7-Ethoxy-4-methyl-2H-chromen-2-one

- CAS No.
- 87-05-8
- Chemical Name:
- 7-Ethoxy-4-methyl-2H-chromen-2-one
- Synonyms
- Morlin;Maraniol;TIMTEC-BB SBB010011;Cefuroxime Impurity 79;7-ETHOXY-4-METHYLCOUMARIN;4-METHYL-7-ETHOXYCOUMARIN;METHYL-7-ETHOXYCOUMARIN, 4-;Coumarin, 7-ethoxy-4-methyl-;7-Ethoxy-4-methylcoumarin>7-Ethoxy-4-methylcoumarin 98%
- CBNumber:
- CB7316399
- Molecular Formula:
- C12H12O3
- Molecular Weight:
- 204.22
- MOL File:
- 87-05-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/12/18 14:15:30
Melting point | 114-116 °C (lit.) |
---|---|
Boiling point | 351.4±37.0 °C(Predicted) |
Density | 1.163±0.06 g/cm3(Predicted) |
storage temp. | -20°C Freezer, Under inert atmosphere |
solubility | DMF: soluble |
form | Solid |
color | White to Off-White |
Odor | at 100.00 %. nutty walnut |
Odor Type | nutty |
BRN | 169998 |
LogP | 2.973 (est) |
CAS DataBase Reference | 87-05-8(CAS DataBase Reference) |
NIST Chemistry Reference | 4-Methyl-7-ethoxycoumarin(87-05-8) |
EPA Substance Registry System | 2H-1-Benzopyran-2-one, 7-ethoxy-4-methyl- (87-05-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302+H312+H332-H319-H335 | |||||||||
Precautionary statements | P261-P271-P280 | |||||||||
Hazard Codes | Xi | |||||||||
Safety Statements | 24/25 | |||||||||
WGK Germany | 3 | |||||||||
F | 8 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | Yes | |||||||||
HS Code | 29322090 | |||||||||
NFPA 704 |
|
7-Ethoxy-4-methyl-2H-chromen-2-one price More Price(2)
7-Ethoxy-4-methyl-2H-chromen-2-one Chemical Properties,Uses,Production
Chemical Properties
White solid; walnut odor. Slightly soluble in alcohol.
Uses
Perfumery, flavoring.
General Description
7-Ethoxy-4-methylcoumarin (EtOMC), also known as ethyl 4-methylumbelliferyl ether, is a coumarin derivative. Its standard molar energy of combustion is ?5888.0 ± 3.2kJ·mol?1 and standard molar enthalpy of formation in the crystalline phase is ?545.4 ± 3.6kJ·mol?1.EtOMC can be prepared by reacting methyl acetoacetate with 3-ethoxyphenol in the presence of boron trifluoride dihydrate.The fluorescence quenching of EtOMC is more effective in the presence 4-hydroxy-TEMPO (4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl).
Synthesis
Prod.:
1) from Diketene plus Resorcinol with sulfuric
acid to produce 4-Methyl-7-hydroxy -
coumarin. Ethylation produces subject
material.
2) from Resorcinol plus Ethylacetoacetate,
followed by Ethylation.
7-Ethoxy-4-methyl-2H-chromen-2-one Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
BTC pharm India | +918790379245 | AndhraPradesh, India | 1262 | 58 | Inquiry |
GLR Innovations | +91 9891111994 | New Delhi, India | 4535 | 58 | Inquiry |
chromsynth pvt ltd | +919704220374 | Hyderabad, India | 244 | 58 | Inquiry |
chakrachem Lifesciences | +91 9902744663 | Hyderabad, India | 451 | 58 | Inquiry |
BASR Fine Chemicals Pvt. Ltd. | +91-9848230391 +91-9848230391 | Telangana, India | 908 | 58 | Inquiry |
Aadish Impex Private Limited | 91-7710067023 | Maharashtra, India | 89 | 58 | Inquiry |
Biosyn Research Chemicals | +91 9346022300/+91 9399339999 | Telangana, India | 1340 | 58 | Inquiry |
Dr Chindepalli | 91-7036227677 | Hyderabad, India | 486 | 58 | Inquiry |
PEE ESS AROMATICS | +91 4426247322 | New Delhi, India | 258 | 30 | Inquiry |
Evans Fine Chem | 08048602255 | Hyderabad, India | 289 | 58 | Inquiry |
Supplier | Advantage |
---|---|
BTC pharm India | 58 |
GLR Innovations | 58 |
chromsynth pvt ltd | 58 |
chakrachem Lifesciences | 58 |
BASR Fine Chemicals Pvt. Ltd. | 58 |
Aadish Impex Private Limited | 58 |
Biosyn Research Chemicals | 58 |
Dr Chindepalli | 58 |
PEE ESS AROMATICS | 30 |
Evans Fine Chem | 58 |