ChemicalBook > Product Catalog >Organic Chemistry >Alcohols,Phenols,Phenol alcohols >Phenol Alcohols derivatives >4-Chlorothiophenol

4-Chlorothiophenol

4-Chlorothiophenol Structure
CAS No.
106-54-7
Chemical Name:
4-Chlorothiophenol
Synonyms
4-CHLOROBENZENETHIOL;4-Chloro;PARA-CHLOROTHIOPHENOL;NSC 229564;orothiophenoL;p-Chlorthiofenol;4-CHLOROTHIOPENOL;4-chlorthiophenol;AKOS BBS-00004252;CHLOROTHIOPHENOL-4
CBNumber:
CB6130893
Molecular Formula:
C6H5ClS
Molecular Weight:
144.62
MOL File:
106-54-7.mol
MSDS File:
SDS
Modify Date:
2023/6/21 21:49:59

4-Chlorothiophenol Properties

Melting point 49-51 °C(lit.)
Boiling point 205-207 °C(lit.)
Density 1.1911
refractive index 1.5480
Flash point >230 °F
storage temp. 2-8°C
solubility methanol: soluble
pka pK1:5.9 (25°C)
form Crystalline Solid
color White to almost white
Water Solubility insoluble
Sensitive Stench/Lachrymatory
BRN 605971
InChIKey VZXOZSQDJJNBRC-UHFFFAOYSA-N
CAS DataBase Reference 106-54-7(CAS DataBase Reference)
NIST Chemistry Reference Benzenethiol, 4-chloro-(106-54-7)
EPA Substance Registry System Benzenethiol, 4-chloro- (106-54-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H314
Precautionary statements  P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes  C
Risk Statements  22-34-36/37-20/21/22
Safety Statements  26-36/37/39-45-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
RTECS  DC1050000
9-13-23
Hazard Note  Corrosive/Lachrymatory/Stench
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29309090
NFPA 704
1
3 0

4-Chlorothiophenol price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 125237 4-Chlorothiophenol 97% 106-54-7 5G ₹2359.85 2022-06-14 Buy
Sigma-Aldrich 125237 4-Chlorothiophenol 97% 106-54-7 100G ₹3290.8 2022-06-14 Buy
Sigma-Aldrich(India) 125237 4-Chlorothiophenol 97% 106-54-7 100G ₹3290.8 2022-06-14 Buy
Sigma-Aldrich(India) 125237 4-Chlorothiophenol 97% 106-54-7 500G ₹10132.2 2022-06-14 Buy
ALFA India ALF-B23838-36 4-Chlorothiophenol, 97% 106-54-7 500g ₹9657 2022-05-26 Buy
Product number Packaging Price Buy
125237 5G ₹2359.85 Buy
125237 100G ₹3290.8 Buy
125237 100G ₹3290.8 Buy
125237 500G ₹10132.2 Buy
ALF-B23838-36 500g ₹9657 Buy

4-Chlorothiophenol Chemical Properties,Uses,Production

Chemical Properties

white to almost white crystalline solid

Uses

4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups.

General Description

4-Chlorothiophenol undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides.

Hazard

Toxic by ingestion.

Purification Methods

Recrystallise the thiophenol from aqueous EtOH. The SMe ether has m 129o and the SEt ether has m 64o. [D'Sousa et al. J Org Chem 52 1720 1987, Beilstein 6 H 326, 6 I 149, 6 III 1034.]

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4-Chlorothiophenol/4-Chlorobenzenethiol 4-Cyano-Acetophonene/4-CA 4-Chlorothiophenol 99% 4-chlorthiophenol BENZENETHIOL,PARA-CHLORO- 4-CHLOROTHIOPENOL 4-Chlorobenzenethiol, 4-Chlorophenyl mercaptan 1-Chloro-4-mercaptobenzene p-Chlorothiophenol 10g [106-54-7] 4-Chlorothiophenol,4-Chlorobenzenethiol, 4-Chlorophenyl mercaptan 4-Chlorothiophenol, 98% 100GR 4-Chlorothiophenol, 98% 5GR 4-Chloromercaptobenzene 4-Chlorothiophenol NSC 229564 p-Chlorophenylthiol Chlorobenzene thiophenol 4-chloro-benzenethio Benzenethiol, p-chloro- Benzenethiol,4-chloro- p-chloro-benzenethio p-Chlorthiofenol Phenyl mercaptan, p-chloro- p-Mercaptochlorobenzene CHLOROTHIOPHENOL-4 AKOS BBS-00004252 4-CHLOROPHENYL MERCAPTAN 4-CHLOROTHIOPHENOL 4-CHLOROMERCAPTOBENZENE 4-Chlorophenylthiol 4-Chlorothiophenol,98% P-CHLOROBENZENETHIOL P-CHLOROTHIOPHENOL P-CHLOROPHENYL MERCAPTAN 4-Chlorobenzenethiol > 4-Chlorothiophenol ISO 9001:2015 REACH orothiophenoL 4-Chloro PARA-CHLOROTHIOPHENOL 4-CHLOROBENZENETHIOL 106-54-7 C6Cl1H5S1 C6H5SCl Thiols/Mercaptans Sulfur Compounds Organic Building Blocks Building Blocks Phenol&Thiophenol&Mercaptan Phenoles and thiophenoles Aromatic Phenols K00001