1-Chloro-3-nitrobenzene
- CAS No.
- 121-73-3
- Chemical Name:
- 1-Chloro-3-nitrobenzene
- Synonyms
- 1-CHLORO-3-NITROBENZENE;mncb;3-CHLORONITROBENZENE;M-NITROCHLOROBENZENE;1-chloronitrobenzene;M-CHLORONITROBENZENE;1-nitro-3-chlorobenzene;1-Chloro-3;3-Chlornitrobenzol;3-NITROCHLOROBENZENE
- CBNumber:
- CB8747505
- Molecular Formula:
- C6H4ClNO2
- Molecular Weight:
- 157.55
- MOL File:
- 121-73-3.mol
- Modify Date:
- 2023/12/1 11:17:17
| Melting point | 43-47 °C(lit.) |
|---|---|
| Boiling point | 236 °C(lit.) |
| Density | 1.534 g/mL at 25 °C(lit.) |
| vapor pressure | 1.9Pa at 25℃ |
| refractive index | 1.5545 (estimate) |
| Flash point | 218 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: freely soluble (hot)(lit.) |
| form | powder to lump to clear liquid |
| color | White or Colorless to Yellow |
| PH | 7 (0.26g/l, H2O, 20℃) |
| Water Solubility | INSOLUBLE |
| Merck | 14,2151 |
| BRN | 1907947 |
| Stability | Stable. Incompatible with strong oxidizing agents, strong acids, strong reducing agents. |
| LogP | 2.49 |
| CAS DataBase Reference | 121-73-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, 1-chloro-3-nitro-(121-73-3) |
| EPA Substance Registry System | m-Chloronitrobenzene (121-73-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H311-H412 | |||||||||
| Precautionary statements | P264-P270-P273-P280-P301+P312-P302+P352+P312 | |||||||||
| Hazard Codes | Xn,N,T | |||||||||
| Risk Statements | 22-50/53-23/24/25 | |||||||||
| Safety Statements | 22-24/25-60-61-45-38-36/37/39-28A | |||||||||
| RIDADR | UN 1578 6.1/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | CZ0940000 | |||||||||
| Autoignition Temperature | 500 °F | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29049085 | |||||||||
| Toxicity | mouse,LD50,oral,380mg/kg (380mg/kg),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(8), Pg. 50, 1981. | |||||||||
| NFPA 704 |
|
1-Chloro-3-nitrobenzene price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 218758 | 1-Chloro-3-nitrobenzene 98% | 121-73-3 | 250G | ₹4494.3 | 2022-06-14 | Buy |
| TCI Chemicals (India) | C0221 | 1-Chloro-3-nitrobenzene min. 99.0 % | 121-73-3 | 25G | ₹1500 | 2022-05-26 | Buy |
| TCI Chemicals (India) | C0221 | 1-Chloro-3-nitrobenzene min. 99.0 % | 121-73-3 | 500G | ₹6100 | 2022-05-26 | Buy |
| ottokemi | N 1805 | 3-Nitrochlorobenzene 99% | 121-73-3 | 250gm | ₹693 | 2022-05-26 | Buy |
| ottokemi | N 1805 | 3-Nitrochlorobenzene 99% | 121-73-3 | 500gm | ₹1107 | 2022-05-26 | Buy |
1-Chloro-3-nitrobenzene Chemical Properties,Uses,Production
Chemical Properties
Moist tan or pale yellow crystalline solid
Uses
Intermediate for dyes. 1-Chloro-3-nitrobenzene was used in the preparation of aromatic azo compounds using gold (Au) nanoparticles supported on TiO2 as a catalyst. It was also used as surrogate standard to evaluate the removal of 2,4-dinitrotoluene from contaminated soils using enhanced electrokinetic remediation.
Production Methods
m-Chloronitrobenzene is of lesser economic importance
than its ortho- and para-isomers, with no U.S. production reported. The annual production in Germany was
reported to be on the order of 1000–3000 metric tons. It
has limited use in the manufacturing of dyes and agricultural
chemicals.
There is no information on potential exposure. Chloronitrobenzene
has been detected in the surface water of the
Rhine River with concentrations between 20 and 500 ng/L
and in fish at levels of up to 1 mg/kg.
General Description
Pale yellow crystals. Insoluble in water.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
3-Nitrochlorobenzene can react with oxidizing materials. .
Hazard
Toxic by inhalation and ingestion. Combustible. Questionable carcinogen.
Fire Hazard
Flash point data for 3-Nitrochlorobenzene are not available. 3-Nitrochlorobenzene is probably combustible.
Safety Profile
Poison by ingestion and inhalation. It forms methemoglobin in the body and gves rise to cyanosis and blood changes. Its effects are cumulative and analogous to those of nitrobenzene. The para compound is thought to be somewhat less toxic than the ortho compound. Chemically, it is probably converted in the body to chloroaniline, whch is also poisonous. In industry, it is the dust of hs material that is most often the source of intoxication. Flammable liquid and dangerous fire hazard when exposed to heat or flame. It can react with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl-, NOx, and phosgene. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
Synthesis
1-Chloro-3-nitrobenzene was synthesised from 4-chloro-2-nitro-benzoic acid by adding copper iodide, triethylamine and dimethyl sulfoxide in the presence of inert gas using the Schlenk technique.
Purification Methods
Crystallise the nitrobenzene from MeOH or 95% EtOH (charcoal), then pentane. [Beilstein 5 IV 722.]
1-Chloro-3-nitrobenzene Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
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| SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8615195660023 | China | 23053 | 58 | Inquiry |
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