Tetrafluoroterephthalonitrile
![Tetrafluoroterephthalonitrile Structure](CAS/GIF/1835-49-0.gif)
- CAS No.
- 1835-49-0
- Chemical Name:
- Tetrafluoroterephthalonitrile
- Synonyms
- etrafluoroterephthalonitrile;2,3,5,6-tetrafluoro-1,4-benzenedicarbonitrile;JJFC;diamond2031;Diamond 2031;JACS-1835-49-0;uoroterephthaL;PTFEtwo of benzenenitrile;PERFLUOROTEREPHTHALONITRILE;Tetrafluoro-t-phthalonitrile
- CBNumber:
- CB7190045
- Molecular Formula:
- C8F4N2
- Molecular Weight:
- 200.09
- MOL File:
- 1835-49-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/30 16:33:02
Melting point | 197-199 °C (lit.) |
---|---|
Boiling point | 243.3±40.0 °C(Predicted) |
Density | 1.6184 (estimate) |
storage temp. | 2-8°C |
solubility | Soluble in hot methanol. |
form | Solid |
color | White to Light yellow |
CAS DataBase Reference | 1835-49-0(CAS DataBase Reference) |
NIST Chemistry Reference | 1,4-Benzenedicarbonitrile, 2,3,5,6-tetrafluoro-(1835-49-0) |
EPA Substance Registry System | Tetrafluoroterephthalonitrile (1835-49-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS06 |
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Signal word | Danger | |||||||||
Hazard statements | H301-H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P270-P301+P310-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | T,Xi | |||||||||
Risk Statements | 25-36/37/38-20/21-23/24/25-36/37/39-20/21/22 | |||||||||
Safety Statements | 26-45-37/39-22-36/37/39-27 | |||||||||
RIDADR | UN 3439 6.1/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | CZ1955000 | |||||||||
Hazard Note | Toxic | |||||||||
HazardClass | 6.1(b) | |||||||||
PackingGroup | III | |||||||||
HS Code | 29269090 | |||||||||
Toxicity | mouse,LD50,oral,56mg/kg (56mg/kg),Journal of Medicinal Chemistry. Vol. 21, Pg. 906, 1978. | |||||||||
NFPA 704 |
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Tetrafluoroterephthalonitrile price More Price(5)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 104426 | Tetrafluoroterephthalonitrile 99% | 1835-49-0 | 5G | ₹2652.13 | 2022-06-14 | Buy |
TCI Chemicals (India) | T1050 | Tetrafluoroterephthalonitrile min. 98.0 % | 1835-49-0 | 1G | ₹2400 | 2022-05-26 | Buy |
TCI Chemicals (India) | T1050 | Tetrafluoroterephthalonitrile min. 98.0 % | 1835-49-0 | 5G | ₹3000 | 2022-05-26 | Buy |
TCI Chemicals (India) | T1050 | Tetrafluoroterephthalonitrile min. 98.0 % | 1835-49-0 | 25G | ₹6900 | 2022-05-26 | Buy |
ALFA India | ALF-H61326-14 | Tetrafluoroterephthalonitrile, 98% | 1835-49-0 | 25g | ₹9440 | 2022-05-26 | Buy |
Tetrafluoroterephthalonitrile Chemical Properties,Uses,Production
Chemical Properties
YELLOW TO YELLOW-GREEN CRYSTALS
Uses
Tetrafluoroterephthalonitrile can be used as a synthessi reagent primarily used to create polymers of intinsic microporosity.
General Description
Tetrafluoroterephthalonitrile reacts with alkyl Grignard reagents to form corresponding 4-alkyltetrafluorobenzonitriles. Tetrafluoroterephthalonitrile acts as a four-electron donor ligand and forms tungsten(II)η2-nitrile complexes.
Synthesis
The specific synthesis method of Tetrafluoroterephthalonitrile is as follows: Potassium fluoride was dired at 500°C and then pulverized. Dimethylformamide was desiccated over potassium hydroxide pellets and then distilled under nitrogen. The water content thereof was determined in dehydrated methanol by the Karl-Fischer method to be 0.02% by weight. A reactor having a reflux condenser, within which the atmosphere was displaced with nitrogen gas, was charged with 1.330 grams of tetrachloroterephthalonitrile, 1.743 grams of dry potassium fluoride, and 10 milliliters of said dimethylformamide. After that, the mixture was heated to 130°C with simultaneous agitation and allowed to undergo a reaction for five hours. After that, the contents of the reactor were poured into ice water, and a saturated aqueous solution of sodium chloride was added.Consequently, the reaction product separated and floated to the surface. The floating phase was separated by filtration, washed with water, and dried. The yield of the product was calculated to be 81.0%.
Tetrafluoroterephthalonitrile Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20308 | 58 | Inquiry |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | China | 3002 | 58 | Inquiry |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16208 | 58 | Inquiry |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21669 | 55 | Inquiry |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | China | 9337 | 55 | Inquiry |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | China | 1377 | 60 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29898 | 58 | Inquiry |
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