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3-Chloroaniline

3-Chloroaniline Structure
CAS No.
108-42-9
Chemical Name:
3-Chloroaniline
Synonyms
M-CHLOROANILINE;3-CHLOROBENZENAMINE;ORANGE GC BASE;1,3-aminochlorobenzene;oroaniL;CI 37005;3-Chloranilin;3-Cloroaniline;m-Chloraniline;3-Chloraniline
CBNumber:
CB9697982
Molecular Formula:
C6H6ClN
Molecular Weight:
127.57
MOL File:
108-42-9.mol
Modify Date:
2024/3/19 15:37:50

3-Chloroaniline Properties

Melting point −11-−9 °C(lit.)
Boiling point 95-96 °C11 mm Hg(lit.)
Density 1.206 g/mL at 25 °C(lit.)
vapor pressure 1 mm Hg ( 63.5 °C)
refractive index n20/D 1.594(lit.)
Flash point 255 °F
storage temp. Store below +30°C.
solubility 6.2g/l
pka 3.46(at 25℃)
form Liquid
color Clear pale yellow to brown
PH 7.3 (H2O)(saturated aqueous solution)
Odor Characteristic odour
Water Solubility 6.8 g/L (20 ºC)
Decomposition 190°C
Merck 14,2118
BRN 605969
Dielectric constant 13.4(19℃)
Stability Material darkens in storage with no loss in purity, Material Darkens In Storage
LogP 0.77-2.03 at 25-30℃
CAS DataBase Reference 108-42-9(CAS DataBase Reference)
NIST Chemistry Reference m-Chloroaniline(108-42-9)
EPA Substance Registry System m-Chloroaniline (108-42-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311-H317-H319-H330-H373-H410
Precautionary statements  P273-P280-P302+P352+P312-P304+P340+P310-P305+P351+P338-P314
Hazard Codes  T,N
Risk Statements  23/24/25-33-50/53
Safety Statements  28-36/37-45-60-61-28A
RIDADR  UN 2019 6.1/PG 2
WGK Germany  2
RTECS  BX0350000
8-10-23
Autoignition Temperature 705 °C
Hazard Note  Toxic
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29214210
Toxicity LD50 orally in Rabbit: 256 mg/kg LD50 dermal Rat 250 mg/kg
NFPA 704
0
2 0

3-Chloroaniline price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) C22407 3-Chloroaniline 99% 108-42-9 5G ₹2890.28 2022-06-14 Buy
Sigma-Aldrich(India) C22407 3-Chloroaniline 99% 108-42-9 500G ₹3604.73 2022-06-14 Buy
Sigma-Aldrich(India) C22407 3-Chloroaniline 99% 108-42-9 100G ₹4416.6 2022-06-14 Buy
TCI Chemicals (India) C0110 3-Chloroaniline min. 99.0 % 108-42-9 25ML ₹1500 2022-05-26 Buy
ALFA India ALF-A12019-36 3-Chloroaniline, 99% 108-42-9 500g ₹3429 2022-05-26 Buy
Product number Packaging Price Buy
C22407 5G ₹2890.28 Buy
C22407 500G ₹3604.73 Buy
C22407 100G ₹4416.6 Buy
C0110 25ML ₹1500 Buy
ALF-A12019-36 500g ₹3429 Buy

3-Chloroaniline Chemical Properties,Uses,Production

Chemical Properties

3-Chloroaniline is a clear pale yellow to brown liquid, which becomes darker during storage, insoluble in water, but soluble in ethanol, ether and acid solution.

Application

3-Chloroaniline is the intermediate of the herbicide chloraniline, and the intermediate of the pharmaceutical diuretic antihypertensive drug hydrochlorothiazide, and can be used to produce azo dyes.
3-Chloroaniline was the only aniline compound to increase plasmaALT/GPT activity at 48 h. It is employed in the bioaugmentation of activated sludge.

Preparation

3-Chloroaniline is obtained by reducing 3-Nitrochlorobenzene with iron powder in the presence of ferrous sulfate.

General Description

Colorless to light amber liquid with a sweet odor.

Air & Water Reactions

Sensitive to prolonged exposure to air and light and tends to darken during storage. Insoluble in water.

Reactivity Profile

3-Chloroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.

Fire Hazard

3-Chloroaniline is combustible.

Safety Profile

Poison by ingestion, skin contact, subcutaneous, and intravenous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland NOx. See also ANILINE DYES.

Global( 497)Suppliers
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