5-Chloromethylfurfural
- CAS No.
- 1623-88-7
- Chemical Name:
- 5-Chloromethylfurfural
- Synonyms
- 5-(CHLOROMETHYL)FURFURAL;5-(ChloroMethyl)-2-furfural;2-ForMyl-5-chloroMethylfuran;5-(ChloroMethyl)furfuraldehyde;5-(chloromethyl)-2-furaldehyde;5-(Chloromethyl)furan-2-carbaldehyde;2-Furancarboxaldehyde, 5-(chloromethyl)-;2-[5-(chloromethyl)-2-furanyl]acetaldehyde
- CBNumber:
- CB6937061
- Molecular Formula:
- C6H5ClO2
- Molecular Weight:
- 144.56
- MOL File:
- 1623-88-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/15 10:43:31
| Melting point | 37 °C |
|---|---|
| Boiling point | 137-138 °C(Press: 5 Torr) |
| Density | 1.295±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Dark Brown to Black Oil to Semi-Solid |
| Stability | Moisture Sensitive |
| EPA Substance Registry System | 2-Furancarboxyaldehyde, 5-(chloromethyl)- (1623-88-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|---|---|
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P321-P363-P405-P501 |
| HS Code | 2932190090 |
5-Chloromethylfurfural Chemical Properties,Uses,Production
Chemical Properties
Dark Brown Oil
Application
5-Chloromethylfurfural is a biofuel that can be made from the reaction of hydrochloric acid and furfural. It is used as a feedstock for the production of 5-hydroxymethylfurfural, which is an important intermediate in the synthesis of many other chemicals. 5-Chloromethylfurfural has been isolated at a yield of 57% from reactions between furfural and chlorine gas. The use of solid catalysts have improved this yield to 68%. It has high chemical stability and can withstand temperatures up to 200°C without decomposition. It also reacts with fatty acids to form amides.
Synthesis Reference(s)
Synthesis, p. 541, 1992 DOI: 10.1055/s-1992-26158
General Description
5-(Chloromethyl) Furfural (CMF) is a potential chemical building block for replacing petroleum-derived chemicals derived from lignocellulosic feedstocks. It is gaining traction as a more practical alternative to 5-(hydroxymethyl)furfural (HMF).
5-Chloromethylfurfural Preparation Products And Raw materials
Raw materials
Preparation Products
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