ChemicalBook > Product Catalog >Biochemical Engineering >Amino Acids and Derivatives >FMOC-amino acid >9-Fluorenylmethyl chloroformate
9-Fluorenylmethyl chloroformate
- CAS No.
- 28920-43-6
- Chemical Name:
- 9-Fluorenylmethyl chloroformate
- Synonyms
- FMOC-CL;FoMc-Cl;(9H-fluoren-9-yl)Methyl carbonochloridate;fmoc-ci;9-Fluorenylmethyl;FMOC-C;FMOC-CHLORIDE;1-(9-fluorenyl)methylchloroformate;9-FLUORENYLMETHOXYCARBONYL CHLORIDE;Fluorenylmethyloxycarbonyl chloride
- CBNumber:
- CB7234569
- Molecular Formula:
- C15H11ClO2
- Molecular Weight:
- 258.7
- MOL File:
- 28920-43-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/29 18:52:01
| Melting point | 62-64 °C(lit.) |
|---|---|
| Boiling point | 365.79°C (rough estimate) |
| Density | 1.1780 (rough estimate) |
| refractive index | 1.5330 (estimate) |
| storage temp. | 2-8°C |
| solubility | dioxane: 0.1 g/mL, clear, colorless |
| form | Crystalline Powder |
| color | White to very pale yellow |
| Sensitive | Moisture Sensitive |
| BRN | 2279177 |
| Stability | Hygroscopic, Moisture Sensitive |
| InChI | InChI=1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2 |
| InChIKey | IRXSLJNXXZKURP-UHFFFAOYSA-N |
| SMILES | C(Cl)(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O |
| LogP | 3.45 |
| CAS DataBase Reference | 28920-43-6(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | C,T | |||||||||
| Risk Statements | 34-20/21/22 | |||||||||
| Safety Statements | 26-36/37/39-45-27 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | LQ6250000 | |||||||||
| F | 10-21 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29159020 | |||||||||
| NFPA 704 |
|
9-Fluorenylmethyl chloroformate price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 8.52259 | (9-Fluorenylmethyl) chloroformate Novabiochem? | 28920-43-6 | 25G | ₹5660.01 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.52259 | (9-Fluorenylmethyl) chloroformate Novabiochem? | 28920-43-6 | 100G | ₹11500.01 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.18203 | (9-Fluorenylmethyl) chloroformate for synthesis | 28920-43-6 | 500MG | ₹3860 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.18203 | (9-Fluorenylmethyl) chloroformate for synthesis | 28920-43-6 | 5G | ₹20450 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.18203 | (9-Fluorenylmethyl) chloroformate for synthesis | 28920-43-6 | 25G | ₹60890 | 2022-06-14 | Buy |
9-Fluorenylmethyl chloroformate Chemical Properties,Uses,Production
Chemical Properties
White to off white crystalline powder
Uses
9-Fluorenylmethyl chloroformate is an N-Protecting agent for peptides research and was used for the pre-column derivatization of the biogenic amines (BAs) cadaverine (Cad), histamine (Him), octopami ne (Ocp), phenylethylamine (Pea), putrescine (Put), spermidine (Spd), spermine (Spm), tyramine (Tym).
General Description
Fmoc chloride is a derivatizing agent.
Safety Profile
A poison. Mutation data reported. A corrosive. When heated to decomposition it emits toxic vapors of Cl-.
Purification Methods
If the IR contains no OH bands (at ~3000 cm-1) due to the hydrolysis product 9-fluorenylmethanol, then purify it by recrystallisation from dry Et2O. IR (CHCl3) has a band at 1770 cm-1 (C=O), and the NMR (CDCl3) has at 4-4.6 (m 2H, CHCH2) and 7.1-7.8 (m, 8 aromatic H) ppm. The azide (FMOC-N3) has m 89-90o (from -1hexane) and IR (CHCl3) at 2135 (N3) and 1730 (C=O) cm , and the carbazate (FMOC-NHNH2) has m 171o(dec) (from nitromethane), IR (KBr) 3310, 3202 (NH) and 1686 (CONH) cm-1. [Caprino & Han J Org Chem 37, 3404 1972 , J Am Chem Soc 92 5748 1970, Koole et al. J Org Chem 59 1657 1989, Fürst et al. J Chromatogr 499 537 1990.]
9-Fluorenylmethyl chloroformate Preparation Products And Raw materials
Raw materials
Preparation Products
2-Ethylpiperazine
Fmoc-8-amino-3,6-dioxaoctanoic acid
3-(9H-FLUOREN-9-YLMETHOXYCARBONYLAMINO)-ISONICOTINIC ACID
Fmoc-D-phenylalanine
FMOC-2-AMINONICOTINIC ACID
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|---|---|---|---|---|---|
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| GLR Innovations | 58 |
| ANJI BIOSCIENCES | 58 |
| Allchem Lifescience Pvt. Ltd | 58 |
| JSK Chemicals | 58 |
| SIDDHI VINAYAKA SPECHEM PVT LTD | 58 |
| CJEX Biochem Pvt Ltd | 58 |
| OCEAN TRADING CORPORATION | 58 |
| A.J Chemicals | 58 |
| CHEMSWORTH | 30 |
| CLEARSYNTH LABS LTD. | 58 |
28920-43-6(9-Fluorenylmethyl chloroformate)Related Search:
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CHLOROFORMIC ACID 9-FLUORENYLMETHYL ESTER
EMOCCI
9-FLUORENYLMETHYL CHLOROFORMATE (FMOC CL)
Fmoc-Cl(9-FluorenylmethoxycarbonylChloride)
Fmoc-Clsee22072
FMOC-CL CHLOROFORMIC ACID 9-FLUORENYLMETHYL ESTER
9-Fluorenylmethoxycarbonyl chloride (Fmoc-Cl)
FMOC-CL, 9-FLLUORENYLMETHYL CHLOROFOMATE
Fmco-chloride(9-Fluorenyl methyl chloroformate)
Chloroformic acid 9H-fluoren-9-ylmethyl ester
9-Fluorenylmethyl Chloroformate [N-Protecting Agent for Peptides Research]
9-Fluorenylmethylchloroformate,98%
9-FLUOROMETHANOL ( FMOC )
9-FLUOROMETHANOL ( FMOC-ONSU )
FMOC-CL (9-FLUORENYLMETHYL CHLOROFORMATE)
9-Fluorenylmethylchloroformate (Fmoc-chloride)
9-Fluorenylmethoxycarbonyl chloride, 9-Fluorenylmethyl chloroformate, Fmoc-Cl
AminoTag
FMoc chloride 97%
FMOC chloride [FMOC-CL]
9-FluorenylMethyl ChloroforMate, 97+%
Fmoc chloride, >=98%
9 - fluorene chlorine Methyl forMate
Fmoc-Chloride≥ 98% (HPLC)
(9-Fluorenylmethyl) chloroformate Novabiochem
(9-Fluorenylmethyl) chloroformate for synthesis
chloro-formicacifluoren-9-ylmethylester
Formicacid,chloro-,fluoren-9-ylmethylester
N-9-FLUORENYLMETHYL CHLOROFORMATE
RARECHEM FM OC 0001
9h-fluoren-9-ylmethyl chloroformate
9-FLUOROENYLMETHYL CHLOROFORMATE
9-FLUORENEMETHYL CHLOROFORMATE
9-FLUORENMETHYL CHLOROFORMATE
9-FLUORENYLMETHYL CHLOROFORMATE
9-(Chloroformyloxymethyl)-9H-fluorene
Chloridocarbonic acid (9H-fluoren-9-yl)methyl ester
Chlorocarbonic acid (9H-fluoren-9-ylmethyl) ester
Chloroformic acid (9H-fluoren-9-yl)methyl
CARBONOCHLORIDIC ACID, 9H-FLUOREN-9-YLMETHYL ESTER
9-Fluoroe
Fmoc chloride,9-Fluorenylmethoxycarbonyl chloride, 9-Fluorenylmethyl chloroformate, Fmoc-Cl
Chloroformic acid 9-
(9H-Fluoren-9-yl)methyl carbonochloridoate
9-FluorenylMethyl chloroforMate, 98% 1GR
9-FluorenylMethyl chloroforMate, 98% 5GR
Fmoc-Cl
Chloroformic Acid 9-Fluorenylmethyl Ester
(9H-Fluoren-9-ylmethoxy)carbonyl Chloride
9H-fluoren-9-ylMethylester carbonochloridric acid
(9-FLUORENYLMETHYL) CHLOROFORMATE FOR SY
FMoc-Cl)FMoc chl
(9H-Fluoren-9-yl)methyl carbonochloridoate, FMOC-chloride
(9H-Fluoren-9-yl)MethOxy]Carbonyl Cl
Chloroformic acid 9-fluorenylmethyl ester(Fmoc-CL)
9-Fluorenylmethyl chloroformate, Chloroformic acid 9-fluorenylmethyl este, Fmoc-Cl
uorenyL
Fmoc-Cl(99%)
Fluorenylmethyl Research
9-FluorenylmethylChloroformate[N-ProtectingAgentforPeptidesResearch]>