N-Benzyl-N-ethylaniline
- CAS No.
- 92-59-1
- Chemical Name:
- N-Benzyl-N-ethylaniline
- Synonyms
- Benzylethylaniline;ETHYLBENZYLANILINE;N-Benzyl-N-ethylanil;n-ethylbenzylaniline;N-Ethyl-N-benzylanilin;ETHYLPHENYLBENZYLAMINE;Phenylethylbenzylamine;Benzylethylphenylamine;N,N-Benzylethylaniline;N-ETHYL-N-BENZYLANILINE
- CBNumber:
- CB4854654
- Molecular Formula:
- C15H17N
- Molecular Weight:
- 211.3
- MOL File:
- 92-59-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/8/14 13:33:12
| Melting point | 34-36°C |
|---|---|
| Boiling point | 163-164 °C6 mm Hg(lit.) |
| Density | 1.029 g/mL at 25 °C(lit.) |
| vapor pressure | 0.013Pa at 20℃ |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: soluble1ml in 5.5ml |
| pka | 5.24±0.50(Predicted) |
| Water Solubility | <0.1 g/100 mL at 22 ºC |
| Merck | 14,3769 |
| BRN | 2099852 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents, acids. |
| LogP | 4.38 at 25℃ |
| CAS DataBase Reference | 92-59-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenemethanamine, N-ethyl-N-phenyl-(92-59-1) |
| EPA Substance Registry System | N-Ethyl-N-phenylbenzylamine (92-59-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H312-H302+H312 | |||||||||
| Precautionary statements | P280-P264-P270-P280h-P301+P312a-P321-P501a | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 21/22-20/21/22 | |||||||||
| Safety Statements | 36/37 | |||||||||
| RIDADR | UN 2274 6.1/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| F | 8-23 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29214990 | |||||||||
| NFPA 704 |
|
N-Benzyl-N-ethylaniline Chemical Properties,Uses,Production
Chemical Properties
colourless or light yellow oily liquid
Uses
N-Benzyl-N-ethylaniline was used in a study to investigate the electron transfer quenching dynamics of excited perylene and cyanoperylene in various donating solvents.
General Description
A colorless to light colored liquid. Insoluble in water and denser than water. Hence sinks in water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
N-Benzyl-N-ethylaniline neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Hazard
Toxic by ingestion and inhalation.
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Purification Methods
Dry the amine over KOH pellets and fractionate it. The picrate crystallises from *C6H6 as lemon yellow crystals m 126-128o (softening at 120o). [Forrest et al. J Chem Soc 303 1951, IR: Hill & Meakins J Chem Soc 760 1958, Beilstein 12 H 1026, 12 IV 2176.]
N-Benzyl-N-ethylaniline Preparation Products And Raw materials
Raw materials
Preparation Products
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