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ChemicalBook > Product Catalogue >Organic Chemistry >Ethers and derivatives >Ethers, ether-alcohols >tert-Butyl methyl ether

tert-Butyl methyl ether

tert-Butyl methyl ether Structure
  • ₹432 - ₹744900
  • Product name: tert-Butyl methyl ether
  • CAS: 1634-04-4
  • MF: C5H12O
  • MW: 88.15
  • EINECS:216-653-1
  • MDL Number:MFCD00008812
  • Synonyms:Methyl-tert-bu;tert-Butyl methyl ether for HPLC, >=99.8%;tert-Butyl methyl ether HPLC Plus, for HPLC, GC, and residue analysis, 99.9%;tert-Butyl methyl ether puriss. p.a., >=99.5% (GC);tert-Butyl methyl ether reagent grade, >=98%;tert-Butyl Methyl ether ACS reagent, >=99.0%;tert-Butyl Methyl ether, 99%, SpcDry, Water≤50 ppM (by K.F.), SpcSeal;N-ALPHA-T-BOC-NG-(4-METHOXY-2,3,6 TRIMETHYLBENZENESULFONYL)-L-ARGININE
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  • Sigma-Aldrich(India)
  • ALFA India
  • TCI Chemicals (India)
  • SRL
  • ottokemi

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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01843
  • Product descriptiontert-Butyl methyl ether EMPLURA?
  • Packaging1018430521
  • Price₹1280
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number179787
  • Product descriptiontert-Butyl methyl ether reagent grade, ≥98%
  • Packaging1L
  • Price₹2944.4
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number34875
  • Product descriptiontert-Butyl methyl ether suitable for HPLC, ≥99.8%
  • Packaging1L
  • Price₹3031
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number34875
  • Product descriptiontert-Butyl methyl ether suitable for HPLC, ≥99.8%
  • Packaging100ML
  • Price₹3810.4
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number306975
  • Product descriptiontert-Butyl methyl ether anhydrous, 99.8%
  • Packaging100ML
  • Price₹3951.13
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number320196
  • Product descriptiontert-Butyl methyl ether reagent grade, 98%
  • Packaging1L
  • Price₹4449.08
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01843
  • Product descriptiontert-Butyl methyl ether EMPLURA?
  • Packaging25L
  • Price₹69119.99
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number443808
  • Product descriptiontert-Butyl methyl ether ACS reagent, ≥99.0%
  • Packaging200L
  • Price₹127161.28
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01843
  • Product descriptiontert-Butyl methyl ether EMPLURA?
  • Packaging190L
  • Price₹446940
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01849
  • Product descriptiontert-Butyl methyl ether for analysis EMSURE? ACS
  • Packaging1018496190
  • Price₹744900
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01849
  • Product descriptiontert-Butyl methyl ether for analysis EMSURE? ACS
  • Packaging1018495011
  • Price₹32460
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01845
  • Product descriptiontert-Butyl methyl ether for liquid chromatography LiChrosolv?
  • Packaging2.5L
  • Price₹34230
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01843
  • Product descriptiontert-Butyl methyl ether EMPLURA?
  • Packaging10L
  • Price₹36140
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product numberRTC000083
  • Product descriptiontert-Butyl Methyl Ether Pharmaceutical Secondary Standard; Certified Reference Material
  • Packaging20ML
  • Price₹40756.13
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number443808
  • Product descriptiontert-Butyl methyl ether ACS reagent, ≥99.0%
  • Packaging4X4L
  • Price₹54958.53
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number1.01843
  • Product descriptiontert-Butyl methyl ether EMPLURA?
  • Packaging1018439221
  • Price₹64040
  • Updated2022-06-14
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Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 1.01843 tert-Butyl methyl ether EMPLURA? 1018430521 ₹1280 2022-06-14 Buy
Sigma-Aldrich(India) 179787 tert-Butyl methyl ether reagent grade, ≥98% 1L ₹2944.4 2022-06-14 Buy
Sigma-Aldrich(India) 34875 tert-Butyl methyl ether suitable for HPLC, ≥99.8% 1L ₹3031 2022-06-14 Buy
Sigma-Aldrich(India) 34875 tert-Butyl methyl ether suitable for HPLC, ≥99.8% 100ML ₹3810.4 2022-06-14 Buy
Sigma-Aldrich(India) 306975 tert-Butyl methyl ether anhydrous, 99.8% 100ML ₹3951.13 2022-06-14 Buy
Sigma-Aldrich(India) 320196 tert-Butyl methyl ether reagent grade, 98% 1L ₹4449.08 2022-06-14 Buy
Sigma-Aldrich(India) 1.01843 tert-Butyl methyl ether EMPLURA? 25L ₹69119.99 2022-06-14 Buy
Sigma-Aldrich(India) 443808 tert-Butyl methyl ether ACS reagent, ≥99.0% 200L ₹127161.28 2022-06-14 Buy
Sigma-Aldrich(India) 1.01843 tert-Butyl methyl ether EMPLURA? 190L ₹446940 2022-06-14 Buy
Sigma-Aldrich(India) 1.01849 tert-Butyl methyl ether for analysis EMSURE? ACS 1018496190 ₹744900 2022-06-14 Buy
Sigma-Aldrich(India) 1.01849 tert-Butyl methyl ether for analysis EMSURE? ACS 1018495011 ₹32460 2022-06-14 Buy
Sigma-Aldrich(India) 1.01845 tert-Butyl methyl ether for liquid chromatography LiChrosolv? 2.5L ₹34230 2022-06-14 Buy
Sigma-Aldrich(India) 1.01843 tert-Butyl methyl ether EMPLURA? 10L ₹36140 2022-06-14 Buy
Sigma-Aldrich(India) RTC000083 tert-Butyl Methyl Ether Pharmaceutical Secondary Standard; Certified Reference Material 20ML ₹40756.13 2022-06-14 Buy
Sigma-Aldrich(India) 443808 tert-Butyl methyl ether ACS reagent, ≥99.0% 4X4L ₹54958.53 2022-06-14 Buy
Sigma-Aldrich(India) 1.01843 tert-Butyl methyl ether EMPLURA? 1018439221 ₹64040 2022-06-14 Buy

Properties

Melting point :-110 °C
Boiling point :55-56 °C(lit.)
Density :0.7404
vapor density :3.1 (vs air)
vapor pressure :4.05 psi ( 20 °C)
refractive index :n20/D 1.369(lit.)
Flash point :-27 °F
storage temp. :Store at +2°C to +25°C.
solubility :42g/l
form :Powder or Needles
color :APHA: ≤10
Specific Gravity :0.740
Relative polarity :0.124
Odor :Characteristic ethereal odor
explosive limit :1.5-8.5%(V)
Water Solubility :51 g/L (20 ºC)
FreezingPoint :-108.6℃
λmax :λ: 210 nm Amax: 1.0
λ: 225 nm Amax: 0.50
λ: 250 nm Amax: 0.10
λ: 300-400 nm Amax: 0.005 Merck :14,6032
BRN :1730942
Exposure limits :ACGIH: TWA 50 ppm
Dielectric constant :4.5
Stability :Stable, but may form explosive peroxides in contact with air. Extremely flammable - note low flash point. Incompatible with strong oxidizing agents.
InChIKey :BZLVMXJERCGZMT-UHFFFAOYSA-N
LogP :1.06 at 20℃
CAS DataBase Reference :1634-04-4(CAS DataBase Reference)
IARC :3 (Vol. 73) 1999
NIST Chemistry Reference :Propane, 2-methoxy-2-methyl-(1634-04-4)
EPA Substance Registry System :Methyl tert-butyl ether (1634-04-4)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

Description

tert-Butyl methyl ether also known as MTBE and methyl tert-butyl ether, a combustible, clear, colorless liquid with a low viscosity and characteristic, turpentine-like odor. It is miscible with organic solvents, and is only slightly soluble in water. It forms azeotropic mixtures with some solvents such as methanol. Methyl tert-butyl ether is very stable under alkaline, neutral, and weakly acidic conditions. In the presence of strong acids, it is cleaved to methanol and isobutene. Depending on reaction conditions the latter can form isobutene oligomers. MTBE does not undergo autoxidation and, in contrast to other ethers, it does not form peroxides with atmospheric oxygen. It improves the antiknock properties when added to motor gasoline.

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