Myrcene
- CAS No.
- 123-35-3
- Chemical Name:
- Myrcene
- Synonyms
- β-myrcene;BETA-MYRCENE;OIL;b-Myrcene;7-METHYL-3-METHYLENE-1,6-OCTADIENE;7-methyl-3-methyleneocta-1,6-diene;Geraniolene;Myrcene CAS;MYRCENE;7-methyl-
- CBNumber:
- CB0135735
- Molecular Formula:
- C10H16
- Molecular Weight:
- 136.23
- MOL File:
- 123-35-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/14 12:24:17
| Melting point | <-10 °C |
|---|---|
| Boiling point | 167 °C (lit.) |
| Density | 0.791 g/mL at 25 °C (lit.) |
| vapor density | 4.7 (vs air) |
| vapor pressure | ~7 mm Hg ( 20 °C) |
| refractive index |
n |
| FEMA | 2762 | MYRCENE |
| Flash point | 103 °F |
| storage temp. | 2-8°C |
| solubility | water: soluble0.00109g/L at 20°C |
| form | Viscous Liquid |
| color | Clear light yellow |
| PH | 7 (H2O, 20℃)(saturated aqueous solution) |
| Odor | at 5.00 % in dipropylene glycol. peppery terpene spicy balsam plastic |
| Odor Type | spicy |
| Water Solubility | practically insoluble |
| Merck | 14,6331 |
| JECFA Number | 1327 |
| BRN | 1719990 |
| Dielectric constant | 2.0（Ambient） |
| Stability | Unstable - may be inhibited by the addition of ca. 400 ppm tenox GT-1 or 1000 ppm BHT. Flammable. Incompatible with strong oxidizing agents, radical initiators. |
| LogP | 4.82 at 30℃ |
| CAS DataBase Reference | 123-35-3(CAS DataBase Reference) |
| IARC | 2B (Vol. 119) 2019 |
| NIST Chemistry Reference | Beta-myrcene(123-35-3) |
| EPA Substance Registry System | Myrcene (123-35-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319-H410 | |||||||||
| Precautionary statements | P210-P233-P240-P273-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 10-36/37/38-R36/37/38-R10-65-38 | |||||||||
| Safety Statements | 16-26-36-37/39-S37/39-S26-S16-62 | |||||||||
| RIDADR | UN 2319 3/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | RG5365000 | |||||||||
| F | 10-23 | |||||||||
| HazardClass | 3.2 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29012990 | |||||||||
| Toxicity | Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1972). | |||||||||
| NFPA 704 |
|
Myrcene price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W276212 | Myrcene sum of isomers, ≥90%, natural, FG | 123-35-3 | 1SAMPLE-K | ₹4058.63 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W276212 | Myrcene sum of isomers, ≥90%, natural, FG | 123-35-3 | 100G | ₹7100.03 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W276200 | Myrcene stabilized, FCC, FG | 123-35-3 | 1SAMPLE-K | ₹4880.63 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W276212 | Myrcene sum of isomers, ≥90%, natural, FG | 123-35-3 | 1KG | ₹50727.68 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W276200 | Myrcene stabilized, FCC, FG | 123-35-3 | 1KG | ₹13645.2 | 2022-06-14 | Buy |
Myrcene Chemical Properties,Uses,Production
Description
Myrcene has a pleasant odor. Prepared from linalool.
Chemical Properties
Myrcene has a pleasant, sweet, balsamic, plastic odor.
Occurrence
Reported found in Mircia acris D.C.; in the distillates from leaves of Rhus cotinus and Barosma venustum (52 and 43%, respectively); in lemongrass, cypress, artemisia; in the fruits of Phellodendron amurense (92%) and Phellodendron japonicum; in the oils of Picea balsamea, Tsuga canadenis, Abies balsamea, clary sage and others. Also reported in over 200 foods and beverages including citrus peel oils and juices, apricot, sweet and sour cherry, berries, guava, pineapple, carrot, celery, potato, bell pepper, black currants, anise, anise seed, cardamom, cinnamon, cassia, clove, capsicum varities, ginger, mentha oils, mace, parsley, thyme, cheeses, cream, pork, hop oil, beer, white wine, rum, cocoa, coffee, tea, mango, tamarind, coriander, gin, sweet bay, prickly pear, calamus, dill, lovage, caraway, buckwheat, corn, basil, fennel, kiwifruit, rosemary, myrtle berry, turmeric, lemon balm, sage, pimento, angelica oil, Roman and German chamomile oil, eucalyptus and mastic gum oil
Uses
Myrcene is the suitable synthetic standard used in the identification of E-myrcenol (2-methyl-6-methylene-E-2,7-octadien-1-01) as a major hindgut constituent in Eurasian bark beetle Ips duplicatus by GC-MS.
Preparation
From linalool
Definition
ChEBI: A monoterpene that is octa-1,6-diene bearing methylene and methyl substituents at positions 3 and 7 respectively.
General Description
A yellow oily liquid with a pleasant odor. Flash point below 200°F. Insoluble in water and less dense than water.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
The unsaturated aliphatic hydrocarbons, such as MYRCENE, are generally much more reactive than the alkanes. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. In the presence of various catalysts (such as acids) or initiators, compounds in this class can undergo very exothermic addition polymerization reactions. Many of these compounds undergo autoxidation upon exposure to the air to form explosive peroxides. Violent explosions have occurred at low temperatures in ammonia synthesis gas units. These explosions have been traced to the addition products of dienes and oxides of nitrogen, produced from the interaction of nitrogen oxide and oxygen [Bretherick, 1995].
Health Hazard
May be harmful by inhalation, ingestion or skin absorption.
Fire Hazard
Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flashback.
Safety Profile
Low toxicity by ingestion and skin contact. Experimental reproductive effects. A moderate skin and eye irritant. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Synthesis
Myrcene occurs naturally in many organisms, but its extraction is uneconomic; it is produced industrially by pyrolysis of b-pinene. The fragmentation of linalool and linalyl acetate and the catalytic dimerization of isoprene have been described as laboratory synthesis methods of myrcene.
Myrcene Preparation Products And Raw materials
Raw materials
1of3
chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| LAURICE LABS | +91-9820672480 +91-9820672480 | Maharashtra, India | 40 | 58 | Inquiry |
| Aamirav Ingredients And Specialties Pvt Ltd | +91-2224980102 +91-9820077171 | Maharashtra, India | 138 | 58 | Inquiry |
| Arpan Aromatics | 08048372666Ext 828 | Ahmedabad, India | 138 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Jay Chem Marketing | 08048964412 | Mumbai, India | 231 | 58 | Inquiry |
| Aamirav Ingredients & Specialties Pvt. Ltd. | 91-22-24980102 | Maharashtra, India | 63 | 58 | Inquiry |
| Souvenier Chemicals | 08048372762Ext 645 | Mumbai, India | 396 | 58 | Inquiry |
| Nishant Aromas | +91 22 24710058 | Mumbai, India | 30 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Nishant Aromas Pvt Ltd | 91-22-288066333 | Maharashtra, India | 48 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| LAURICE LABS | 58 |
| Aamirav Ingredients And Specialties Pvt Ltd | 58 |
| Arpan Aromatics | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Jay Chem Marketing | 58 |
| Aamirav Ingredients & Specialties Pvt. Ltd. | 58 |
| Souvenier Chemicals | 58 |
| Nishant Aromas | 58 |
| Clearsynth Labs | 58 |
| Nishant Aromas Pvt Ltd | 58 |