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BARBAN

BARBAN Structure
CAS No.
101-27-9
Chemical Name:
BARBAN
Synonyms
Oatax;A 980;a-980;C-847;S 847;s-847;BARBAN;Carbin;Caryne;CS-847
CBNumber:
CB4405478
Molecular Formula:
C11H9Cl2NO2
Molecular Weight:
258.1
MOL File:
101-27-9.mol
Modify Date:
2023/4/23 13:52:06

BARBAN Properties

Melting point 75-76℃
Boiling point 340.8±32.0 °C(Predicted)
Density 1.403
refractive index 1.6070 (estimate)
storage temp. 0-6°C
form Powder/Solid
pka 12.30±0.70(Predicted)
color White
Water Solubility 11mg/L(25 ºC)
Merck 13,962
BRN 2376181
EPA Substance Registry System Barban (101-27-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H317-H410
Precautionary statements  P273-P280-P501
Hazard Codes  Xn,N
Risk Statements  22-43-50/53
Safety Statements  24-36/37-60-61
RIDADR  UN3077 9/PG 3
WGK Germany  3
RTECS  FD7700000
HS Code  29242990
Toxicity LD50 orally in rats: 600 mg/kg (Bailey, White)

BARBAN Chemical Properties,Uses,Production

Chemical Properties

Crystalline solid; melts at 75°C (167°F);insoluble in water [11 mg/L at 25°C (77°F)];slightly soluble in hexane; soluble in benzeneand chlorinated hydrocarbons.

Uses

Barban is used as a selective herbicide forwild oats.

Definition

ChEBI: A carbamate ester that is 4-chlorobut-2-yn-1-yl ester of N-(3-chlorophenyl)carbamic acid. A herbicide, it is no longer approved for use within the European Community.

General Description

Crystalline solid. Water solubility is 11 ppm at 20°C. Used as a selective herbicide.

Air & Water Reactions

Hydrolyzed by strong acid or base.

Reactivity Profile

BARBAN is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Health Hazard

Moderately toxic by ingestion and inhalation;absorption through skin may be very slowand, therefore, almost nontoxic by dermalroute; used as a herbicide, rather than as apesticide; toxic symptoms are those of othercarbamate esters;
LD50 oral (rat): 600 mg/kg
LD50 skin (rabbit): >20,000 mg/kg.

BARBAN Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 46)Suppliers
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CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
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Aladdin Scientific +1-+1(833)-552-7181 United States 57511 58 Inquiry
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United States Biological 800.520.3011 or 781.639.5092 United States 6256 80 Inquiry
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(3-Chlorophenyl)carbamic acid 4-chloro-2-butynyl ester (3-chlorophenyl)-carbamicaci4-chloro-2-butynylester (3-chlorophenyl)carbamicacid4-chloro-2-butynylester (4-Chloor-but-2-yn-yl)-N-(3-chloor-fenyl)-carbamaat (4-Chlor-but-2-in-yl)-N-(3-chlor-phenyl)-carbamat (4-Cloro-but-2-in-il)-N-(3-cloro-fenil)-carbammato 2-Butyn-1-ol, 4-chloro-, m-chlorocarbanilate 2-Butynyl 4-chloro-m-chlorocarbanilate 2-butynyl-4-chloro-m-chlorocarbanilate 4-chloro-2-butyn-1-om-chlorocarbanilate 4-Chloro-2-butynyl 3-chlorocarbanilate 4-Chloro-2-butynyl 3-chlorophenylcarbamate 4-chloro-2-butynyl3-chlorocarbanilate barban (ISO) 4-chlorbut-2-ynyl N-(3-chlorophenyl)carbamate Carbyne【pesticide】 Oatax 4-chlorbut-2-ynyl N-(3-chlorophenyl)carbamate,barban (ISO) 4-chloro-2-butynyl-N-(3-chlorphenyl)carbamate Barban 100mg [101-27-9] 4-[N-(3-Chlorophenyl)carbamoyloxy]-1-chloro-2-butyne A 980 (herbicide) NSC 29168 3-CHLOROCARBANILIC ACID 4-CHLORO-2-BUTYNYL ESTER 4-Chlorobut-2-yn-1-yl (3-chlorophenyl)carbamate CARBYNE(R) BARBAMATE(R) BARBAN BARBANATE ENT 28201 4-CHLORO-2-BUTYNYL-M-CHLOROCARBANILATE 4-CHLORO-2-BUTYNYL N-(3-CHLOROPHENYL)CARBAMATE 4-CHLOROBUT-2-YNYL-3-CHLOROPHENYLCARBAMATE 4-Chloro-2-butynyl3-Chlorophenylcarbamate 4-chloro-2-butynylmeta-chlorocarbanilate 4-Chlorobut-2-ynyl-m-chlorocarbanilate barban (ansi,bsi,wssa,iso) CARBANILICACID,META-CHLORO-,4-CHLORO-2-BUTYNYLESTER (4-chloor-but-2-yn-yl)-n-(3-chloor-fenyl)-carbamaat (dutch) BARBAN, 100MG, NEAT BARBAN PESTANAL. A 980 a-980 Barbamate Barbane C-847 Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester carbamicacid,(3-chlorophenyl)-,4-chloro-2-butynylester Carbanilic acid, m-chloro-, 4-chloro-2-butynyl ester carbanilicacid,m-chloro-,4-chloro-2-butynylester Carbin Carbine Carbyne Carbyne (Herbicide) carbyne(herbicide) Caryne Chlorinat Chloro-2-butynyl m-chlorocarbamate chloro-2-butynylm-chlorocarbamate