANG P, XIAO D, WANG B. Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?[J]. Chemical Communications, 2017. DOI:10.1039/C6CC09582H.
[2] J. R. ALLAN M. J P A D Paton. The preparation, characterisation and thermal analysis studies on complexes of cobalt(II), nickel(II), and copper(II) with 3-picolylamine[J]. Journal of Thermal Analysis and Calorimetry, 1985. DOI:10.1007/BF01913603.
3-(Aminomethyl)pyridine Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
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| Terma Medicare India Pvt.,Ltd | 58 |
| ALS INDIA LIFE SCIENCES | 58 |
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| Jubilant Ingrevia | 58 |
| Vardhaman P Golechha | 58 |
| HiMedia Laboratories | 58 |
| Alkali Metals Ltd. | 58 |
| ASM Organics | 58 |