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Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Structure
  • ₹2408.7 - ₹5516.7
  • Product name: Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
  • CAS: 373650-12-5
  • MF: C38H28O4P2.C4H6O4Ru
  • MW: 829.741
  • EINECS:
  • MDL Number:MFCD09753024
  • Synonyms:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);(S)-Ru(OAc)2(SEGPHOS(R));Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos];Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)];Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...;(S)-Ru(OAc)2(SEGPHOS);RU(OAC)2[(S)-SEGPHOS]
3 prices
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Brand

  • Sigma-Aldrich
  • Sigma-Aldrich(India)

Package

  • 50MG
  • 100MG
  • ManufacturerSigma-Aldrich
  • Product number693243
  • Product description(S)-Ru(OAc)2(SEGPHOS®)
  • Packaging50MG
  • Price₹2408.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number693243
  • Product description(S)-Ru(OAc)2(SEGPHOS®)
  • Packaging50MG
  • Price₹2408.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number693243
  • Product description(S)-Ru(OAc)2(SEGPHOS®)
  • Packaging100MG
  • Price₹5516.7
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 693243 (S)-Ru(OAc)2(SEGPHOS®) 50MG ₹2408.7 2022-06-14 Buy
Sigma-Aldrich(India) 693243 (S)-Ru(OAc)2(SEGPHOS®) 50MG ₹2408.7 2022-06-14 Buy
Sigma-Aldrich(India) 693243 (S)-Ru(OAc)2(SEGPHOS®) 100MG ₹5516.7 2022-06-14 Buy

Properties

Melting point :>100°C
storage temp. :2-8°C
form :solid
color :yellow to black
Sensitive :air sensitive

Safety Information

Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
Precautionary statements:

Description

(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:
  • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
  • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
  • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.


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