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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Structure
  • ₹1931.4 - ₹12800
  • Product name: Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • CAS: 325146-81-4
  • MF: C48H40O4P2Ru
  • MW: 843.86
  • EINECS:
  • MDL Number:MFCD09753020
  • Synonyms:Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);(R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′binaphthyl]ruthenium(II);Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap];RU(OAC)2[(R)-BINAP];Ru(OAc)2[(R)-binap];-binaphthyl]ruthenium(II),Ru(OAc)2[(R)-binap].;(OC-6-22)-Bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]ruthenium;(R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2bis(diphenylphosphino)-1,1inaphthyl]ruthenium(II)
Price4 Properties Safety Information Description
4 prices
Selected condition：

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 200MG
  • 500MG
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberR0166
  • Product descriptionRu(OAc)2[(R)-binap]
  • Packaging200MG
  • Price₹3400
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberR0166
  • Product descriptionRu(OAc)2[(R)-binap]
  • Packaging1G
  • Price₹12800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692220
  • Product description(R)-Ru(OAc)2(BINAP)
  • Packaging100MG
  • Price₹1931.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692220
  • Product description(R)-Ru(OAc)2(BINAP)
  • Packaging500MG
  • Price₹9435
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) R0166 Ru(OAc)2[(R)-binap] 200MG ₹3400 2022-05-26 Buy
TCI Chemicals (India) R0166 Ru(OAc)2[(R)-binap] 1G ₹12800 2022-05-26 Buy
Sigma-Aldrich(India) 692220 (R)-Ru(OAc)2(BINAP) 100MG ₹1931.4 2022-06-14 Buy
Sigma-Aldrich(India) 692220 (R)-Ru(OAc)2(BINAP) 500MG ₹9435 2022-06-14 Buy

Properties

Melting point :>100°C
storage temp. :2-8°C
form :Powder
color :ocher to green
Sensitive :air sensitive
InChIKey :XANQJWCSQJDBEA-UHFFFAOYSA-N
SMILES :CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.

Description

(R)-Ru(OAc)2(BINAP) may be used as a catalyst for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins.It can also catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.

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Suppliers and manufacturers

career henan chemical co
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
₹1.00 /1KG
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) CAS:325146-81-4
SOLFYN INTERNATIONAL LLP Evans Fine Chem TCI Chemicals (India) Pvt. Ltd. Synthesis With Catalysts Private Limited
XINXIANG RUNYU MATERIAL CO., LTD.
Shanghai Daken Advanced Materials Co.,Ltd
Shanghai Time Chemicals CO., Ltd.
ATK CHEMICAL COMPANY LIMITED
Chongqing Chemdad Co., Ltd