4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Structure
CAS No.
53413-67-5
Chemical Name:
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Synonyms
6-NITROVERATRYL BROMIDE;1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;4,5-dimenoxy-2-nitrobenzyl bromide;3,4-Dimethoxy-6-nitrobenzyl bromide;4,5-DIMETHOXY-2-NITROBENZYL BROMIDE;4,5-Dimethoxy-2-nitrobenzyl bromide 95%;4,5-Dimethoxy-2-nitro-1-bromomethylbenzene;1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene
CBNumber:
CB4762285
Molecular Formula:
C9H10BrNO4
Molecular Weight:
276.08
MOL File:
53413-67-5.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Properties

Melting point 131-133 °C (lit.)
Boiling point 372.3±37.0 °C(Predicted)
Density 1.544
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Crystalline Powder or Needles
color Yellow to brown
Sensitive Lachrymatory

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  22-26-27-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
HazardClass  8
PackingGroup  III
HS Code  29093090

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 53413-67-5 1G ₹8100 2022-06-14 Buy
Sigma-Aldrich(India) 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 53413-67-5 5G ₹31910 2022-06-14 Buy
Product number Packaging Price Buy
392855 1G ₹8100 Buy
392855 5G ₹31910 Buy

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Chemical Properties,Uses,Production

Uses

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis of N-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid. It may be used in the synthesis of the following:

  • 4-(4′,5′-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehyde
  • N-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamide
  • caged derivative of pyridostatin ([C]-PDS)
  • photosensitive polyimide (PI-DMNB)
  • caged β-ecdysone
  • 4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SBNV) nucleobase
  • alkylation of dihydrofluorescein
  • 4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde

General Description

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNBB, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene) is a 4,5-dimethoxy-2-nitrobenzyl derivative. 4,5-Dimethoxy-2-nitrobenzyl (DMNB) group of DMNBB is used as a photolabile protecting group in caging technology to develop pro-drugs. Synthesis of 1-(bromomethyl)-4,5-dimethoxy-2-nitrobenzene by using 6-nitroveratraldehyde as starting reagent has been reported.

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Suppliers

Global( 78)Suppliers
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A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
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Aladdin Scientific +1-+1(833)-552-7181 United States 57511 58 Inquiry
Amadis Chemical Company Limited 571-89925085 China 131980 58 Inquiry
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE 4,5-Dimethoxy-2-nitrobenzyl bromide 95% 1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene 4,5-dimenoxy-2-nitrobenzyl bromide 3,4-Dimethoxy-6-nitrobenzyl bromide 4,5-Dimethoxy-2-nitro-1-bromomethylbenzene -4,5-dimethoxy-2-nitrobenzene JR-13611, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene, 97% Benzene, 1-(bromomethyl)-4,5-dimethoxy-2-nitro- -4,5-dimethoxy-2-nitrobenzene 6-NITROVERATRYL BROMIDE 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene 53413-67-5 O2NC6H2OCH32CH2Br Organic Building Blocks Nitrogen Compounds Nitro Compounds Building Blocks