Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Structure
CAS No.
373650-12-5
Chemical Name:
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
Synonyms
RU(OAC)2[(S)-SEGPHOS];(S)-Ru(OAc)2(SEGPHOS);(S)-Ru(OAc)2(SEGPHOS(R));Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II),Ru(OAc)2[(S)-segphos;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos];Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
CBNumber:
CB71181064
Molecular Formula:
C38H28O4P2.C4H6O4Ru
Molecular Weight:
829.741
MOL File:
373650-12-5.mol
Modify Date:
2023/4/23 13:52:06

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Properties

Melting point >100°C
storage temp. 2-8°C
form solid
color yellow to black
Sensitive air sensitive

SAFETY

Risk and Safety Statements

WGK Germany  3

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 693243 (S)-Ru(OAc)2(SEGPHOS®) 373650-12-5 50MG ₹2408.7 2022-06-14 Buy
Sigma-Aldrich(India) 693243 (S)-Ru(OAc)2(SEGPHOS®) 373650-12-5 50MG ₹2408.7 2022-06-14 Buy
Sigma-Aldrich(India) 693243 (S)-Ru(OAc)2(SEGPHOS®) 373650-12-5 100MG ₹5516.7 2022-06-14 Buy
Product number Packaging Price Buy
693243 50MG ₹2408.7 Buy
693243 50MG ₹2408.7 Buy
693243 100MG ₹5516.7 Buy

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Chemical Properties,Uses,Production

Uses

(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:

  • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
  • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
  • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 60)Suppliers
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career henan chemical co +86-0371-86658258 +8613203830695 China 29900 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
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Hefei TNJ Chemical Industry Co.,Ltd. 0551-65418684 +8618949823763 China 25363 58 Inquiry
LEAPCHEM CO., LTD. +86-852-30606658 China 43348 58 Inquiry
Sinocompound Catalysts Co., Ltd. 0512-67216630 18962121273 China 279 64 Inquiry
Pushan Industry (Shaanxi) Co., Ltd. 029-81310890 13571859809 China 9999 58 Inquiry
Shanghai Ruipu Medical Technology Co., Ltd 15895968936 China 9996 58 Inquiry
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) (S)-Ru(OAc)2(SEGPHOS(R)) Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos] Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)] Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be... (S)-Ru(OAc)2(SEGPHOS) RU(OAC)2[(S)-SEGPHOS] Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II),Ru(OAc)2[(S)-segphos 373650-12-5 C42H34O8P2Ru Ru