Benzyl methacrylate
- CAS No.
- 2495-37-6
- Chemical Name:
- Benzyl methacrylate
- Synonyms
- BZMA;Benzylmethacrylat;BENZYL METHACRYLATE;BENZYLMETHACRAYLATE;Benzyl 2-methylacrylate;Methacrylic acid benzyl;Benzyl methacrylate ,98%;benzyl 2-methylprop-2-enoate;METHACRYLIC ACID BENZYL ESTER;Benzyl Methacrylate, stabilized
- CBNumber:
- CB7306028
- Molecular Formula:
- C11H12O2
- Molecular Weight:
- 176.21
- MOL File:
- 2495-37-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/6 17:14:09
| Melting point | <25 °C |
|---|---|
| Boiling point | 95-98 °C/4 mmHg (lit.) |
| Density | 1.04 g/mL at 25 °C (lit.) |
| vapor pressure | 3Pa at 20℃ |
| refractive index |
n |
| Flash point | 225 °F |
| storage temp. | 2-8°C(protect from light) |
| form | clear liquid |
| color | Colorless |
| Water Solubility | Insoluble in water. |
| Sensitive | Light Sensitive |
| BRN | 2045924 |
| Stability | Stable. Flammable. Incompatible with free-radical initiators, oxidizing agents, reducing agents. Avoid heat. Light-sensitive. |
| LogP | 3.1 at 20℃ |
| CAS DataBase Reference | 2495-37-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzyl methacrylate(2495-37-6) |
| EPA Substance Registry System | 2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26 | |||||||||
| WGK Germany | 1 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163990 | |||||||||
| NFPA 704 |
|
Benzyl methacrylate price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 409448 | Benzyl methacrylate 96%, contains monomethyl ether hydroquinone as inhibitor | 2495-37-6 | 250ML | ₹3972.78 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 409448 | Benzyl methacrylate 96%, contains monomethyl ether hydroquinone as inhibitor | 2495-37-6 | 1L | ₹7014.6 | 2022-06-14 | Buy |
| TCI Chemicals (India) | M0279 | Benzyl Methacrylate (stabilized with MEHQ) min. 98.0 % | 2495-37-6 | 25ML | ₹1900 | 2022-05-26 | Buy |
| ALFA India | ALF-L10840-30 | Benzyl methacrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol | 2495-37-6 | 250g | ₹3854 | 2022-05-26 | Buy |
| TCI Chemicals (India) | M0279 | Benzyl Methacrylate (stabilized with MEHQ) min. 98.0 % | 2495-37-6 | 500ML | ₹5500 | 2022-05-26 | Buy |
Benzyl methacrylate Chemical Properties,Uses,Production
Description
The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].
Chemical Properties
Colorless oily liquid. Very slightly soluble in water, soluble in alcohol and oils. Soft, warm, herbaceous-rosy odor of moderate tenacity.
Uses
Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.
Advantages
The Tg of the copolymer was elevated, while thermal stability was first increased and then decreased with the introduction of Benzyl methacrylate. Besides, the water resistance of the latex PSA was improved by the presence of BzMA, which was confirmed by water contact angle measurements. Furthermore, as the BzMA content increased, the gel content slightly decreased, while sol molecular weight (Mw, Mn) of the polymer increased. Finally, with respect to the adhesive properties of the PSA, it was observed that loop tack decreased, while shear strength increased with the incorporation of BzMA. 180° peel strength initially increased and then decreased with the addition of Benzyl methacrylate from 0 to 30 wt%, with a maximum value at 5 wt%.
References
[1] Cheng Fang , Xiaolong Zhu, Fuxiang Zhou . “The application research of benzyl methacrylate (BzMA) in acrylate latex pressure sensitive adhesives.” International Journal of Adhesion and Adhesives 107 (2021): Article 102861.
Benzyl methacrylate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Kowa India Pvt., Ltd. | 91-22-28524680 | Maharashtra, India | 54 | 58 | Inquiry |
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 | China | 163 | 58 | Inquiry |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | China | 12459 | 58 | Inquiry |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20313 | 58 | Inquiry |
| Ouhuang Engineering Materials (Hubei) Co., Ltd | +86-86177 | China | 2952 | 58 | Inquiry |