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CHLOROMETHYL METHYL SULFIDE

CHLOROMETHYL METHYL SULFIDE Structure
  • ₹2035.1 - ₹17000
  • Product name: CHLOROMETHYL METHYL SULFIDE
  • CAS: 2373-51-5
  • MF: C2H5ClS
  • MW: 96.58
  • EINECS:219-148-4
  • MDL Number:MFCD00000923
  • Synonyms:alpha-Chlorodimethyl sulfide;alpha-chlorodimethylsulfide ;chloro(methylthio)-methan ;chloro(methylthio)methane ;Chlorodimethyl thioether;chlorodimethylthioether ;Chloromethyl methyl thioether;chloromethylmethylthioether
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 5G
  • 10g
  • 25G
  • 50g
  • 100G
  • ManufacturerTCI Chemicals (India)
  • Product numberC0608
  • Product descriptionChloromethyl Methyl Sulfide min. 97.0 %
  • Packaging25G
  • Price₹5800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberC0608
  • Product descriptionChloromethyl Methyl Sulfide min. 97.0 %
  • Packaging100G
  • Price₹17000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberC54007
  • Product descriptionChloromethyl methyl sulfide 95%
  • Packaging5G
  • Price₹2035.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberC54007
  • Product descriptionChloromethyl methyl sulfide 95%
  • Packaging25G
  • Price₹5098.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberC54007
  • Product descriptionChloromethyl methyl sulfide 95%
  • Packaging100G
  • Price₹14689.53
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L10858-18
  • Product descriptionChloromethyl methyl sulfide, 94%
  • Packaging50g
  • Price₹12118
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L10858-09
  • Product descriptionChloromethyl methyl sulfide, 94%
  • Packaging10g
  • Price₹5092
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) C0608 Chloromethyl Methyl Sulfide min. 97.0 % 25G ₹5800 2022-05-26 Buy
TCI Chemicals (India) C0608 Chloromethyl Methyl Sulfide min. 97.0 % 100G ₹17000 2022-05-26 Buy
Sigma-Aldrich(India) C54007 Chloromethyl methyl sulfide 95% 5G ₹2035.1 2022-06-14 Buy
Sigma-Aldrich(India) C54007 Chloromethyl methyl sulfide 95% 25G ₹5098.58 2022-06-14 Buy
Sigma-Aldrich(India) C54007 Chloromethyl methyl sulfide 95% 100G ₹14689.53 2022-06-14 Buy
ALFA India ALF-L10858-18 Chloromethyl methyl sulfide, 94% 50g ₹12118 2022-05-26 Buy
ALFA India ALF-L10858-09 Chloromethyl methyl sulfide, 94% 10g ₹5092 2022-05-26 Buy

Properties

Boiling point :105 °C (lit.)
Density :1.153 g/mL at 25 °C (lit.)
refractive index :n20/D 1.498(lit.)
Flash point :63 °F
storage temp. :2-8°C
form :clear liquid
color :Colorless to Light orange to Yellow
Water Solubility :Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.
Sensitive :Moisture Sensitive
BRN :1730851
CAS DataBase Reference :2373-51-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.

Description

Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

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