Chlorotriphenyltin
- CAS No.
- 639-58-7
- Chemical Name:
- Chlorotriphenyltin
- Synonyms
- TPTC;gc8993;ls4442;GC 8993;Aquatin;hoe2872;LS 4442;Tinmate;SKL1129;HOE 2872
- CBNumber:
- CB7143511
- Molecular Formula:
- C18H15ClSn
- Molecular Weight:
- 385.47
- MOL File:
- 639-58-7.mol
- Modify Date:
- 2023/12/22 17:53:22
| Melting point | 108 °C (dec.)(lit.) |
|---|---|
| Boiling point | 240 °C13.5 mm Hg(lit.) |
| Density | 1.49 g/cm3 (20℃) |
| vapor pressure | <0.02 hPa (20 °C) |
| Flash point | 70°C |
| storage temp. | APPROX 4°C |
| solubility | 0.04g/l |
| form | Powder |
| color | white |
| Water Solubility | insoluble |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 524762 |
| Exposure limits |
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
| Stability | Very Moisture Sensitive |
| CAS DataBase Reference | 639-58-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Chlorotriphenyl tin(639-58-7) |
| EPA Substance Registry System | Triphenyltin chloride (639-58-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS06,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H311+H331-H315-H318-H410 | |||||||||
| Precautionary statements | P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338 | |||||||||
| Hazard Codes | T,N,C | |||||||||
| Risk Statements | 23/24/25-50/53-34 | |||||||||
| Safety Statements | 26-27-28-45-60-61-28A-36/37/39 | |||||||||
| RIDADR | UN 3146 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | WH6860000 | |||||||||
| Autoignition Temperature | >250 °C | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29310095 | |||||||||
| Toxicity | LD50 orally in Rabbit: 135 mg/kg | |||||||||
| NFPA 704 |
|
Chlorotriphenyltin price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 45492 | Fentin chloride PESTANAL?, analytical standard | 639-58-7 | 250MG | ₹5131.05 | 2022-06-14 | Buy |
| ALFA India | ALF-L14289-36 | Triphenyltin chloride, 95% | 639-58-7 | 500g | ₹15078 | 2022-05-26 | Buy |
| ALFA India | ALF-L14289-22 | Triphenyltin chloride, 95% | 639-58-7 | 100g | ₹3771 | 2022-05-26 | Buy |
| ALFA India | ALF-L14289-14 | Triphenyltin chloride, 95% | 639-58-7 | 25g | ₹1869 | 2022-05-26 | Buy |
| TCI Chemicals (India) | T0447 | Triphenyltin Chloride | 639-58-7 | 5G | ₹4100 | 2022-05-26 | Buy |
Chlorotriphenyltin Chemical Properties,Uses,Production
Uses
Chlorotriphenylstannane is used in the synthesis of nanoparticles which bear triamide ligands.
Definition
ChEBI: An organotin compound that is triphenylstannane in which the hydrogen attached to tin is replaced by a chloro group. A fungicide used to control blights on potatoes, leaf spot diseases on sugar beet and anthracnose on beans.
General Description
White crystalline solid, insoluble in water; soluble in organic solvents. Used as a rodent repellent, molluscicide, fungicide and insecticide.
Air & Water Reactions
Hydrolyzes to hydroxide in water.
Reactivity Profile
Chlorotriphenyltin is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation.
Health Hazard
Toxic and irritating to the skin. Dermal exposure may lead to severe skin burns as well as renal failure and possible death. (Non-Specific -- Tin Compounds, Organic) Target organs affected are central nervous system, eyes, liver, urinary tract, skin and the blood.
Fire Hazard
When heated to decomposition, Chlorotriphenyltin emits toxic fumes of chlorides. Hydrolyzes to hydroxide in water. Stable when stored in dark with dry air.
Safety Profile
Poison by ingestion, intraperitoneal, and intravenous routes. Experimental reproductive effects. Mutation data reported. An insect chemosterilant. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-.
Purification Methods
Purify it by distillation, followed by recrystallisation from MeOH by adding pet ether (b 30-60o), m 105-106o [Kozeschow et al. Chem Ber 67 1348 1934], or by crystallisation from Et2O, or 5 parts of EtOH and a small volume of pet ether. [Krause Chem Ber 51 914 1918.] It sublimes in a vacuum. [Beilstein 16 H 914, 16 I 540, 16 II 625, 16 III 1240, 16 IV 1606.] HIGHLY TOXIC.
Chlorotriphenyltin Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
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| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
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