POTASSIUM SELENOCYANATE
- CAS No.
- 3425-46-5
- Chemical Name:
- POTASSIUM SELENOCYANATE
- Synonyms
- CHNSe·K;enocyanate;Potassium seL;POTASSIUM SELENOCYAN;POTASSIUM SELENOCYANATE;potassiumselenoisocyanate;Potassium isoselenocyanate;Potassium selenocyanate,99%;Selenocyanic acid potassium;Monopotassium selenocyanate
- CBNumber:
- CB2745266
- Molecular Formula:
- CKNSe
- Molecular Weight:
- 144.08
- MOL File:
- 3425-46-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/1/17 11:32:08
| Melting point | 147 °C |
|---|---|
| Density | 2.347 |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Crystalline Solid, Powder, Crystals and/or Chunks |
| Specific Gravity | 2.347 |
| color | White to off-white |
| Water Solubility | Soluble in water, ethanol, dimethyl formamide, hexamethylphosphoramide, acetonitrile and methanol. Slightly soluble in terahydrofuran. |
| Sensitive | Moisture Sensitive |
| BRN | 3912121 |
| Exposure limits |
ACGIH: TWA 0.2 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 |
| InChIKey | KYEKHFSRAXRJBR-UHFFFAOYSA-M |
| CAS DataBase Reference | 3425-46-5(CAS DataBase Reference) |
| EPA Substance Registry System | Selenocyanic acid, potassium salt (3425-46-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H300-H331-H373-H410 | |||||||||
| Precautionary statements | P260-P264-P273-P301+P310-P304+P340+P311-P314 | |||||||||
| Hazard Codes | T,N,T+ | |||||||||
| Risk Statements | 23/25-33-50/53-28-23 | |||||||||
| Safety Statements | 20/21-28-45-60-61-36/37 | |||||||||
| RIDADR | UN 3283 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | VT1400000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 28429090 | |||||||||
| Toxicity | guinea pig,LD50,skin,50mg/kg (50mg/kg),SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE",National Technical Information Service. Vol. OTS0536978, | |||||||||
| NFPA 704 |
|
POTASSIUM SELENOCYANATE price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 483699 | Potassium selenocyanate ReagentPlus?, ≥99% | 3425-46-5 | 5G | ₹8335.25 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 216186 | Potassium selenocyanate reagent grade, 97% | 3425-46-5 | 10G | ₹11333.78 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 483699 | Potassium selenocyanate ReagentPlus?, ≥99% | 3425-46-5 | 25G | ₹15663.78 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 216186 | Potassium selenocyanate reagent grade, 97% | 3425-46-5 | 50G | ₹31641.48 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 216186 | Potassium selenocyanate reagent grade, 97% | 3425-46-5 | 250G | ₹104504.55 | 2022-06-14 | Buy |
POTASSIUM SELENOCYANATE Chemical Properties,Uses,Production
Description
Potassium selenocyanate, a crystalline solid, is a reagent for the conversion of alkyl halides to nitriles and for the production of pharmaceutical intermediates. It is also used in the field of energy storage devices.
Chemical Properties
white to light beige crystalline powder or needles
Uses
Potassium selenocyanate is used to prepare triphenylphosphine selenide by reacting with triphenylphosphine. It finds application in solid state NMR of heavy-metal nuclei which results in the preparation of several mercury thiocyanate and selenocyanate compounds.
Application
Potassium selenocyanate can be used to:
(1) Redox-active electrolyte to enhance the performance of carbon-based supercapacitors.
(2) Starting material for the one-pot stereoselective synthesis of alkyl styryl selenides.
(3) Precursor to synthesize Cu and Ni complexes with antioxidant/anti-inflammatory activities.
(4) Selenylating agent to prepare stereoselective selenoglycosides and selenium-linked disaccharides.
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NOx, CN-, K2O, and Se. See also SELENIUM COMPOUNDS and CYANATES.
Purification Methods
Dissolve it in acetone, filter and precipitate it by adding Et2O.
POTASSIUM SELENOCYANATE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| SNA HEALTHCARE PVT LTD | +91-8652842416 +91-8652842416 | Mumbai, India | 88 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| VASIN BIO LIFE SCIENCES PVT LTD | 9491644688 | Hyderabad, India | 2096 | 58 | Inquiry |
| Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | China | 10978 | 58 | Inquiry |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | China | 9338 | 55 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29826 | 58 | Inquiry |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | China | 12922 | 58 | Inquiry |
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