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2-Methylthiophene

2-Methylthiophene Structure
CAS No.
554-14-3
Chemical Name:
2-Methylthiophene
Synonyms
Thiophene, 2-methyl-;methylthiol;2-Methylthiophene CAS NO.554-14-3;2-methylthiacyclopentadiene (2-methylthiophene);2MT;2-thiotolene;α-Thiotolene;5-Methylthiophene;2-METHYLTHIOPHENE;2-methyl-thiophen
CBNumber:
CB2386865
Molecular Formula:
C5H6S
Molecular Weight:
98.17
MOL File:
554-14-3.mol
MSDS File:
SDS
Modify Date:
2024/7/18 5:12:15

2-Methylthiophene Properties

Melting point -63 °C (lit.)
Boiling point 113 °C (lit.)
Density 1.014 g/mL at 25 °C (lit.)
vapor pressure 47.6 mm Hg ( 37.7 °C)
refractive index n20/D 1.52(lit.)
Flash point 45 °F
storage temp. 2-8°C
solubility immiscible
form Liquid
Specific Gravity 1.025 (20℃)
color Clear colorless to yellow
Odor at 0.01 % in propylene glycol. sulfurous alliaceous onion roasted green
Odor Type sulfurous
Water Solubility immiscible
BRN 103734
InChIKey XQQBUAPQHNYYRS-UHFFFAOYSA-N
LogP 2.330
CAS DataBase Reference 554-14-3(CAS DataBase Reference)
NIST Chemistry Reference Thiophene, 2-methyl-(554-14-3)
EPA Substance Registry System Thiophene, 2-methyl- (554-14-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210-P370+P378-P403+P235
Hazard Codes  F,Xn,Xi
Risk Statements  11-22-36/37/38-37-2017/11/22
Safety Statements  16-37/39-26-36-33-7/9
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  XM9625000
10-13
TSCA  T
HazardClass  3
PackingGroup  II
HS Code  29349990
NFPA 704
3
2 1

2-Methylthiophene price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) M84208 2-Methylthiophene 98% 554-14-3 25G ₹2500.58 2022-06-14 Buy
Sigma-Aldrich(India) M84208 2-Methylthiophene 98% 554-14-3 100G ₹7415.13 2022-06-14 Buy
Sigma-Aldrich(India) 80364 2-Methylthiophene certified reference material, TraceCERT? 554-14-3 100MG ₹12264.73 2022-06-14 Buy
Sigma-Aldrich(India) 78833 2-Methylthiophene analytical standard 554-14-3 1ML ₹7339.35 2022-06-14 Buy
TCI Chemicals (India) M0635 2-Methylthiophene min. 97.0 % 554-14-3 25ML ₹3900 2022-05-26 Buy
Product number Packaging Price Buy
M84208 25G ₹2500.58 Buy
M84208 100G ₹7415.13 Buy
80364 100MG ₹12264.73 Buy
78833 1ML ₹7339.35 Buy
M0635 25ML ₹3900 Buy

2-Methylthiophene Chemical Properties,Uses,Production

Chemical Properties

clear colorless to slightly yellow liquid

Uses

2-Methylthiophene, is used as a flavoring agent that naturally occurs in grilled and roasted beef, papaya, cooked shrimp, whiskey, and in trace amounts in roasted chicken;

Production Methods

2-Methylthiophene is commercially produced to 98 wt% purity by VP cyclization.

Application

2-Methylthiophene is a feasible raw material for the production of several of the important 2-substituted thiophenes. It may be used to manufacture 2-chloromethylthiophene (2-thenyl chloride), but this and further syntheses must be completed in situ, because of its instability.

Synthesis Reference(s)

The Journal of Organic Chemistry, 14, p. 638, 1949 DOI: 10.1021/jo01156a016
Tetrahedron Letters, 22, p. 2443, 1981 DOI: 10.1016/S0040-4039(01)92928-4

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