Benzyl 2-chloroacetate
![Benzyl 2-chloroacetate Structure](CAS/GIF/140-18-1.gif)
- CAS No.
- 140-18-1
- Chemical Name:
- Benzyl 2-chloroacetate
- Synonyms
- AKOS B029322;monochloroacetate;benzyl chloracetate;Benzyl 2-chloroaceta;BENZYL CHLOROACETATE;BENZYL-(CHLORACETAT);benzyl 2-chloroacetate;benzylmonochloracetate;Benzyl chloroacetate,98%;Benzyl chloroacetate 99%
- CBNumber:
- CB3245642
- Molecular Formula:
- C9H9ClO2
- Molecular Weight:
- 184.62
- MOL File:
- 140-18-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/11 9:28:58
Boiling point | 90 °C/1 mmHg (lit.) |
---|---|
Density | 1.215 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | >230 °F |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | clear liquid |
Specific Gravity | 1.215 |
color | Oil |
Water Solubility | insoluble |
CAS DataBase Reference | 140-18-1(CAS DataBase Reference) |
EPA Substance Registry System | Acetic acid, chloro-, phenylmethyl ester (140-18-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | AF8750000 | |||||||||
HS Code | 29154000 | |||||||||
Toxicity | LDLo ipr-mus: 500 mg/kg CBCCT* 8,99,56 | |||||||||
NFPA 704 |
|
Benzyl 2-chloroacetate price More Price(3)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 349712 | Benzyl chloroacetate 99% | 140-18-1 | 5ML | ₹2868.63 | 2022-06-14 | Buy |
TCI Chemicals (India) | C1265 | Benzyl Chloroacetate min. 97.0 % | 140-18-1 | 25G | ₹6200 | 2022-05-26 | Buy |
TCI Chemicals (India) | C1265 | Benzyl Chloroacetate min. 97.0 % | 140-18-1 | 250G | ₹27000 | 2022-05-26 | Buy |
Benzyl 2-chloroacetate Chemical Properties,Uses,Production
Chemical Properties
Benzyl 2-chloroacetate is a colorless, slightly viscous liquid. Insoluble in water, soluble in alcohol and oils. Sp.Gr = 1.22. Mild, Jasmin-type odor, floral-fruity, of considerable tenacity.
Uses
Benzyl chloroacetate may be used:
- in the synthesis of monoesters of phosphonoacetic acid
- in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis
- as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E
Preparation
From Benzyl alcohol and Monochloroacetic acid by direct esterification under azeotropic conditions.
General Description
Benzyl chloroacetate is an ester. Could find usc in Jasmin, Lilac. Appleblossom fragrances, particularly for soap, where this ester has greater fixative effect than the Benzyl acetate. However, this ester must be absolutely acid-free to be permitted or recommended for use in any cosmetic product. The acid is highly corrosive. Older odor-descriptions of this ester seem to indicate that the product has not always been very pure.
Safety Profile
Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .
Benzyl 2-chloroacetate Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
Resins and Allied Products | 9960187829 | Maharashtra, India | 24 | 58 | Inquiry |
Sontara Organo Industries | +919423554439 | Maharashtra, India | 46 | 58 | Inquiry |
Ralington Pharma | +91-7948911722 +91-9687771722 | Gujarat, India | 1350 | 58 | Inquiry |
Sontara Organo Industries | 08048969185 | Mumbai, India | 49 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Hemadri Chemicals | 08047646492 | Mumbai, India | 17 | 58 | Inquiry |
Resins & Allied Products | 08068979866Ext 499 | Maharashtra, India | 7 | 58 | Inquiry |
P C Chem | +91-8046061281 | Mumbai, India | 676 | 58 | Inquiry |
d & d chemical consultancy services | 07798149760 | Maharashtra, India | 4 | 58 | Inquiry |
Supplier | Advantage |
---|---|
GLR Innovations | 58 |
Resins and Allied Products | 58 |
Sontara Organo Industries | 58 |
Ralington Pharma | 58 |
Sontara Organo Industries | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Hemadri Chemicals | 58 |
Resins & Allied Products | 58 |
P C Chem | 58 |
d & d chemical consultancy services | 58 |
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