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ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Structure
CAS No.
12257-42-0
Chemical Name:
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
Synonyms
Chiralyst P461;bis[(2,3,5,6-B7;-chlorodirhodium;4-norbornadiene)dirhodium(I);Dichloro(norbornadiene)dirhodium;NORBORNADIENE RHODIUM(1) CHLORIDE;Chloronorbornadiene rhodium dimer;Bis[chloro(norbornadiene)rhodium];BIS(NORBORNADIENE-MU-CHLORORHODIUM);Dichlorobis(norbornadiene)dirhodium
CBNumber:
CB5697449
Molecular Formula:
C14H16Cl2Rh28*
Molecular Weight:
460.99
MOL File:
12257-42-0.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02
Request For Quotation

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Properties

Melting point 239-241°C (dec.)
storage temp. 2-8°C
solubility sol chloroform and benzene; insol ether and light petroleum
form Powder
color yellow to orange
Water Solubility insoluble in water
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P304+P340-P305+P351+P338-P405-P501a-P261-P280a
Hazard Codes  Xi,Xn
Risk Statements  36/37/38
Safety Statements  37/39-26
WGK Germany  3
F  10-21
TSCA  No
HS Code  28439000
NFPA 704
0
2 0

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 683167 Chiralyst P461 Umicore 12257-42-0 500MG ₹12176.7 2022-06-14 Buy
Sigma-Aldrich(India) 683167 Chiralyst P461 Umicore 12257-42-0 2G ₹45177 2022-06-14 Buy
Sigma-Aldrich(India) 249939 Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 96% 12257-42-0 500MG ₹11899.2 2022-06-14 Buy
TCI Chemicals (India) N0453 Norbornadiene Rhodium(I) Chloride Dimer 12257-42-0 100MG ₹4200 2022-05-26 Buy
Product number Packaging Price Buy
683167 500MG ₹12176.7 Buy
683167 2G ₹45177 Buy
249939 500MG ₹11899.2 Buy
N0453 100MG ₹4200 Buy

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Chemical Properties,Uses,Production

Chemical Properties

mustard yellow crystals

Uses

Di-μ-chlorobis(norbornadiene)dirhodium(I) is used as catalysts in olefin hydroformylation, olefin hydrogenation and olefin isomerization

Preparation

Bis(bicyclo[2.2.1]hepta-2,5- diene)dichlorodirhodium is prepared by reacting rhodium(III) Chloride and bicyclo[2.2.1]hepta-2,5-diene in aq ethanol, when shaken for 2 days, give a yellow deposit.

Purification Methods

It recrystallises from hot CHCl3/pet ether as fine crystals soluble in CHCl3 and *C6H6 but is almost insoluble in Et2O or pet ether. [Abel et al. J Chem Soc 3178 1959.]

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Preparation Products And Raw materials

Raw materials

Preparation Products

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Suppliers

Global( 184)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
GLR Innovations +91 9891111994 New Delhi, India 4535 58 Inquiry
Omkar Lab +91-9130062553 +91-9326135973 Maharashtra, India 47 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6768 58 Inquiry
Souvenier Chemicals 08048372762Ext 645 Mumbai, India 396 58 Inquiry
Manus Aktteva Biopharma LLP 08048250218Ext 800 Ahmedabad, India 655 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-+86-371-66670886 China 19805 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21628 55 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 33024 60 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29858 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418671 +8618949823763 China 34563 58 Inquiry
Supplier Advantage
GLR Innovations 58
Omkar Lab 58
TCI Chemicals (India) Pvt. Ltd. 58
Souvenier Chemicals 58
Manus Aktteva Biopharma LLP 58
Shanghai Daken Advanced Materials Co.,Ltd 58
Henan Tianfu Chemical Co.,Ltd. 55
ATK CHEMICAL COMPANY LIMITED 60
career henan chemical co 58
Hefei TNJ Chemical Industry Co.,Ltd. 58

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Spectrum

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER(12257-42-0)1HNMR(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER(12257-42-0)Raman(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER(12257-42-0)IR

12257-42-0((BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER)Related Search:

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[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Dichloro(p-cymene)ruthenium(II) dimer Rhodium(II) acetate dimer Ruthenium(II) chloride mesitylene dimer Tris(triphenylphosphine)rhodiu
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2,5-Norbornadiene Rhodium (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
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NORBORNADIENE RHODIUM(1) CHLORIDE NORBORNADIENE RHODIUM(I) CHLORIDE DIMER RHODIUM(I) CHLORIDE 2,5-NORBORNADIENE COMPLEX DIMER Chloronorbornadienerhodium(I)dimer,99% di-ae-chlorobis(norbornadiene) dirhodium(i) bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]di-mu-chlorodirhodium BICYCLO(2.2.1)HEPTA-2,5-DIENE-RHODIUM(I) Chloro(norbornadiene)rhodium(I), dimer, 99.9% Di-μ-chlorobis(norbornadiene)dirhodium(I), Rh 44% min 4-norbornadiene)dirhodium(I) DI-M-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I) Chloronorbornadiene rhodium dimer 2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer Norbornadiene rhodium chloride dimer Di-μ-chlorobis(norbornadiene) dirhodiuM(I) Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 96% Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer 2,5-NORBORNADIENE-RHODIUM(I) CHLORIDE DIMER Di-^m-chlorobis(norbornadiene)dirhodium(I), Rh 44% min (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER BICYCLO[2.2.1]HEPTA-2,5-DIENE-RHODIUM(I) CHLORIDE DIMER BIS(NORBORNADIENE-MU-CHLORORHODIUM) CHLORO(2,5-NORBORNADIENE)RHODIUM(I) DIMER CHLORO(NORBORNADIENE)RHODATE (I) DIMER CHLORONORBORNADIENE RHODIUM(I) DIMER DI-MU-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I) Di-mu-chlorobis(norbornadiene)dirhodium(I), Rh 44% min bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodirhodium Chloronorbornadiene rhodiuM(I) diMer, 99% 100MG Bis((mu-chloro)(norbornadiene)rhodium) Bis(chloro(eta4-norbornadiene)rhodium) Bis(mu-chloro)bis(norbornadiene)dirhodium Bis(mu-chloro)bis[(norbornadiene)rhodium] Bis[chloro(norbornadiene)rhodium] Dichloro(norbornadiene)dirhodium Dichlorobis(norbornadiene)dirhodium Di-mu-chlorobis(eta4-norbornadiene)dirhodium(I) Chloronorbornadiene rhodiuM(I) diMer,98% [Rh(NBD)Cl]2 Bis(norbornadiene-mu-chlororhodium) Chloronorbornadiene Rhodium(I) Dimer Di-Mu-chlorobis(norbornadiene)dirhodiuM Chloronorbornadiene rhodium(Ⅰ) dimer Chloronorbornadiene rhodium(I) dimer, [Rh(NBD)Cl]2 (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER ISO 9001：2015 REACH Chloronorbornadienerhodium(I) Dimer, Rh 44.0% bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorod... )-bicyclo[2.2.1]hepta-2,5-diene]di-BC bis[(2,3,5,6-B7 -chlorodirhodium Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 12257-42-0 bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-;... Chiralyst P461 12257-42-0 RhNBDCl2 C14H16Cl2Rh2 RhClC7H82 C14H16Cl2Rh 2C7H82ClRh Catalysts for Organic Synthesis