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Benzyl 2-chloroacetate

Benzyl 2-chloroacetate Structure
CAS No.
140-18-1
Chemical Name:
Benzyl 2-chloroacetate
Synonyms
AKOS B029322;monochloroacetate;benzyl chloracetate;Benzyl 2-chloroaceta;BENZYL CHLOROACETATE;BENZYL-(CHLORACETAT);benzyl 2-chloroacetate;benzylmonochloracetate;Benzyl chloroacetate,98%;Benzyl chloroacetate 99%
CBNumber:
CB3245642
Molecular Formula:
C9H9ClO2
Molecular Weight:
184.62
MOL File:
140-18-1.mol
MSDS File:
SDS
Modify Date:
2024/6/11 9:28:58

Benzyl 2-chloroacetate Properties

Boiling point 90 °C/1 mmHg (lit.)
Density 1.215 g/mL at 25 °C (lit.)
refractive index n20/D 1.525(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
Specific Gravity 1.215
color Oil
Water Solubility insoluble
CAS DataBase Reference 140-18-1(CAS DataBase Reference)
EPA Substance Registry System Acetic acid, chloro-, phenylmethyl ester (140-18-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
RTECS  AF8750000
HS Code  29154000
Toxicity LDLo ipr-mus: 500 mg/kg CBCCT* 8,99,56
NFPA 704
1
0 0

Benzyl 2-chloroacetate price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 349712 Benzyl chloroacetate 99% 140-18-1 5ML ₹2868.63 2022-06-14 Buy
TCI Chemicals (India) C1265 Benzyl Chloroacetate min. 97.0 % 140-18-1 25G ₹6200 2022-05-26 Buy
TCI Chemicals (India) C1265 Benzyl Chloroacetate min. 97.0 % 140-18-1 250G ₹27000 2022-05-26 Buy
Product number Packaging Price Buy
349712 5ML ₹2868.63 Buy
C1265 25G ₹6200 Buy
C1265 250G ₹27000 Buy

Benzyl 2-chloroacetate Chemical Properties,Uses,Production

Chemical Properties

Benzyl 2-chloroacetate is a colorless, slightly viscous liquid. Insoluble in water, soluble in alcohol and oils. Sp.Gr = 1.22. Mild, Jasmin-type odor, floral-fruity, of considerable tenacity.

Uses

Benzyl chloroacetate may be used:

  • in the synthesis of monoesters of phosphonoacetic acid
  • in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis
  • as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E

Preparation

From Benzyl alcohol and Monochloroacetic acid by direct esterification under azeotropic conditions.

General Description

Benzyl chloroacetate is an ester. Could find usc in Jasmin, Lilac. Appleblossom fragrances, particularly for soap, where this ester has greater fixative effect than the Benzyl acetate. However, this ester must be absolutely acid-free to be permitted or recommended for use in any cosmetic product. The acid is highly corrosive. Older odor-descriptions of this ester seem to indicate that the product has not always been very pure.

Safety Profile

Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .

Benzyl 2-chloroacetate Preparation Products And Raw materials

Global( 174)Suppliers
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GLR Innovations +91 9891111994 New Delhi, India 4542 58 Inquiry
Resins and Allied Products 9960187829 Maharashtra, India 24 58 Inquiry
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Sontara Organo Industries 08048969185 Mumbai, India 49 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Hemadri Chemicals 08047646492 Mumbai, India 17 58 Inquiry
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P C Chem +91-8046061281 Mumbai, India 676 58 Inquiry
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AKOS B029322 CHLOROACETIC ACID BENZYL ESTER BENZYL-(CHLORACETAT) BENZYL CHLOROACETATE benzyl 2-chloroacetate Acetic acid, chloro-, phenylmethyl ester benzyl chloracetate Phenylmethyl 2-chloroacetate Benzyl chloroacetate,98% Benzyl 2-chloroaceta Benzyl chloroacetate, 98% 25ML Benzyl chloroacetate 99% 2-CHLORO ACETIC ACID BENZYLESTER benzyl-alpha-chloroacetate benzylmonochloracetate chloro-aceticacibenzylester chloro-aceticaciphenylmethylester monochloroacetate phenylmethylchloroacetate Benzyl monochloroacetate 2-chloroacetic acid (phenylmethyl) ester Benzyl Chloroacetate > Acetic acid, 2-chloro-, phenylmethyl ester 2-CHLORO ACETIC ACID BENZYLESTER (BENZYL CHLORO ACETATE) 140-18-1 140-18-0 ClCH2COOCH2C6H5 ClCH2CO2CH2C6H5 Carbonyl Compounds C8 to C9 Building Blocks HALOGEN Organic Building Blocks Esters C8 to C9 Carbonyl Compounds Esters