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4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Structure
  • ₹8100 - ₹31910
  • Product name: 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
  • CAS: 53413-67-5
  • MF: C9H10BrNO4
  • MW: 276.08
  • EINECS:
  • MDL Number:MFCD00192064
  • Synonyms:4,5-DIMETHOXY-2-NITROBENZYL BROMIDE;4,5-Dimethoxy-2-nitrobenzyl bromide 95%;1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene;4,5-dimenoxy-2-nitrobenzyl bromide;3,4-Dimethoxy-6-nitrobenzyl bromide;4,5-Dimethoxy-2-nitro-1-bromomethylbenzene;-4,5-dimethoxy-2-nitrobenzene;JR-13611, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene, 97%
Price2 Properties Safety Information Description
2 prices
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Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number392855
  • Product description4,5-Dimethoxy-2-nitrobenzyl bromide 97%
  • Packaging1G
  • Price₹8100
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number392855
  • Product description4,5-Dimethoxy-2-nitrobenzyl bromide 97%
  • Packaging5G
  • Price₹31910
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 1G ₹8100 2022-06-14 Buy
Sigma-Aldrich(India) 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 5G ₹31910 2022-06-14 Buy

Properties

Melting point :131-133 °C (lit.)
Boiling point :372.3±37.0 °C(Predicted)
Density :1.544
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Crystalline Powder or Needles
color :Yellow to brown
Sensitive :Lachrymatory

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.

Description

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis ofN-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid.It may be used in the synthesis of the following:4-(4’,5’-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehydeN-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamidecaged derivative of pyridostatin ([C]-PDS)photosensitive polyimide (PI-DMNB)caged β-ecdysone4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SBNV) nucleobasealkylation of dihydrofluorescein4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde

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