Biphenyl-4,4'-dicarboxylic acid
- CAS No.
- 787-70-2
- Chemical Name:
- Biphenyl-4,4'-dicarboxylic acid
- Synonyms
- DK7488;usafdo-69;Biphenyl-4,4;BIBENZOIC ACID;-4,4’-dicarboxyL;4,4'-DIPHENIC ACID;4,4'-Diphenit acid;P,P'-DIPHENIC ACID;4,4'-BIBENZOIC ACID;4,4'-DIBENZOIC ACID
- CBNumber:
- CB3236752
- Molecular Formula:
- C14H10O4
- Molecular Weight:
- 242.23
- MOL File:
- 787-70-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/30 14:17:11
Melting point | >300 °C(lit.) |
---|---|
Boiling point | 482.5±38.0 °C(Predicted) |
Density | 1.347±0.06 g/cm3(Predicted) |
storage temp. | Sealed in dry,Room Temperature |
pka | 3.77±0.10(Predicted) |
form | Powder |
color | White to light beige |
BRN | 523308 |
InChIKey | NEQFBGHQPUXOFH-UHFFFAOYSA-N |
CAS DataBase Reference | 787-70-2(CAS DataBase Reference) |
EPA Substance Registry System | [1,1'-Biphenyl]-4,4'-dicarboxylic acid (787-70-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P305+P351+P338 | |||||||||
Hazard Codes | Xi,Xn | |||||||||
Risk Statements | 36/37/38-20/21/22 | |||||||||
Safety Statements | 26-37/39-36 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | DV2975000 | |||||||||
HS Code | 29173990 | |||||||||
NFPA 704 |
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Biphenyl-4,4'-dicarboxylic acid price More Price(4)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 225266 | Biphenyl-4,4′-dicarboxylic acid 97% | 787-70-2 | 5G | ₹13206.5 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 225266 | Biphenyl-4,4′-dicarboxylic acid 97% | 787-70-2 | 25G | ₹28989.35 | 2022-06-14 | Buy |
TCI Chemicals (India) | B1191 | 4,4'-Biphenyldicarboxylic Acid min. 95.0 % | 787-70-2 | 5G | ₹6300 | 2022-05-26 | Buy |
TCI Chemicals (India) | B1191 | 4,4'-Biphenyldicarboxylic Acid min. 95.0 % | 787-70-2 | 25G | ₹19100 | 2022-05-26 | Buy |
Biphenyl-4,4'-dicarboxylic acid Chemical Properties,Uses,Production
Chemical Properties
White to light beige powder
Uses
Dendrimer building block.
Purification Methods
The dicarboxylic acid is a white amorphous or microcrystalline substance which does not melt or sublime. It is best purified by precipitation of an aqueous alkaline solution with mineral acid, washing well with H2O and drying in vacuo at 100o. It is characterized by conversion to diphenyl-4,4’-dicarbonyl chloride (with PCl5 [Work J Chem Soc 1317 1940], or by phase transfer catalysis with SOCl2 + BuEt3N+Cl-in 1,2-dichloroethane [Burdett Synthesis 441 1991]) which crystallises from *C6H6 with m 184o. The di-acid chloride gives the dimethyl ester with MeOH, and has m 215-217o (plates from MeOH, m’s of 214o and 224o were also reported). The diethyl ester is similarly prepared with EtOH and has m 122o (from EtOH). [Beilstein 9 II 665, 9 III 4519, 9 IV 3563.]
Biphenyl-4,4'-dicarboxylic acid Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Aether Industries Limited | +91-261-6603130 +91-2616603130 | Gujarat, India | 145 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Metropolitan Eximchem Limited | +91 22 2408 1528 | Mumbai, India | 48 | 58 | Inquiry |
Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
Gharda Chemicals Limited | 08048372602Ext 584 | Maharashtra, India | 31 | 58 | Inquiry |
Metropolitan Eximchem Ltd. | 91 22 408 1529 | New Delhi, India | 148 | 38 | Inquiry |
Dalian Richfortune Chemicals Co., Ltd | 0411-84820922 8613904096939 | China | 304 | 57 | Inquiry |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | China | 12458 | 58 | Inquiry |
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