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7-OCTEN-2-OL, 2-METHYL-6-METHYLENE

7-OCTEN-2-OL, 2-METHYL-6-METHYLENE Structure
CAS No.
543-39-5
Chemical Name:
7-OCTEN-2-OL, 2-METHYL-6-METHYLENE
Synonyms
MYCENOL5;MYRCENOL;MYRCENOL 50;2H MYRCENOL;MYRCENOL 50 IN D.E.P.;2-Methyl-6-methylenoct-7-en-2-ol;2-methyl-6-methylene-7-octen-2-o;2-methyl-6-methyleneoct-7-en-2-ol;3-Methylene-7-methyl-1-octen-7-ol;2-Methyl-6-methylene-7-octen-2-ol
CBNumber:
CB2697190
Molecular Formula:
C10H18O
Molecular Weight:
154.25
MOL File:
543-39-5.mol
MSDS File:
SDS
Modify Date:
2024/6/27 18:05:36

7-OCTEN-2-OL, 2-METHYL-6-METHYLENE Properties

Boiling point 217.64°C (rough estimate)
Density 0.8389 (rough estimate)
refractive index 1.4666 (estimate)
solubility Practically insoluble in water, soluble in alcohol and oils.
form viscous liquid
pka 15.30±0.29(Predicted)
color Colorless
Specific Gravity 0.89
Odor at 100.00 %. fresh floral lavender citrus
Odor Type floral
Stability Tends to polymerize on standing, increases in viscosity, decreases in odor power
LogP 2.613 (est)
EPA Substance Registry System 7-Octen-2-ol, 2-methyl-6-methylene- (543-39-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362

7-OCTEN-2-OL, 2-METHYL-6-METHYLENE Chemical Properties,Uses,Production

Chemical Properties

It is a colorless liquid with a fresh, floral, slightly lime-like odor. Due to its conjugated double bonds, it tends to polymerize; polymerization can be suppressed by adding inhibitors (e.g., antioxidants such as BHT).
Myrcenol can be prepared by treating myrcene with diethylamine to give a mixture of geranyl- and neryldiethylamine. These compounds are hydrated with a dilute acid to the corresponding hydroxydiethylamines. Deamination tomyrcenol is effected by using a palladium–phosphine–cation complex as a catalyst.
Myrcenol is used in perfumery to obtain a lifting top note in citrus and lavender compositions. It is mainly important in the production of 4-(4-hydroxy-4- methylpentyl)-3-cyclohexenecarboxaldehyde.

Uses

Myrcenol is used in perfume compositions for “lift” and freshness in floral or citrusy and “light” compositions, including soap perfumes.

Definition

ChEBI: A monoterpenoid that is oct-7-en-2-ol substituted by a methyl group at position 2 and a methylidene group at position 6 respectively.

Preparation

By chlorination of Myrcene, followed by hydrolysis.

7-OCTEN-2-OL, 2-METHYL-6-METHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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MYRCENOL 50 2-methyl-6-methylene-7-octen-2-o 2-Methyl-6-methylene-7-octen-2-ol 3-Methylene-7-methyl-1-octen-7-ol 2-methyl-6-methyleneoct-7-en-2-ol MYCENOL5 2-Methyl-6-methylenoct-7-en-2-ol 2H MYRCENOL MYRCENOL 50 IN D.E.P. 2-methyl-6-methylidene-oct-7-en-2-ol 2-methyl-6-methylideneoct-7-en-2-ol 7-OCTEN-2-OL, 2-METHYL-6-METHYLENE MYRCENOL 543-39-5 534-39-5