ChemicalBook > Product Catalog >Organic Chemistry >Carboxylic acids and derivatives >Carboxylic acid esters and derivatives >Allyl chloroformate

Allyl chloroformate

Allyl chloroformate Structure
CAS No.
2937-50-0
Chemical Name:
Allyl chloroformate
Synonyms
Alloc-Cl;Allyl carbonochloridate;ACF;2-propenylchloroformate;ALLYL CHLOROCARBONATE;CHLOROFORMIC ACID ALLYL ESTER;A1CF;Ally chloroformate;allyl chlorofomate;ALLYL CHLOROFORMATE
CBNumber:
CB7338849
Molecular Formula:
C4H5ClO2
Molecular Weight:
120.53
MOL File:
2937-50-0.mol
MSDS File:
SDS
Modify Date:
2024/4/6 17:48:18

Allyl chloroformate Properties

Melting point 106℃
Boiling point 109 °C
Density 1.134 g/mL at 20 °C(lit.)
vapor pressure 3.67 psi ( 20 °C)
refractive index n20/D 1.422(lit.)
Flash point 88 °F
storage temp. 2-8°C
solubility Chloroform
form Liquid
color Clear slightly yellow to light orange to reddish brown
Odor Extremely irritating, causes tears; pungent.
BRN 773915
Stability Moisture Sensitive
CAS DataBase Reference 2937-50-0(CAS DataBase Reference)
NIST Chemistry Reference Allyl chloroformate(2937-50-0)
EPA Substance Registry System Carbonochloridic acid, 2-propen-1-yl ester (2937-50-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H226-H301-H314-H330
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T+
Risk Statements  10-22-26-34
Safety Statements  26-28-36/37/39-45
RIDADR  UN 1722 6.1/PG 1
WGK Germany  3
RTECS  LQ5775000
19
HazardClass  6.1(b)
PackingGroup  I
HS Code  29159000
Toxicity mouse,LC50,inhalation,23100ug/m3 (23.1mg/m3),LUNGS, THORAX, OR RESPIRATION: DYSPNEA,Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(5), Pg. 51, 1984.
NFPA 704
3
4 1

Allyl chloroformate Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

General Description

A colorless liquid with a pungent odor. Flash point 88°F. Corrosive to metals and tissue. Very toxic by inhalation, ingestion and/or skin contact. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Water reaction produces heat and acidic HCl. In the presence of moist air, corrosive hydrogen chloride is produced.

Reactivity Profile

Acid halides, such as Allyl chloroformate, are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

Vapor irritates eyes and respiratory tract. Contact with liquid causes eye and skin irritation, and ingestion irritates mouth and stomach.

Chemical Reactivity

Reactivity with Water Reacts slowly generating hydrogen chloride; Reactivity with Common Materials: Corrosive metals; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water, rinse with sodium bicarbonate solution; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Poison by inhalation and ingestion. Corrosive. Dangerous when exposed to heat, open flame (or sparks), or powerful oxidizers. Can react with oxidizing materials. To fight fire, use alcohol foam, spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and ESTERS.

Global( 226)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
SYNGREEN LIFESCIENCES PVT.LTD +919849474297 Telangana, India 82 58 Inquiry
Paushak Limited +91-2653007932 +91-9727736899 Vadodara, India 59 58 Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
OCEAN TRADING CORPORATION +91(22) 24921669 New Delhi, India 6211 58 Inquiry
Survival Technologies Pvt Ltd +91 (22) 4212-8221 New Delhi, India 290 50 Inquiry
Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21675 55 Inquiry
ALLYLCHLOROFORMATE(ACF) Prop-1-enylchlorocarbonate (Allyloxycarbonyl) chloride Chloridocarbonic acid allyl Chloridocarbonic acid allyl ester Allyl chloroformate,97% Alloc-Clallyloxycarbonylchloride Chlorine forMic acid allyl ester A1CF APOBEC1 complementation factor Carbonochloridicacid, 2-propen-1-yl ester Allyl chloroforMate, 98+% ALOC-CL allyloxycarbonylchloride allylesterkyselinychlormravenci carbonochloridicacid,2-propenylester chlorocarbonicacidallylester chloro-formicaciallylester ALLYL CHLOROFORMATE Ally chloroformate ALLYL CHLOROFORMATE, STAB. allyl chlorofomate Allyl Chloroformate > Allyl chloroformate ISO 9001:2015 REACH prop-2-enyl carbonochloridate 2-propenylchloroformate Allyl carbonochloridate Alloc-Cl CHLOROFORMIC ACID ALLYL ESTER ALLYL CHLOROCARBONATE ACF ANTI-ACF(C-TERMINAL) antibody produced in rabbit Allyi Chloro Formate 2937-50-0 2397-50-0 C4H5CIO2 ClCOOCH2CHCH2 CH2CHCH2OCOCl Synthetic Reagents Others Protection and Derivatization Protecting and Derivatizing Reagents Amine ProtectionProtection and Derivatization Others Peptide Synthesis Protecting and Derivatizing Reagents Specialty Synthesis Pharmaceutical Intermediates CHLOROFORMATES