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CRUFOMATE

CAS No.: 299-86-5

Chemical Name:: CRUFOMATE

Synonyms: 4-t;M-1261;Rulene;MONTREL;Ruelene;Amidofos;Crufomat;dowdo132;DOWCO 132;CRUFOMATE

CBNumber:: CB4311757

Molecular Formula:: C12H19ClNO3P

Molecular Weight:: 291.71

MOL File:: 299-86-5.mol

Modify Date:: 2024/3/14 15:18:26

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CRUFOMATE Properties

Melting point	60℃
Boiling point	bp0.01 117-118°
Density	1.176
refractive index	nD20 1.5142
form	solid
pka	0.05±0.70(Predicted)
Water Solubility	4.975g/L(temperature not stated)
EPA Substance Registry System	Crufomate (299-86-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07,GHS09
Signal word	Warning
Hazard statements	H302-H312-H410
Precautionary statements	P264-P270-P301+P312-P330-P501-P280-P302+P352-P312-P322-P363-P501-P273-P391-P501
Hazard Codes	Xn,N
Risk Statements	21/22-50/53
Safety Statements	36/37-60-61
RIDADR	UN2783 (solid)
OEB	B
OEL	TWA: 5 mg/m3, STEL: 20 mg/m3
HS Code	29299090
Toxicity	LD50 in male, female rats (mg/kg): 635, 460 orally (Gaines)

CRUFOMATE Chemical Properties,Uses,Production

Chemical Properties

Crufomate is a white crystalline solid; the commercial product is a yellow oil.

General Description

White crystalline solid Mp: 61.5°C. The commercial product is a yellow oil. A phosphoramidate insecticide.

Reactivity Profile

CRUFOMATE is combustible; liquid formulations containing organic solvents may be flammable. Incompatible with strongly basic and strongly acidic materials. Unstable over long periods in aqueous preparations or above140°F. Emits toxic fumes of POx, Cl2 and NOx when heated to decomposition (Hazardous Chemicals Desk Reference p. 272 (1987)).

Hazard

Cholinesterase inhibitor. Questionable carcinogen.

Agricultural Uses

Insecticide, Anthelmintic (for cattle): All residue limits for crufomate, as listed in 40 CFR 180.295, were revoked by the U.S. EPA on June 9, 1993. All registered uses of crufomate in or on fat, meat, and meat byproducts of cattle, goats, and sheep were canceled It is applied as a spray on plants to kill insects, grubs, and worms on cattle. Not listed for use in EU countries

Trade name

DOWCO® 132[C]; MONTREL®[C]; RUELENE®[C]; DRENCH®[C]; RULENE®[C]

Potential Exposure

A potential danger to those involved in the manufacture, formulation, and application of this insecticide and anthelmintic for cattle.

Shipping

UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Contact with oxidizers may cause the release of phosphorous oxides. Contact with strong reducing agents, such as hydrides, may cause the formation of flammable and toxic phosphine gas. Decomposes on heating, forming corrosive and toxic fumes of hydrogen chloride and nitrogen and phosphorous oxides. Incompatible with strongly alkaline and strongly acidic media. Unstable over long periods in aqueous preparations or above 60°C.

Waste Disposal

Crufomate decomposes above pH 7.0 in alkaline media. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

CRUFOMATE Preparation Products And Raw materials

Raw materials

Preparation Products

CRUFOMATE Suppliers

Global( 66)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	China	2931	58	Inquiry
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	China	39916	58	Inquiry
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	United States	19892	58	Inquiry
AFINE CHEMICALS LIMITED	+86-0571-85134551	China	15395	58	Inquiry
Shaanxi Didu New Materials Co. Ltd	+86-89586680 +86-13289823923	China	9003	58	Inquiry
SUZHOU SENFEIDA CHEMICAL CO.,LTD	+86-0512-83500002 +8615195660023	China	10814	58	Inquiry
Shanghai Likang New Materials Co., Limited	+86-16631818819 +86-17736933208	China	9311	58	Inquiry
Amadis Chemical Company Limited	571-89925085	China	131980	58	Inquiry
LGC Standards	+44 (0)20 8943 8480	United Kingdom	6495	0	Inquiry

Supplier	Advantage
CLEARSYNTH LABS LTD.	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Chongqing Chemdad Co., Ltd	58
TargetMol Chemicals Inc.	58
AFINE CHEMICALS LIMITED	58
Shaanxi Didu New Materials Co. Ltd	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	58
Shanghai Likang New Materials Co., Limited	58
Amadis Chemical Company Limited	58
LGC Standards	0

299-86-5(CRUFOMATE)Related Search:

Phoxim Phosmet Metasystox CRUFOMATE 4-tert-Butyl-2-chlorophenol

TRIMETHYLPHOSPHORAMIDE

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RUELENE (TM) MONTREL crufomate (bsi,iso,ansi) 4-TERT-BUTYL-2-CHLOROPHENYLMETHYLMETHYLPHOSPHORAMIDE (4-tetra-Butyl-2-chlorophenylmethyl methylphosphoramidate crufomat (ISO) 4-tert-butyl-2-chlorophenyl methyl methylphosphoramidate DOWCO 132 ENT 25602-X CRUFOMATE Cruformate(content>90%) Cruformate emulsion(content>20%) 2-chloro-4-(1,1-dimethylethyl)phenylmethylmethylphosphoramidate 4-t-butyl-2-chloro-phenoesterwithmethylmethylphosphoramidate 4-t-Butyl-2-chlorophenyl methyl methylphosphoramidate 4-t-butyl-2-chlorophenylmethylmethylphosphoramidate 4-tert.butyl2-chlorophenylmethylphosphoramidatedemethyle 4-tert.butyl2-chlorophenylmethylphosphoramidatedemethyle(french) 4-tert-Butyl-2-chlorophenyl methyl methylamidophosphate 4-tert-Butyl-2-Chlorophenyl methyl methylphosphoramidate 4-tert-Butyl-2-chlorophenyl O-methyl methylphosphoroamidate 4-tert-butyl-2-chlorophenylmethylmethylphosphoramidate 4-tert-butyl-2-chlorophenyln-methylo-methylphosphoramidate Amidofos Amidophos Crufomat Crufomate A crufomatea Cruformate dowdo132 M-1261 Methylphosphoramidic acid, 4-t-butyl-2-chlorophenyl methyl ester Methylphosphoramidic acid, 4-tert-butyl-2-chlorophenyl methyl ester methyl-phosphoramidicaci4-tert-butyl-2-chlorophenylmethylester methylphosphoramidicacid,4-t-butyl-2-chlorophenylmethylester methylphosphoramidicacid2-chloro-4-(1,1-dimethylethyl)phenylmethylester methylphosphoramidicacid4-tert-butyl-2-chlorophenylmethylester N,O-Dimethyl-o-(4-tert-butyl-2-chlorophenyl)phosphoramidate O-(4-tert Butyl-2-chloor-fenyl)-O-methyl-fosforzuur-N-methyl-amide o-(4-tertbutyl-2-chloor-fenyl)-o-methyl-fosforzuur-n-methyl-amide O-(4-tert-Butyl-2-chlorophenyl) O-methyl N-methylamido phosphate o-(4-tert-butyl-2-chlorophenyl)o-methyln-methylamidophosphate o-(4-tert-Butyl-2-chlor-phenyl)-O-methyl-phosphorsaeure-N-methylamid O-(4-Terz.-butil-2-cloro-fenil)-O-metil-fosforammide O-Methyl O-2-chloro-4-tert-butylphenyl N-methylamidophosphate o-methyl-o-(4-tert-butyl-2-chlorophenyl)methylphosphoramidate ruelenedrench Rulene 4-TERT-BUTYL-2-CHLOROPHENYLMETHYL-N-METHYL-PHOSPHORAMIDATE 4-TERT-BUTYL-2-CHLOROPHENYL METHYLPHOSPHORAMIDATE 4-t (RS)-4-tert-Butyl-2-chlorophenyl methyl methylphosphoramidate [(4-tert-butyl-2-chloro-phenoxy)-methoxy-phosphoryl]-methyl-amine N-[(4-tert-butyl-2-chloro-phenoxy)-methoxy-phosphoryl]methanamine N-[(4-tert-butyl-2-chlorophenoxy)-methoxyphosphoryl]methanamine Ruelene (TM) 50mg [299-86-5] 4-tert-Butyl-2-chlorophenyl Methyl N- NSC 253463 o-methylo-2-chloro-4-tert-butylphenyln-methylamidophosphate