Isobutyl formate
- CAS No.
- 542-55-2
- Chemical Name:
- Isobutyl formate
- Synonyms
- NSC 6968;FEMA 2197;tetrylformate;Tertyl formate;Tetryl formate;Isobutyl forMat;ISOBUTYL FORMATE;IsobutylFormate>Iso-butyl methanoate;2-methylpropyl ester
- CBNumber:
- CB2853789
- Molecular Formula:
- C5H10O2
- Molecular Weight:
- 102.13
- MOL File:
- 542-55-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/25 15:44:26
| Melting point | -96 °C |
|---|---|
| Boiling point | 98.4 °C (lit.) |
| Density | 0.885 g/mL at 25 °C (lit.) |
| vapor density | 3.52 (vs air) |
| FEMA | 2197 | ISOBUTYL FORMATE |
| refractive index |
n |
| Flash point | 50 °F |
| storage temp. | Flammables area |
| Water Solubility | Soluble in water |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Odor | at 10.00 % in dipropylene glycol. sweet chemical ether fruity |
| Odor Type | chemical |
| Odor Threshold | 0.49ppm |
| explosive limit | 8.9% |
| Merck | 14,5143 |
| JECFA Number | 124 |
| Dielectric constant | 6.5（19℃） |
| InChIKey | AVMSWPWPYJVYKY-UHFFFAOYSA-N |
| LogP | 1.23 |
| CAS DataBase Reference | 542-55-2(CAS DataBase Reference) |
| EPA Substance Registry System | Formic acid, 2-methylpropyl ester (542-55-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H319-H335 | |||||||||
| Precautionary statements | P210-P305+P351+P338 | |||||||||
| Hazard Codes | F,C,Xi | |||||||||
| Risk Statements | 11-34-36/37 | |||||||||
| Safety Statements | 16-26-33-36/37/39-45-24-9 | |||||||||
| RIDADR | UN 2393 3/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | LQ8650000 | |||||||||
| Autoignition Temperature | 608 °F | |||||||||
| HazardClass | 3.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29151300 | |||||||||
| NFPA 704 |
|
Isobutyl formate price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W219703 | Isobutyl formate ≥95%, FG | 542-55-2 | 1SAMPLE-K | ₹5141.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W219703 | Isobutyl formate ≥95%, FG | 542-55-2 | 1KG | ₹10305.4 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W219703 | Isobutyl formate ≥95%, FG | 542-55-2 | 9KG | ₹51115.65 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 158658 | Isobutyl formate 97% | 542-55-2 | 100G | ₹5488.28 | 2022-06-14 | Buy |
| TCI Chemicals (India) | F0055 | Isobutyl Formate min. 95.0 % | 542-55-2 | 25ML | ₹2200 | 2022-05-26 | Buy |
Isobutyl formate Chemical Properties,Uses,Production
Description
Isobutyl formate has a fruity, ether-like odor and a sweet taste reminiscent of rum. Isobutyl formate may be prepared from isobutyl alcohol and carbon monoxide in the presence of sodium isobutylate at 110°C and 400 atm.
Chemical Properties
Isobutyl formate has a fruity, ether-like odor and a sweet taste reminiscent of rum.
Occurrence
Reported found in pineapple, apple, vinegar, wheat bread, beer, cognac and rum.
Uses
Isobutyl Formate is a synthetic flavoring agent that is a stable, colorless liquid of fruity odor. storage should be in glass or tin containers. it is used in fruit flavors such as pear, raspberry, and other berry flavors with applications in beverages, ice cream, candy, and baked goods at 2–18 ppm.
Preparation
From isobutyl alcohol and carbon monoxide in the presence of sodium isobutylate at 110°C and 400 atm
General Description
A colorless liquid. Less dense than water. Flash point 60°F. Vapors heavier than air. Vapors may be narcotic and irritating in high concentrations. Used as a solvent and to make perfumes.
Air & Water Reactions
Highly flammable. Soluble in water.
Reactivity Profile
Isobutyl formate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health Hazard
May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Synthesis
Iso-BUTYL FORMATE is synthesized from iso-Butanol by direct esterification with formic acid under azeotropic conditions, using e. g. para-Tolylsulfonic acid catalyst.
Purification Methods
Wash the formate with saturated aqueous NaHCO3, in the presence of saturated NaCl solution until no further reaction occurs, then with saturated aqueous NaCl, dry (MgSO4) and fractionally distil it. [Beilstein 2 H 21, 2 I 18, 2 II 30, 2 III 41, 2 IV 29.]
Isobutyl formate Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| S G Arochem Industries | +91-9557176200 +91-9806006051 | Madhya Pradesh, India | 48 | 58 | Inquiry |
| Amines Biotech Private Limited | 08048974617 | Vadodara, India | 104 | 58 | Inquiry |
| Vijay Trading Company | 91-22-24132120 | Maharashtra, India | 109 | 58 | Inquiry |
| Aroma Sales Corporation | 08068442234Ext 905 | Delhi, India | 131 | 58 | Inquiry |
| S.G. Arochem Industries | 08048969648 | Madhya Pradesh, India | 42 | 58 | Inquiry |
| Arofine Chemical Industries | +91 251-2870 800 | Maharashtra, India | 54 | 58 | Inquiry |
| S.G. Arochem Industries. | 91-731-4266051 | Madhya Pradesh, India | 19 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
| Juhi Essence Sugandhi | 09958833263 | Uttar Pradesh, India | 60 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| S G Arochem Industries | 58 |
| Amines Biotech Private Limited | 58 |
| Vijay Trading Company | 58 |
| Aroma Sales Corporation | 58 |
| S.G. Arochem Industries | 58 |
| Arofine Chemical Industries | 58 |
| S.G. Arochem Industries. | 58 |
| CHEMSWORTH | 30 |
| Central Drug House(P) Ltd. | 58 |
| Juhi Essence Sugandhi | 58 |
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