Boron trifluoride methyl sulfide complex

- CAS No.
- 353-43-5
- Chemical Name:
- Boron trifluoride methyl sulfide complex
- Synonyms
- C2H6BF3S;uoride-dimethyL;purified,packagedunderArgon;boron trifluoride-dimethyl s;TRIFLUOROBORANE-METHYL SULFIDE;DIMETHYL SULFIDE-TRIFLUOROBORANE;Boron Trifluoride-Dimethyl Sulfide;BORON FLUORIDE-DIMETHYL SULFIDE COMPLEX;BORON TRIFLUORIDE-METHYL SULFIDE COMPLEX;Boron trifluoride-dimethyl sulfide (1:1)
- CBNumber:
- CB3251258
- Molecular Formula:
- C2H7BF3S
- Molecular Weight:
- 130.94
- MOL File:
- 353-43-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225-H314 | |||||||||
Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | F,C | |||||||||
Risk Statements | 11-34 | |||||||||
Safety Statements | 16-26-27-36/37/39-45 | |||||||||
RIDADR | UN 2924 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | I | |||||||||
HS Code | 2930909899 | |||||||||
NFPA 704 |
|
Boron trifluoride methyl sulfide complex Chemical Properties,Uses,Production
Description
Boron trifluoride methyl sulfide complex is reagent for the cleavage of benzyl ethers and carbamates.
Uses
Boron trifluoride methyl sulfide complex is a common reagent used for dealkylation of ethers. It can also be used to synthesize boron trifluoride complex with phosphine ligands.
Preparation
Boron trifluoride methyl sulfide complex is made by the addition of equimolar amounts of the two components at -78 °C. Dissociation of the complex reported as 96.2% at 12 °C and 97.4% at 34 °C. Also formed when crystalline bromodimethylsulfonium tetrafluoroborate is aspirated at rt to give a colorless product without change in crystal form. The reagent system is normally assembled by adding a large excess of dimethyl sulfide to an excess of boron trifluoride etherate.
storage
moisture-sensitive; use with carefully dried apparatus. All work must be carried out in an efficient fume hood.
Boron trifluoride methyl sulfide complex Preparation Products And Raw materials
Raw materials
Preparation Products
Boron trifluoride methyl sulfide complex Suppliers
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Tiancheng Chemical (Jiangsu) Co., Ltd | 18662433356 | China | 2026 | 58 | Inquiry |
Nanxing Chemical (Jiangsu) Co., Ltd | 18662433356 | China | 2026 | 58 | Inquiry |
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