1-NAPHTHOL-3,8-DISULFONIC ACID

1-NAPHTHOL-3,8-DISULFONIC ACID Structure
CAS No.
117-43-1
Chemical Name:
1-NAPHTHOL-3,8-DISULFONIC ACID
Synonyms
Epsilon acid;Disulfo acid E;Andresen's acid;1-NAPHTHOL-3,8-DISULFONIC ACID;4-Hydroxy-2,5-naphthalenedisulfonic acid;8-Hydroxy-1,6-naphthalenedisulfonic acid;8phydroxynaphthalene-1,6-disulfonic acid;8-Hydroxynaphthalene-1,6-Disulfonic Acid;8-hydroxynaphthalene-1,6-disulphonic acid;1,6-Naphthalenedisulfonic acid, 8-hydroxy-
CBNumber:
CB7676349
Molecular Formula:
C10H8O7S2
Molecular Weight:
304.3
MOL File:
117-43-1.mol
Modify Date:
2023/11/1 14:39:28

1-NAPHTHOL-3,8-DISULFONIC ACID Properties

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

1-NAPHTHOL-3,8-DISULFONIC ACID Chemical Properties,Uses,Production

Chemical Properties

White, crystalline scales. Soluble in hot water. 1-Hydroxynaphthalene-3,8-disulfonic acid [117-43-1]. (8-hydroxynaphthalene-1,6- disulfonic acid), epsilon acid, C10H8O7S2, Mr 304.3: the sodium salt crystallizes as the hexahydrate and is readily soluble in water. Alkali fusion at 200 ℃ gives 1,8-dihydroxynaphthalene-3-sulfonic acid and amination with ammonia and ammonium chloride at 170℃ gives 6,8-diaminonaphthalene-1-sulfonic acid. Diazo coupling takes place in the 2-position and bromination in the 4-position. The 1,8-sultone is formed on dehydration with concentrated sulfuric acid.

Uses

Azo-dye intermediate.

Production Methods

The acid sodium salt of 1-aminonaphthalene-3,8-disulfonic acid is hydrolyzed by heating with water under pressure at 180℃.

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1-NAPHTHOL-3,8-DISULFONIC ACID 8-Hydroxynaphthalene-1,6-Disulfonic Acid 8-hydroxynaphthalene-1,6-disulphonic acid Epsilon acid 8phydroxynaphthalene-1,6-disulfonic acid 8-Hydroxy-1,6-naphthalenedisulfonic acid Disulfo acid E 4-Hydroxy-2,5-naphthalenedisulfonic acid Andresen's acid 1,6-Naphthalenedisulfonic acid, 8-hydroxy- 117-43-1 C10H8O7S2 Intermediates of Dyes and Pigments