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Manganese sulfide

Manganese sulfide Structure
CAS No.
18820-29-6
Chemical Name:
Manganese sulfide
Synonyms
Alabandite;Thioxomanganese;Manganoussulphide;MANGANOUS SULFIDE;MANGANESE SULFIDE;MANGANOUS SULFATE;MANGANOUS SULPHATE;manganese sulphide;manganesesulfide(mns);MANGANESE(II) SULFIDE
CBNumber:
CB7216608
Molecular Formula:
MnS
Molecular Weight:
87
MOL File:
18820-29-6.mol
MSDS File:
SDS
Modify Date:
2024/4/15 13:16:46

Manganese sulfide Properties

Melting point 1610°C
Density 3,99 g/cm3
vapor pressure 0Pa at 25℃
Flash point 280°C
solubility insoluble in H2O; soluble in dilute acid solutions
form Powder
color Green
Specific Gravity 3.99
Water Solubility 0.47 mg/100 mL (18 ºc)
Crystal Structure Hexagonal, Wurtzite (Zincite) Structure - Space Group P 63mc
Merck 14,5740
Solubility Product Constant (Ksp) pKsp: 9.60
Exposure limits ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
CAS DataBase Reference 18820-29-6(CAS DataBase Reference)
EPA Substance Registry System Manganese sulfide (MnS) (18820-29-6)

Manganese sulfide Properties

Hardness, Mohs 3.8

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H315-H317-H319-H411
Precautionary statements  P261-P264-P273-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-24/25
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
TSCA  Yes
NFPA 704
0
0 0

Manganese sulfide price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 400947 Manganese(II) sulfide ~100?mesh particle size 18820-29-6 5G ₹3875.35 2022-06-14 Buy
ALFA India ALF-012835-22 Manganese(II) sulfide, 99.9% (metals basis) 18820-29-6 100g ₹56641 2022-05-26 Buy
ALFA India ALF-012835-14 Manganese(II) sulfide, 99.9% (metals basis) 18820-29-6 25g ₹14160 2022-05-26 Buy
ALFA India ALF-012835-06 Manganese(II) sulfide, 99.9% (metals basis) 18820-29-6 5g ₹4305 2022-05-26 Buy
ottokemi M 1500 Manganese sulphide 18820-29-6 100gm ₹1602 2022-05-26 Buy
Product number Packaging Price Buy
400947 5G ₹3875.35 Buy
ALF-012835-22 100g ₹56641 Buy
ALF-012835-14 25g ₹14160 Buy
ALF-012835-06 5g ₹4305 Buy
M 1500 100gm ₹1602 Buy

Manganese sulfide Chemical Properties,Uses,Production

Description

Manganese(II) sulfide, MnS, occurs in nature as the mineral alabandite (isometric), rambergite (hexagonal), and the recently found browneite (isometric, with sphalerite-type, ZnS, structure, extremely rare and is only known from a meteorite). Manganese(II) sulfide can be formed through the reaction of a manganese(II) salt (such as manganese(II) chloride) with ammonium sulfide.

Chemical Properties

pink, green, or brownish green powder(s); three crystal(s) forms: α: green cub; β: red cub; γ: red hexagonal; used as an additive in steel production [HAW93] [MER06]

Physical properties

Habit: massive or granular.
Color: Brownish black to black, tarnish upon exposure to moist air.
Luster: submetallic.
Diaphaneity: opaque.
Cleavage: (110) perfect.
Fracture: uneven.
Streak: green.
Occurrence: epithermal sulfide vein deposits.

Uses

Additive in steel making.

General Description

MnS can exist in three polymorphs; α,β,γ, of these, the α phase is most thermodynamically stable.

Structure and conformation

The crystal structure of manganese(II) sulfide is comparable to that of sodium chloride. The pink color of MnS is probably caused by poor coupling between the lowest energy unoccupied Mn orbitals, resulting in discrete states rather than a delocalized band. Consequently, the lowest energy band-to-band electronic transition requires very high-energy (ultraviolet) photons.

Manganese sulfide Preparation Products And Raw materials

Raw materials

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Preparation Products

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