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Geranylacetone

CAS No.: 3796-70-1

Chemical Name:: Geranylacetone

Synonyms: (E)-geranylacetone;6,10-DIMETHYLUNDECA-5,9-DIEN-2-ONE;trans-Geranylacetone;(E)-6,10-dimethylundeca-5,9-dien-2-one;(5E)-6,10-DIMETHYLUNDECA-5,9-DIEN-2-ONE;(5E)-6,10-Dimethyl-5,9-undecadien-2-one;5,9-Undecadien-2-one,6,10-dimethyl-,(E)-;FEMA 3542;Zinc01599359;Geranylaceton

CBNumber:: CB5761078

Molecular Formula:: C13H22O

Molecular Weight:: 194.31

MOL File:: 3796-70-1.mol

MSDS File:: SDS

Modify Date:: 2024/6/25 17:38:21

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Geranylacetone Properties

Boiling point	254-258 °C(lit.)
Density	0.873 g/mL at 25 °C(lit.)
FEMA	3542 \| 6,10-DIMETHYL-5,9-UNDECADIEN-2-ONE
refractive index	n20/D 1.467(lit.)
Flash point	>230 °F
solubility	Very slightly soluble in water, soluble in alcohol and oils, 10% soluble in propylene glycol.
form	oily liquid
color	pale yellowish or almoti colorless
Specific Gravity	0.873
Odor	at 100.00 %. fresh green fruity waxy rose woody magnolia tropical
Odor Type	floral
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
JECFA Number	1122
BRN	1722277
LogP	4.129 (est)
CAS DataBase Reference	3796-70-1(CAS DataBase Reference)
NIST Chemistry Reference	5,9-Undecadien-2-one, 6,10-dimethyl-, (E)-(3796-70-1)
EPA Substance Registry System	5,9-Undecadien-2-one, 6,10-dimethyl-, (5E)- (3796-70-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P305+P351+P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39-36
WGK Germany	3
Hazard Note	Irritant
HS Code	29141900

Geranylacetone Chemical Properties,Uses,Production

Chemical Properties

6,10-Dimethyl-5,9-undecadien-2-one has a green and rosy floral odor and fresh-floral, light, but rather penetrating sweet-rosy, slightly green, magnolia-like odor. It blends well in lavender and fruity notes, where it imparts a clean and natural character. It helps to round out floral bouquets

Occurrence

Reported found in oil of citronella, yellow passion fruit, peppermint, Scotch spearmint oil, Japanese seafood, scallop, tomato, tomato paste, citrus peel oils, carrots, papaya, melon, Parmesan cheese, milk powder, cognac, tea, starfruit, figs, mango, red sage, nectarines, clams, pork, anise, and hyssop

Uses

(E)-6,10-Dimethylundeca-5,9-dien-2-one is diastereoselective used in preparation of Geranyl Acetone by Carroll reaction of linalool with Acetoacetate. This ketone, which was developed as an intermediate in the synthesis of Nerolidol, has been suggested for use in perfume compositions, particularly in soap perfumes, where its superior stability makes it a very reliable Itorahzer anct sweetener in floral compositions.

Preparation

By reaction of linalool and ethyl acetoacetate with an alkaline catalyst and subsequent rearrangement and decarboxylation.

Definition

ChEBI: A monoterpene ketone in which an (E)-geranyl group is bonded to one of the alpha-methyls of acetone. It is a component of essential oils from various plants including Nelumbo nucifera.

Geranylacetone Preparation Products And Raw materials

Raw materials

2-Methoxypropene Linalool Ethyl acetoacetate Aluminium isopropoxide

Preparation Products

(5E,9E)-6,10,14-Trimethylpentadeca-5,9,13-trien-2-one Isophytol

Geranylacetone Suppliers

Global( 194)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	China	12460	58	Inquiry
Hebei Kingfiner Technology Development Co.Ltd	+86-15532196582 +86-15373005021	China	2989	58	Inquiry
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	China	21675	55	Inquiry
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	China	8828	58	Inquiry
career henan chemical co	+86-0371-86658258 +8613203830695	China	29826	58	Inquiry
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 15319487004	China	2417	58	Inquiry
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	China	12922	58	Inquiry
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	China	34571	58	Inquiry
ANHUI WITOP BIOTECH CO., LTD	+8615255079626	China	23556	58	Inquiry
Shaanxi Dideu Medichem Co. Ltd	+86-029-89586680 +86-18192503167	China	9030	58	Inquiry

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Kingfiner Technology Development Co.Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hebei Guanlang Biotechnology Co., Ltd.	58
career henan chemical co	58
Shaanxi Dideu Medichem Co. Ltd	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
ANHUI WITOP BIOTECH CO., LTD	58
Shaanxi Dideu Medichem Co. Ltd	58

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(E)-6,10-dimethyl-5,9- undecadien-2-one TRANS-6,10-DIMETHYL-5,9-UNDECADIEN-2-ONE 6 10-DIMETHYL-5 9-UNDECADIEN-2-ONE 97+% Geranylacetone,trans geranylacetone,2,6-dimethyl-2,6-undecadien-10-one 5,9-Undecadien-2-one, 6,10-dimethyl-, (5E)- Geranylaceton GERANYLACETONE: CONTAINS CA. 35% NERYLACETONE Geranylacetone trans-6,10-Dimethyl-5,9-undecadien-2-one, Geranylacetone Geranylacetone, (E)+(Z), 97%, (Z)-isomer (nerylacetone) ca 45% Geranylacetone,6,10-Dimethyl-5,9-undecadien-2-one 6,10-Dimethyl-5,9-undecadien-2-one,6,10-Dimethyl-5,9-undecadien-2-one, Geranylacetone Zinc01599359 Geranylacetone, (E)+(Z), (Z)-Isomer (Nerylacetone) ca 45% Geranylacetone, (6E)-2,6-Dimethyl-10-oxoundeca-2,6-diene Geranylacetone, (E)+(Z) 10-dimethyl-9-undecadien-2-on(e)-6 2,6-Dimethyl-2,6-undecadien-10-one 6,10-dimethyl-(E)-5,9-undecadien-2-one 6,10-dimethyl-5,9-undecadien-2-one, (E) 9-Undecadien-2-one,6,10-dimethyl-,(E)-5 Acetone, Geranyl- geranylacetane CBI-BB ZERO/001230 FEMA 3542 GERANYL-2-PROPANONE Geranylacetone, 99%, mixture of isomers 6,10-Dimethyl-5,9-undecadien-2-one, mixed isomers cis,trans-Geranylacetone Geranylacetone USP/EP/BP 5,9-Undecadien-2-one,6,10-dimethyl-,(E)- (E)-6,10-dimethylundeca-5,9-dien-2-one (5E)-6,10-DIMETHYLUNDECA-5,9-DIEN-2-ONE (E)-geranylacetone trans-Geranylacetone 6,10-DIMETHYLUNDECA-5,9-DIEN-2-ONE (5E)-6,10-Dimethyl-5,9-undecadien-2-one 3796-70-1 CH32CCHCH2CH2CCH3CHCH2CH2COCH3 Organic Building Blocks Ketones C13 to C14 Carbonyl Compounds Building Blocks Analytical Standards Analytical Chromatography Product Catalog Alphabetic Acyclic Monoterpenes Terpenes