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1-Hydroxynaphthalene-8-sulfonic acid

1-Hydroxynaphthalene-8-sulfonic acid Structure
CAS No.
117-22-6
Chemical Name:
1-Hydroxynaphthalene-8-sulfonic acid
Synonyms
1-NAPHTHOL-8-SULFOMIC ACID;1 NAPTHOL-8-SULPHONIC ACID;1-NAPHTHOL-8-SULFONIC ACID;alpha-Naphthol-8-sulfonic acid;1-Hydroxynaphthalene-8-sulfonicaci;8-hydroxynaphthalenesulphonic acid;8hydroxynaphthalene-1-sulfonic acid;1-Hydroxynaphthalene-8-sulfonic acid;8-hydroxy-1-naphthalenesulfonic acid;1-Naphthalenesulfonic acid, 8-hydroxy-
CBNumber:
CB5405682
Molecular Formula:
C10H8O4S
Molecular Weight:
224.23
MOL File:
117-22-6.mol
MSDS File:
SDS
Modify Date:
2024/5/23 18:06:45

1-Hydroxynaphthalene-8-sulfonic acid Properties

Density 1.549
pka 0.05±0.40(Predicted)
CAS DataBase Reference 117-22-6(CAS DataBase Reference)
EPA Substance Registry System 1-Naphthalenesulfonic acid, 8-hydroxy- (117-22-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338

1-Hydroxynaphthalene-8-sulfonic acid Chemical Properties,Uses,Production

Chemical Properties

1-Hydroxynaphthalene-8-sulfonic acid [117-22-6]. (8-hydroxynaphthalene-1-sulfonic acid), C10H8O4S, Mr 224.2, crystallizes as the monohydrate with mp 106℃. Sulfonation gives 1-hydroxynaphthalene-4,8-disulfonic acid, and alkali fusion with potassium hydroxide at 230℃ yields 1,8-dihydroxynaphthalene. Coupling with diazo compounds occurs in the 2- position.

Uses

The naphthosultone is usually satisfactory as an intermediate for further processing; however, for azo dye preparation the free naphthol must be used, for example, in C.I. Acid Black 54 and C.I. Acid Blue 158.

Production Methods

1-Aminonaphthalene-8-sulfonic acid is diazotized over 16 h at 50℃ and then heated to 80 ℃. After cooling, the precipitated naphthosultone is filtered off and washed. The sultone is heated with dilute sodium hydroxide at 100℃, which causes ring opening; the product is isolated after salting out.
	1-Hydroxynaphthalene-8-sulfonic acid synthesis

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8-hydroxy-1-naphthalenesulfonic acid alpha-Naphthol-8-sulfonic acid 1-Hydroxynaphthalene-8-sulfonic acid 1-NAPHTHOL-8-SULFONIC ACID 1 NAPTHOL-8-SULPHONIC ACID 8-hydroxynaphthalenesulphonic acid 8hydroxynaphthalene-1-sulfonic acid 1-Naphthalenesulfonic acid, 8-hydroxy- 1-NAPHTHOL-8-SULFOMIC ACID 1-Hydroxynaphthalene-8-sulfonicaci 117-22-6 117-26-6 Intermediates of Dyes and Pigments