4-Chlorophenol
- CAS No.
- 106-48-9
- Chemical Name:
- 4-Chlorophenol
- Synonyms
- PARA CHLORO PHENOL;P-CHLOROPHENOL;4-CHLORPHENOL;4-chloro-1-hydroxybenzene;Chloroether;Phenol,4-chloro-;4-Chlorophenol(form2);4-Chlorophenol 5g [106-48-9];4-CHLOROPHENOL SOLUTION 725 MG/L FORAOX DETERMINATION ACCORDING TO DIN 38409-H41;(GC)>98%
- CBNumber:
- CB9477357
- Molecular Formula:
- C6H5ClO
- Molecular Weight:
- 128.56
- MOL File:
- 106-48-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/26 15:15:06
| Melting point | 42-45 °C |
|---|---|
| Boiling point | 220 °C (lit.) |
| Density | 1.306 g/mL at 25 °C (lit.) |
| vapor density | 4.43 (vs air) |
| vapor pressure | 1 mm Hg ( 49.8 °C) |
| refractive index | 1.5579 |
| Flash point | 240 °F |
| storage temp. | 2-8°C |
| solubility | ethanol: soluble50mg/mL, clear to very slightly hazy, colorless to faintly brownish-yellow |
| form | Low Melting Crystalline Mass |
| pka | 9.18(at 25℃) |
| color | White to pale yellow |
| Odor | Phenolic |
| Odor Threshold | 30 ppm |
| Water Solubility | 2.7 g/100 mL (20 ºC) |
| Sensitive | Air Sensitive |
| Merck | 14,2154 |
| BRN | 507004 |
| Dielectric constant | 9.5（54.0℃） |
| Stability | Stable. Incompatible with acid chlorides, acid anhydrides, oxidizing agents, iron. |
| LogP | 2.5 at 35℃ |
| CAS DataBase Reference | 106-48-9(CAS DataBase Reference) |
| NIST Chemistry Reference | p-Chlorophenol(106-48-9) |
| EPA Substance Registry System | p-Chlorophenol (106-48-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302+H312+H332-H314-H411 | |||||||||
| Precautionary statements | P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,N | |||||||||
| Risk Statements | 20/21/22-51/53-50 | |||||||||
| Safety Statements | 28-61-28A-24/25-60-36/37 | |||||||||
| RIDADR | UN 2020 6.1/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | SK2800000 | |||||||||
| F | 10-23 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29081000 | |||||||||
| Toxicity | LD50 orally in rats: 0.67 g/kg (Deichmann) | |||||||||
| NFPA 704 |
|
4-Chlorophenol price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 8.02254 | 4-Chlorophenol for synthesis | 106-48-9 | 100G | ₹2570 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.02254 | 4-Chlorophenol for synthesis | 106-48-9 | 500G | ₹3580 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.02254 | 4-Chlorophenol for synthesis | 106-48-9 | 1KG | ₹7200.01 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | PHR2596 | Parachlorophenol Pharmaceutical Secondary Standard; Certified Reference Material | 106-48-9 | 1G | ₹22764.98 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.02254 | 4-Chlorophenol for synthesis | 106-48-9 | 25KG | ₹65560 | 2022-06-14 | Buy |
4-Chlorophenol Chemical Properties,Uses,Production
Chemical Properties
off-white to light tan crystals or powder
Uses
It is used as main raw material of compounding for medicine, dye, plastic and other industries. 4-Chlorophenol was used in visible-light-induced degradation of 4-chlorophenol in aqueous suspension of pure TiO2.
Definition
ChEBI: A monochlorophenol substituted at the pare position by a chlorine atom.
General Description
White crystals with a strong phenol odor Slightly soluble to soluble in water, depending on the isomer, and denser than water. Noncombustible. Used as an intermediate in organic synthesis of dyes and drugs.
Air & Water Reactions
Slightly soluble to soluble in water.
Reactivity Profile
CHLOROPHENOLS, SOLID are incompatible with acid chlorides, acid anhydrides and oxidizing agents. Also incompatible with iron . Liquefy and darken in color at temperatures above 108°F.
Hazard
Toxic by skin absorption, inhalation, or ingestion; strong irritant to tissue.
Health Hazard
Inhalation causes headache, dizziness, weak pulse. Ingestion causes irritation of mouth and stomach; headache, dizziness, weak pulse. Contact with eyes causes severe irritation and burning. Contact with skin causes irritation and burn; if absorbed, causes same symptoms as inhalation.
Fire Hazard
Special Hazards of Combustion Products: Toxic and irritating hydrogen chloride and chlorine gases may form in fires.
Safety Profile
Poison by inhalation and intraperitoneal routes. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe skin and eye irritant. Human systemic effects by inhalation: excitement, irritability. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use water, spray, mist, fog, foam, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROPHENOLS and CHLORIDES.
Potential Exposure
Monochlorophenols are used in the manufacture of fungicides, slimicides, bactericides, pesticides, herbicides, disinfectants, wood and glue preservatives; in the production of phenolic resins; in the extraction of certain minerals from coal; as a denaturant for ethanol; as an antiseptic; as a disinfectant, and others.
Shipping
UN 2020 (solid); UN2021 (liquid) Chlorophenols, solid and liquid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Purification Methods
Distil the phenol, then crystallise it from pet ether (b 40-60o) or hexane, and dry it under vacuum over P2O5 at room temperature. [Bernasconi & Paschalis J Am Chem Soc 108 2969 1986, Beilstein 6 IV 820.]
Incompatibilities
May form explosive mixture with air. Contact with oxidizing agents can cause fire and explosion hazard. Heat produces hydrogen chloride and chlorine. Corrosive to aluminum, copper and other chemically active metals.
Waste Disposal
Incinerate in admixture with flammable solvent in furnace equipped with afterburner and scrubber.
4-Chlorophenol Preparation Products And Raw materials
Raw materials
Preparation Products
1of4
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| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| KARPSCHEM LABORATORIES | 58 |
| JSK Chemicals | 58 |
| CNS CHEMICALS | 58 |
| Aarti Industries Limited (AIL) | 58 |
| Super Hygienic Chemicals | 58 |
| S D Fine Chem Limited | 58 |
| ALPHA CHEMIKA | 43 |
| OCEAN TRADING CORPORATION | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Otto Chemie Pvt. Ltd. | 58 |