ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Borane >Borane-methyl sulfide complex
Borane-methyl sulfide complex
- CAS No.
- 13292-87-0
- Chemical Name:
- Borane-methyl sulfide complex
- Synonyms
- BMS;Dimethylsulfide borane complex;(Dimethyl sulfide)trihydroboron;DMSB;borane-methyl sulfide;DIMETHYL SULFIDE BORANE;BORANE-DIMETHYLSULFIDE;BORANE-DIMETHYLSULFIDE COMPLEX;borane dimethyl sulfide complex solution;Borane dimethyL
- CBNumber:
- CB3700534
- Molecular Formula:
- C2H10BS
- Molecular Weight:
- 76.97
- MOL File:
- 13292-87-0.mol
- Modify Date:
- 2024/4/25 13:42:50
| Melting point | -40--37°C |
|---|---|
| Boiling point | ~34 °C |
| Density | 1.287 g/mL at 25 °C |
| refractive index | 1.4570 |
| Flash point | 65 °F |
| storage temp. | 2-8°C |
| solubility | Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. |
| form | Solution |
| color | Colorless to pale yellow |
| Specific Gravity | 0.801 |
| Water Solubility | reacts |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3663489 |
| InChIKey | RMHDLBZYPISZOI-UHFFFAOYSA-N |
| CAS DataBase Reference | 13292-87-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Borane-methyl sulfide complex(13292-87-0) |
| EPA Substance Registry System | Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H260-H301+H311-H318-H360FD-H412 | |||||||||
| Precautionary statements | P210-P231+P232-P273-P280-P301+P310-P305+P351+P338 | |||||||||
| Hazard Codes | F+,Xn,F,Xi | |||||||||
| Risk Statements | 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37 | |||||||||
| Safety Statements | 36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39 | |||||||||
| RIDADR | UN 3399 4.3/PG 1 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | PV5080000 | |||||||||
| F | 10-13-23 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29309090 | |||||||||
| NFPA 704 |
|
Borane-methyl sulfide complex price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 775118 | Borane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran | 13292-87-0 | 4X25ML | ₹5519.5 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 775118 | Borane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran | 13292-87-0 | 100ML | ₹9788.8 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 775118 | Borane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran | 13292-87-0 | 500ML | ₹31215.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 192120 | Borane dimethyl sulfide complex solution 2.0?M in THF | 13292-87-0 | 100ML | ₹5856.33 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 192120 | Borane dimethyl sulfide complex solution 2.0?M in THF | 13292-87-0 | 4X25ML | ₹5964.58 | 2022-06-14 | Buy |
Borane-methyl sulfide complex Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow solution
Uses
Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
General Description
Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.
Borane-methyl sulfide complex Preparation Products And Raw materials
Raw materials
Preparation Products
4H-AMINO-6-BROMO-2,3-DIHYDROTHIOCHROMEN-1,1-DIOXIDE
Ethylferrocene
5'-BROMO-2'-CHLOROACETOPHENONE
1,1'-DI-N-BUTYLFERROCENE
4-Hydroxy-6-bromo-2,3-dihydrothiochromen-1,1-dioxide
Butylferrocene
3-Nitrobenzylammonium hydrochloride
(S)-5-Hydroxymethyldihydrofuran-2-one
1,1,2-Trimethylpropylborane
1,1'-DIMETHYLFERROCENE
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Global( 295)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Almas Life Sciences | +919441456585 | Hyderabad, India | 54 | 58 | Inquiry |
| JLS Laboratories Pvt Limited | +91 8790545679 | Hyderabad, India | 62 | 58 | Inquiry |
| SREEGANAPHARMACEUTICALS | +91 9121019922 | Hyderabad, India | 14 | 58 | Inquiry |
| VASISTA LIFE SCIENCES PRIVATE LIMITED | +91-04029554774 +91-9010855544 | Hyderabad, India | 153 | 58 | Inquiry |
| Oceanic Pharmachem Pvt Ltd | +91-91-2242128600 +91-2242128600 | Maharashtra, India | 33 | 58 | Inquiry |
| Organo Metallics | +91-9391016448 +91-9705345345 | Telangana, India | 32 | 58 | Inquiry |
| Arnavi Laboratory | +91-7780703633 +91-7780703633 | Telangana, India | 83 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| AMINO ORGANICS | +919866989891 | Hyderabad, India | 275 | 58 | Inquiry |
| Sanpra Synthesis Pvt. Ltd. | +91-4043460830 +91-9246161600 | AndhraPradesh, India | 49 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Almas Life Sciences | 58 |
| JLS Laboratories Pvt Limited | 58 |
| SREEGANAPHARMACEUTICALS | 58 |
| VASISTA LIFE SCIENCES PRIVATE LIMITED | 58 |
| Oceanic Pharmachem Pvt Ltd | 58 |
| Organo Metallics | 58 |
| Arnavi Laboratory | 58 |
| JSK Chemicals | 58 |
| AMINO ORGANICS | 58 |
| Sanpra Synthesis Pvt. Ltd. | 58 |
13292-87-0(Borane-methyl sulfide complex)Related Search:
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dimethylsulfideborane,dmsb,in
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methylsulfide,compd.withborane(1:1)
BMS~Borane-methyl sulphide~Dimethyl sulphide borane
dimethyl sulphide--borane
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METHYL SULFIDE BORANE
BORANE-METHYL SULFIDE COMPLEX
BORANE DIMETHYL SULPHIDE COMPLEX
Borane, compd. with dimethylsulfide
borane,compd.withdimethylsulfide