ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >HEXARHODIUM HEXADECACARBONYL
HEXARHODIUM HEXADECACARBONYL
- CAS No.
- 28407-51-4
- Chemical Name:
- HEXARHODIUM HEXADECACARBONYL
- Synonyms
- RHODIUM CARBONYL;rhodium(0) carbonyl;[Rh6(CO)12(μ3-CO)4];rhodium hexacarbonyl;Hexadecacarbonylhexa;Carbon Monoxide rhodiuM;HEXADECACARBONYLHEXARHODIUM;HEXARHODIUM HEXADECACARBONYL;HEXADECACARBONYLHEXARHODIUM (0);hexarhodium(0) hexadecacarbonyl
- CBNumber:
- CB5101874
- Molecular Formula:
- C16O16Rh6
- Molecular Weight:
- 1065.59
- MOL File:
- 28407-51-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
| Melting point | 238-242°C |
|---|---|
| Density | 2,87 g/cm3 |
| solubility | Very sparingly soluble in chloroform, carbon tetrachloride and dichloromethane |
| form | crystal |
| Specific Gravity | 2.87 |
| color | black |
| Sensitive | Air Sensitive |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| EPA Substance Registry System | Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro (28407-51-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332 | |||||||||
| Precautionary statements | P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22 | |||||||||
| Safety Statements | 36/37 | |||||||||
| RIDADR | 1325 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| NFPA 704 |
|
HEXARHODIUM HEXADECACARBONYL price More Price(3)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 247650 | Hexarhodium(0) hexadecacarbonyl Rh 57-60?% (approx.) | 28407-51-4 | 1G | ₹34254.6 | 2022-06-14 | Buy |
| ALFA India | ALF-B24185-77 | Hexarhodium hexadecacarbonyl, 98% | 28407-51-4 | 0.1g | ₹3951 | 2022-05-26 | Buy |
| ALFA India | ALF-B24185-02 | Hexarhodium hexadecacarbonyl, 98% | 28407-51-4 | 0.5g | ₹45190 | 2022-05-26 | Buy |
HEXARHODIUM HEXADECACARBONYL Chemical Properties,Uses,Production
Chemical Properties
black crystal(s); cluster structure; used as a catalyst [COT88] [ALD94] [ALF95]
Uses
Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds
Purification Methods
It slowly loses CO when heated in air, but may be regenerated by heating at 80-200o in the presence of CO at 200atmospheres pressure for 15hours, preferably in the presence of Cu. It forms black crystals which are insoluble in hexane. It has bands at 2073, 2026 and 1800cm-1 in the IR. [Hieber & Lagally Z Anorg Allgem Chem 251 96 1963, Corey & Dahl J Am Chem Soc 85 1202 1963, Doyle et al. Tetrahedron Lett 22 1783 1981.] POISONOUS.
HEXARHODIUM HEXADECACARBONYL Preparation Products And Raw materials
Raw materials
Preparation Products
HEXARHODIUM HEXADECACARBONYL Suppliers
Global( 103)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Hindustan Platinum Pvt., Ltd. | 91-22-61904199 | Maharashtra, India | 53 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21676 | 55 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29826 | 58 | Inquiry |
| SIMAGCHEM CORP | +86-13806087780 | China | 17367 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | China | 34571 | 58 | Inquiry |
| Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 | China | 2255 | 58 | Inquiry |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | China | 9030 | 58 | Inquiry |
28407-51-4(HEXARHODIUM HEXADECACARBONYL)Related Search:
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HEXARHODIUM HEXADECACARBONYL
HEXADECACARBONYLHEXARHODIUM
HEXADECACARBONYLHEXARHODIUM (0)
RHODIUM CARBONYL
Rhodium carbonyl (Hexarhodium hexadecacarbonyl)
tetra-mu3-carbonyldodecacarbonyl-octahedro-hexarhodium
HEXARHODIUM(0) HEXADECACARBONYL, 57-60% RH
Hexarhodiumhexadecacarbonyl,min.98%
hexarhodium(0) hexadecacarbonyl
rhodium hexacarbonyl
rhodium(0) carbonyl
Hexarhodium hexadecacarbonyl,98%
Hexadecacarbonylhexa
Hexadecacarbonylhexarhodium, 98+%
Hexarhodium hexadecacarbonyl, min. 98%
Carbon Monoxide rhodiuM
Hexarhodium(0) hexadecacarbonyl Rh 57-60 % (approx.)
Carbon monooxide - rhodium (8:3)
[Rh6(CO)12(μ3-CO)4]
HEXARHODIUM HEXADECACARBONYL ISO 9001：2015 REACH
28407-51-4
Rh6CO16
C16O16Rh6
16CORh6
Catalysis and Inorganic Chemistry
metal carbonyl complexes