Triallylamine
- CAS No.
- 102-70-5
- Chemical Name:
- Triallylamine
- Synonyms
- TAA;Trialkylamine;N,N-Diallyl-2-propen-1-amine;2-Propen-1-amine, N,N-di-2-propen-1-yl-;tertiaryamine;(CH2=CHCH2)3N;TRIALLYLAMINE;triallylaMate;TRIALLYAMINE HCL;Triallylamine 99%
- CBNumber:
- CB4359230
- Molecular Formula:
- C9H15N
- Molecular Weight:
- 137.22
- MOL File:
- 102-70-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/12/25 13:23:17
| Melting point | -70°C |
|---|---|
| Boiling point | 150-151 °C (lit.) |
| Density | 0.79 g/mL at 25 °C (lit.) |
| vapor density | 4.73 (vs air) |
| vapor pressure | 90 mm Hg ( 80 °C) |
| refractive index |
n |
| Flash point | 87 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| pka | pK1:8.31(+1) (25°C) |
| color | Colorless to Yellow to Orange |
| Water Solubility | 250 g/100 mL |
| Stability | Stable. Flammable. Incompatible with strong oxidizing agents. |
| InChIKey | VPYJNCGUESNPMV-UHFFFAOYSA-N |
| CAS DataBase Reference | 102-70-5(CAS DataBase Reference) |
| NIST Chemistry Reference | 2-Propen-1-amine, N,N-di-2-propenyl-(102-70-5) |
| EPA Substance Registry System | Triallylamine (102-70-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H302+H312-H314-H331 | |||||||||
| Precautionary statements | P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 10-20/21/22-34 | |||||||||
| Safety Statements | 16-26-36/37/39-45 | |||||||||
| RIDADR | UN 2610 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | XX5950000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29211990 | |||||||||
| NFPA 704 |
|
Triallylamine price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | T45004 | Triallylamine 99% | 102-70-5 | 250ML | ₹3777.93 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | T45004 | Triallylamine 99% | 102-70-5 | 1L | ₹12080.7 | 2022-06-14 | Buy |
| ALFA India | ALF-A12081-30 | Triallylamine, 97% | 102-70-5 | 250g | ₹4765 | 2022-05-26 | Buy |
| TCI Chemicals (India) | T0332 | Triallylamine min. 95.0 % | 102-70-5 | 25ML | ₹2100 | 2022-05-26 | Buy |
| ALFA India | ALF-A12081-18 | Triallylamine, 97% | 102-70-5 | 50g | ₹1549 | 2022-05-26 | Buy |
Triallylamine Chemical Properties,Uses,Production
Chemical Properties
Triallylamine is a flammble liquid. Triallylamine can be detected at 0.5 ppm and is severely irritating at 75 ppm.
Uses
Triallylamine is used in organic synthesis.Triallylamine has been proposed as a catalyst for the production of polyesters and as an initiator for the polymerization of butadiene.
Application
Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.
TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines.
Production Methods
Triallylamine is manufactured using allyl chloride and ammonia under heat and pressure. It is used as a solvent and in organic syntheses.
General Description
A colorless liquid with a fishlike odor. Density 0.800 g / cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.
Air & Water Reactions
Flammable. Insoluble in water.
Reactivity Profile
Triallylamine is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn [Handling Chemicals Safely 1980 p. 912] . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Health Hazard
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Profile
Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion and inhalation. An eye and severe skin irritant. Human systemic effects by inhalation: structural or functional changes in trachea or bronchi. Flammable liquid when exposed to heat, flame or oxidlzers. To fight fire, use foam, alcohol foam, fog. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALLYL COMPOUNDS.
Triallylamine Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Black Rose Industries Ltd. | 91-22-43337200 | Maharashtra, India | 45 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | China | 12460 | 58 | Inquiry |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20324 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | China | 2989 | 55 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29900 | 58 | Inquiry |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | China | 8828 | 58 | Inquiry |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | China | 6387 | 58 | Inquiry |
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