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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Borane >Borane-methyl sulfide complex

Borane-methyl sulfide complex

Borane-methyl sulfide complex Structure
  • ₹1381 - ₹50325.43
  • Product name: Borane-methyl sulfide complex
  • CAS: 13292-87-0
  • MF: C2H10BS
  • MW: 76.97
  • EINECS:236-313-6
  • MDL Number:MFCD00013189
  • Synonyms:Borane-Methyl sulfide coMplex, 1M solution in Methylene chloride, AcroSeal 100ML;Borane-Methyl sulfide coMplex, 2M solution in tetrahydrofuran, AcroSeal 100ML;Borane-Methyl sulfide coMplex, 2M solution in tetrahydrofuran, AcroSeal 800ML;Borane - Dimethyl Sulfide Complex DMSB Methyl Sulfide Borane;Borane-Methyl sulfide coMplex, 2M solution in toluene, AcroSeal;Borane-Methyl sulfide coMplex, 5M solution in diethyl ether, AcroSeal;Borane-Methyl sulfide coMplex (BMS;DiMethylsulfide Borane in tetrahydrofurane
24 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 5mL
  • 25ML
  • 50mL
  • 4X25ML
  • 100ML
  • 500ML
  • 800ML
  • ManufacturerTCI Chemicals (India)
  • Product numberD1843
  • Product descriptionDimethyl Sulfide Borane
  • Packaging25ML
  • Price₹3200
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD1843
  • Product descriptionDimethyl Sulfide Borane
  • Packaging100ML
  • Price₹7500
  • Updated2022-05-26
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  • ManufacturerSigma-Aldrich(India)
  • Product number179825
  • Product descriptionBorane dimethyl sulfide complex
  • Packaging25ML
  • Price₹4947.03
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number775118
  • Product descriptionBorane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran
  • Packaging4X25ML
  • Price₹5519.5
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number192120
  • Product descriptionBorane dimethyl sulfide complex solution 2.0?M in THF
  • Packaging100ML
  • Price₹5856.33
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number192120
  • Product descriptionBorane dimethyl sulfide complex solution 2.0?M in THF
  • Packaging4X25ML
  • Price₹5964.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number447145
  • Product descriptionBorane dimethyl sulfide complex solution 5.0?M in diethyl ether
  • Packaging100ML
  • Price₹6310.98
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number775118
  • Product descriptionBorane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran
  • Packaging100ML
  • Price₹9788.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number179825
  • Product descriptionBorane dimethyl sulfide complex
  • Packaging100ML
  • Price₹11755.95
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number179825
  • Product descriptionBorane dimethyl sulfide complex
  • Packaging4X25ML
  • Price₹20123.68
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number192120
  • Product descriptionBorane dimethyl sulfide complex solution 2.0?M in THF
  • Packaging800ML
  • Price₹30797.13
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number775118
  • Product descriptionBorane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran
  • Packaging500ML
  • Price₹31215.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number179825
  • Product descriptionBorane dimethyl sulfide complex
  • Packaging800ML
  • Price₹50325.43
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042963-AP
  • Product descriptionBorane-dimethyl sulfide complex, 2M in toluene, packaged under Argon in resealable ChemSeal™ bottles
  • Packaging500mL
  • Price₹47594
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042967-AP
  • Product descriptionBorane-dimethyl sulfide complex, packaged under Argon in resealable ChemSeal™ bottles
  • Packaging500mL
  • Price₹32293
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042965-AP
  • Product descriptionBorane-dimethyl sulfide complex, 2M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • Packaging500mL
  • Price₹21077
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D1843 Dimethyl Sulfide Borane 25ML ₹3200 2022-05-26 Buy
TCI Chemicals (India) D1843 Dimethyl Sulfide Borane 100ML ₹7500 2022-05-26 Buy
Sigma-Aldrich(India) 179825 Borane dimethyl sulfide complex 25ML ₹4947.03 2022-06-14 Buy
Sigma-Aldrich(India) 775118 Borane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran 4X25ML ₹5519.5 2022-06-14 Buy
Sigma-Aldrich(India) 192120 Borane dimethyl sulfide complex solution 2.0?M in THF 100ML ₹5856.33 2022-06-14 Buy
Sigma-Aldrich(India) 192120 Borane dimethyl sulfide complex solution 2.0?M in THF 4X25ML ₹5964.58 2022-06-14 Buy
Sigma-Aldrich(India) 447145 Borane dimethyl sulfide complex solution 5.0?M in diethyl ether 100ML ₹6310.98 2022-06-14 Buy
Sigma-Aldrich(India) 775118 Borane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran 100ML ₹9788.8 2022-06-14 Buy
Sigma-Aldrich(India) 179825 Borane dimethyl sulfide complex 100ML ₹11755.95 2022-06-14 Buy
Sigma-Aldrich(India) 179825 Borane dimethyl sulfide complex 4X25ML ₹20123.68 2022-06-14 Buy
Sigma-Aldrich(India) 192120 Borane dimethyl sulfide complex solution 2.0?M in THF 800ML ₹30797.13 2022-06-14 Buy
Sigma-Aldrich(India) 775118 Borane dimethyl sulfide complex solution 1.0?M in 2-methyltetrahydrofuran 500ML ₹31215.1 2022-06-14 Buy
Sigma-Aldrich(India) 179825 Borane dimethyl sulfide complex 800ML ₹50325.43 2022-06-14 Buy
ALFA India ALF-042963-AP Borane-dimethyl sulfide complex, 2M in toluene, packaged under Argon in resealable ChemSeal™ bottles 500mL ₹47594 2022-05-26 Buy
ALFA India ALF-042967-AP Borane-dimethyl sulfide complex, packaged under Argon in resealable ChemSeal™ bottles 500mL ₹32293 2022-05-26 Buy
ALFA India ALF-042965-AP Borane-dimethyl sulfide complex, 2M in THF, packaged under Argon in resealable ChemSeal™ bottles 500mL ₹21077 2022-05-26 Buy

Properties

Melting point :-40--37°C
Boiling point :~34 °C
Density :1.287 g/mL at 25 °C
refractive index :1.4570
Flash point :65 °F
storage temp. :2-8°C
solubility :Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.
form :Solution
color :Colorless to pale yellow
Specific Gravity :0.801
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :3663489
InChIKey :RMHDLBZYPISZOI-UHFFFAOYSA-N
CAS DataBase Reference :13292-87-0(CAS DataBase Reference)
NIST Chemistry Reference :Borane-methyl sulfide complex(13292-87-0)
EPA Substance Registry System :Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.

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