Chinese english Japanese Germany Korea
ChemicalBook > Product Catalog >Inorganic chemistry >Inorganic salts >Rare Earth Metals Oxides >Platinum dioxide

Platinum dioxide

Platinum dioxide Structure
CAS No.
1314-15-4
Chemical Name:
Platinum dioxide
Synonyms
PtO2;PLATINUM OXIDE;dioxoplatinum;ADAMS CATALYST;PLATINIC OXIDE;1341-15-4;Platinium oxide;75 NSC 402624;Platindioxid
CBNumber:
CB1254558
Molecular Formula:
O2Pt
Molecular Weight:
227.08
MOL File:
1314-15-4.mol
Modify Date:
2024/6/18 13:26:42
Request For Quotation

Platinum dioxide Properties

Melting point 450 °C (lit.)
Density 10.2
RTECS TP2506020
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystalline
color Dark brown
Water Solubility Soluble in caustic potash solution. Insoluble in water, acid, aquaregia.
Merck 14,7527
Stability Contact with combustible material may cause fire. Incompatible with organic materials, powdered metals.
InChI InChI=1S/2O.Pt
InChIKey WNVYCMIJBVIKSY-UHFFFAOYSA-N
SMILES [Pt](=O)=O
CAS DataBase Reference 1314-15-4(CAS DataBase Reference)
NIST Chemistry Reference Platinum dioxide(1314-15-4)
EPA Substance Registry System Platinum oxide (PtO2) (1314-15-4)
solubility THF, o-xylene, chloroform, chlorobenzene and dichlorobenzene

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS03,GHS07
Signal word  Danger
Hazard statements  H272-H319
Precautionary statements  P210-P305+P351+P338
Hazard Codes  O,Xi
Risk Statements  8-36-41-38-36/37/38
Safety Statements  26-36/37/39-28A-22-17-36
RIDADR  UN 1479 5.1/PG 2
WGK Germany  2
TSCA  Yes
HazardClass  5.1
PackingGroup  II
HS Code  28439000
NFPA 704
0
2 2
OX

Platinum dioxide price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 459925 Platinum(IV) oxide surface area ≥75?m2/g 1314-15-4 250MG ₹5461.2 2022-06-14 Buy
Sigma-Aldrich(India) 459925 Platinum(IV) oxide surface area ≥75?m2/g 1314-15-4 1G ₹18703.5 2022-06-14 Buy
Sigma-Aldrich(India) 206032 Platinum(IV) oxide surface area ≥60?m2/g 1314-15-4 250MG ₹6615.6 2022-06-14 Buy
Sigma-Aldrich(India) 459925 Platinum(IV) oxide surface area ≥75?m2/g 1314-15-4 5G ₹58519.2 2022-06-14 Buy
Sigma-Aldrich(India) 206032 Platinum(IV) oxide surface area ≥60?m2/g 1314-15-4 1G ₹19147.5 2022-06-14 Buy
Product number Packaging Price Buy
459925 250MG ₹5461.2 Buy
459925 1G ₹18703.5 Buy
206032 250MG ₹6615.6 Buy
459925 5G ₹58519.2 Buy
206032 1G ₹19147.5 Buy

Platinum dioxide Chemical Properties,Uses,Production

Chemical Properties

Platinum dioxide, also known as Adams catalyst, is a dark brown powder, a hydrated form of platinum (IV) oxide (PtO2), produced by heating chloroplatinic acid (H2PtCl6) with sodium nitrate (NaNO3). Platinum nitrate is produced, and this decomposes to Platinum (IV) oxide with evolution of NO2 and oxygen. It is used in hydrogenations of alkenes to alkanes, nitro compounds to aminos, and ketones to alcohols. The actual catalyst is not the oxide but finely divided platinum black, which forms during the hydrogenation reaction.

Uses

As catalyst in hydrogenations. The actual catalyst is platinum black which is formed in situ by reduction of the PtO2 by the hydrogen used for the hydrogenation. Especially useful for reduction at room tempereture and hydrogen pressures up to 4 atmospheres. Suitable for the reduction of double and triple bonds, aromatic nuclei, carbonyl groups, nitro groups, and nitriles.

Application

Platinum (IV) Oxide commonly referred to as Adam’s Catalyst is used frequently in organic synthesis reactions, mainly catalytic hydrogenation. The compound itself shows no cytotoxicity in cells of the pulmonary origin when compared to its PtCl4 counterpart. It has also been used as a catalyst in amperometric biosensors that are based on oxidase enzymes.

Production Methods

PtO2 is obtained by reduction in chloroplatinic acid with formaldehyde or by fusing chloroplatinic acid with sodium nitrate.

General Description

Platinum(IV) oxide has been used for the reduction of citernyl bromide to form (S)-3,7-dimethyloctylbromide. Prepared by Adams′ nitrate fusion method.

Platinum dioxide Preparation Products And Raw materials

Raw materials

Chloroplantinic acid Sodium nitrate

Preparation Products

2-(2,3-DIHYDRO-1BENZENESULFONYL-PYRROLO[2,3-B]PYRIDIN-3-YL)ETHANAMINE (1,3-DIMETHYL-BUTYL)-HYDRAZINE 5-(BENZYLOXY)-1H-PYRROLO[3,2-B]PYRIDINE-2-CARBALDEHYDE (2-METHOXY-1-METHYL-ETHYL)-HYDRAZINE (1,2-DIMETHYL-PROPYL)-HYDRAZINE
3-Cyclohexyl-5,6,7,8-tetrahydroimidazo[1,5-a]pyrazine Platinum 1-Methyl-4-(methylamino)piperidine 2,5-Diaminopyrimidine 4-BROMO-2-(TRIFLUOROMETHYL)-5-METHOXYPYRIDINE
Finasteride
chevron_left

1of3

chevron_right

Platinum dioxide Suppliers

Global( 498)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
ANJI BIOSCIENCES +91-9000100077 +91-9000100077 Hyderabad, India 430 58 Inquiry
Yogi Dye Chem Industries +91-9821098577 +91-9821098577 Mumbai, India 124 58 Inquiry
Evans Fine Chem +91-9821340302 +91-9821340302 Maharashtra, India 286 58 Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
Vineeth Precious Catalysts Pvt Ltd +91-9049600004 +91-9049600004 Mumbai, India 29 58 Inquiry
Dhara Industries +91-9322395199 +91-9322395199 Mumbai, India 190 58 Inquiry
Metal Chem India +91-8999856889 +91-9011882000 Maharashtra, India 46 58 Inquiry
Scientific OEM +91-22- 2343 7546 / 2341 3094 New Delhi, India 1996 38 Inquiry
ALPHA CHEMIKA +91-22-22061123 +91-22-66382501 Mumbai, India 1681 43 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Supplier Advantage
ANJI BIOSCIENCES 58
Yogi Dye Chem Industries 58
Evans Fine Chem 58
JSK Chemicals 58
Vineeth Precious Catalysts Pvt Ltd 58
Dhara Industries 58
Metal Chem India 58
Scientific OEM 38
ALPHA CHEMIKA 43
CLEARSYNTH LABS LTD. 58

Related articles

1314-15-4(Platinum dioxide )Related Search:

Zirconium dioxide Carbon dioxide Boron oxide Rutile Thiourea dioxide
Quartz Bismuth trioxide Chlorine dioxide Platinum Stannic oxide
Platinum nitrate Platinum tetrachloride Carboplatin Rhodium Platinum dichloride
Holmium Oxide Ruthenium dioxide Ruthenium(IV) oxide hydrate
chevron_left

1of4

chevron_right
PLATINUM OXIDE (Black) Platinum(IV) oxide, anhydrous, Premion, 99.95% (metals basis), Pt 84.4% min PlatinuM(Ⅱ)oxide PlatinuM oxide anhydrous PlatinuM(IV) oxide, 83% Pt 1GR PlatinuM(IV) oxide, 83% Pt 5GR PLATINUM-(IV)-OXIDE, ANHYDROUS Platinium (IV)oxide anhydrous PLATINUM (IV) OXIDE HYDRATE (ADAMS CATALYST) Platinum(IV) oxide, anhydrous, Premion(R), 99.95% (metals basis), Pt 84.4% min Platinum(IV) oxide monohydrate, Adams Catalyst, Pt 75% min PLATINUM DIOXIDE, PtO2 ADAM'S CATALYST ADAMS' CATALYST ADAM'S TYPE CATALYST PlatinuM(IV) oxide surface area >=60 M2/g PlatinuM(IV) oxide surface area >=75 M2/g 99.95% (Metals basis), Pt 84.4% Min Platinum dioxide Platinum(IV) dioxide NSC 402624 PlatinuM(Ⅳ) oxide trihydrate Platimicoxide Platinium oxide, PtO2 Platinum oxide (PtO2) platinumoxide(pto2) PLATINUM(+4)OXIDE PLATINUM DIOXIDE PLATINUM(IV) DIOXIDE Platinum(II )oxide Platinum(IV)oxidehydrate(~80-82%Pt)(99.95+%-Pt)ADAM'SCATALYST[BASFC7018] platinum(iv) oxide monohydrate, adams catalyst platinum(iv) oxide, anhydrous, premion Platinum(IV) oxide, 83% Pt Platindioxid PLATINUM(IV) OXIDE HYDRATE: (80-82% PT)(99.95%-PT) ADAM''S CATALYST [ENGELHARD C7018] PLATINUM(IV) OXIDE (ADAMS CATALYST) PlatinuM Dioxid Platinum(IV) oxide, anhydrous, 99.95% trace metals basis atinum(IV) oxide PLATINUM(IV)OXIDE(HSE) Pt85.4%Platinum(IV oxide Platinum(IV)Oxide> Platinum dioxide ISO 9001：2015 REACH PtO2 50% moist (Adam's Catalyst) Platinum(Iv) Dioxide, Pure, Fisher Chemical Platinum(IV) oxide, anhydrous, Premion&trade ADAMS CATALYST Platinium oxide PtO2 PLATINIC OXIDE PLATINUM OXIDE 1341-15-4 dioxoplatinum 75  m2/g surface area ≥ Platinum(lV) oxide, Anhydrous, premion PLATINUM OXIDE ADAM CATALYST