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Poly(tetrahydrofuran)

Poly(tetrahydrofuran) Structure
CAS No.
25190-06-1
Chemical Name:
Poly(tetrahydrofuran)
Synonyms
ptmg;PTMEG 2000;ptmg1000;POLYTETRAHYDROFURAN;PTHF;PTMEG 1000;TETRAMETHYLENE ETHER GLYCOL 2000 POLYMER;ptmg2000;polymeg;PTMEG 250
CBNumber:
CB6323066
Molecular Formula:
(C4H8O)nH2O
Molecular Weight:
305.43
MOL File:
25190-06-1.mol
MSDS File:
SDS
Modify Date:
2024/7/2 17:04:22

Poly(tetrahydrofuran) Properties

Melting point 33-36 °C
Boiling point >204
Density 1 g/mL at 25 °C
vapor pressure <0.01 mm Hg ( 25 °C)
refractive index n20/D 1.465
Flash point >230 °F
storage temp. Store below +30°C.
solubility <10g/l
form Fused mass
Specific Gravity 0.961
PH 7 (H2O, 20℃)Aqueous solution
EPA Substance Registry System Poly(oxy-1,4-butanediyl), .alpha.-hydro-.omega.-hydroxy- (25190-06-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H412
Precautionary statements  P273
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  1
RTECS  MD0916000
TSCA  TSCA listed
HS Code  3907 20 20
Toxicity LD50 orally in Rabbit: > 5000 mg/kg

Poly(tetrahydrofuran) price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 8.18402 Polytetrahydrofuran 1000 (stabilised with 2,6-di-tert-butyl-4-methylphenol) for synthesis 25190-06-1 100G ₹3550.01 2022-06-14 Buy
Sigma-Aldrich(India) 345334 Poly(tetrahydrofuran) average Mn ~2,900 25190-06-1 25ML ₹3344.93 2022-06-14 Buy
Sigma-Aldrich(India) 8.18402 Polytetrahydrofuran 1000 (stabilised with 2,6-di-tert-butyl-4-methylphenol) for synthesis 25190-06-1 500G ₹7180 2022-06-14 Buy
Sigma-Aldrich(India) 345334 Poly(tetrahydrofuran) average Mn ~2,900 25190-06-1 1L ₹7490.9 2022-06-14 Buy
Sigma-Aldrich(India) 345334 Poly(tetrahydrofuran) average Mn ~2,900 25190-06-1 3L ₹17006.08 2022-06-14 Buy
Product number Packaging Price Buy
8.18402 100G ₹3550.01 Buy
345334 25ML ₹3344.93 Buy
8.18402 500G ₹7180 Buy
345334 1L ₹7490.9 Buy
345334 3L ₹17006.08 Buy

Poly(tetrahydrofuran) Chemical Properties,Uses,Production

Chemical Properties

mp 11 - 38 °C 100 - 4,400 mPa.s @ 40 °C

Definition

ChEBI: A macromolecule composed of repeating oxybutylene units.

Preparation

Low molecular weight polymers of tetrahydrofuran were introduced commercially in 1955. The polymers were intended for use in the preparation of flexible polyurethane foams, being terminated by hydroxyl groups:

25190-06-1 synthesis_1


Although these polyethers produced good foams they were rather expensive and were soon displaced by the cheaper propylene oxide-based polyethers. However, these polymers of tetrahydrofuran (commonly called poly(oxytetramethylene)glycol) now find use in the preparation of polyamide, polyester and polyurethane thermoplastic elastomers.
Details of the manufacture of polytetrahydrofuran have not been disclosed. Polymerization of tetrahydrofuran can be effected only by cationic initiators. Combinations of metal halides with water are not effective but protic acids (e.g. HCl04) and oxonium salts (e.g. (C2H5£?3O+BF4-) are efficient initiators. Polymerization occurs by a ring-opening mechanism involving a tertiary oxonium ion, e.g.

25190-06-1 synthesis_2

Poly(tetrahydrofuran) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 217)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Hebei Mojin Biotechnology Co., Ltd +86 13288715578 +8613288715578 China 12447 58 Inquiry
Hebei Yanxi Chemical Co., Ltd. +86-17531190177; +8617531190177 China 5873 58 Inquiry
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Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
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Xiamen AmoyChem Co., Ltd +86-592-6051114 +8618959220845 China 6387 58 Inquiry

Poly(tetrahydrofuran) Spectrum

4-butanediyl),.alpha.-hydro-.omega.-hydroxy-poly(oxy-1 alpha-hydro-omega-hydroxy-poly(oxy-4-butanediyl) b2000 glycols,polytetramethylene hiprenemc532 polifurit poly(butyleneoxide) poly(oxy-1,4-butylene)glycol poly(oxybutylene)glycol poly(oxytetramethylene) poly(oxytetramethylene)diol poly(tetramethyleneether) poly(tetramethyleneether)diol poly(tetramethyleneglycol) poly(tetramethyleneoxide)glycol polybutyleneglycol polyfurit polyfurit1000 polyfurite polymeg1000 polymeg1020 polymeg2000 polymeg2010 polymeg600 polymeg650 polytetramethyleneetherglycols polytetramethyleneglycol ptg100 ptg200 ptg300 ptg400 ptg500 ptg500p qopolymeg qopolymeg1000 teracol teracol1000 teracol2000 teracol30 teracol650 terathane terathane1000 terathane2900 Tetrahydrofuranhomopolymer POLYETETRAHYDROFURAN, LINEAR-CHAIN POLYMER POLY(1,4-OXYBUTYLENE) GLYCOL POLYTETRAHYDROFURAN 1000 POLYTETRAHYDROFURAN 1000 S POLYTETRAHYDROFURAN 1400 POLYTETRAHYDROFURAN 1800 POLY(TETRAMETHYLENE ETHER) GLYCOL POLYTETRAMETHYLENE ETHER GLYCOL 1000 POLYTETRAMETHYLENE ETHER GLYCOL 1000 S POLYTETRAHYDROFURAN 2000 POLYTETRAHYDROFURAN 250 POLYTETRAHYDROFURAN 650 S POLYTETRAHYDROFURAN, LINEAR-CHAIN POLYMER POLY(TETRAMETHYLENE OXIDE) 2,000